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NCERT Exemplar · Q2

Q.Which of the following is not an actinoid?

(i) Curium (Z = 96)
(ii) Californium (Z = 98)
(iii) Uranium (Z = 92)
(iv) Terbium (Z = 65)
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✓ Free question

Actinoids are the fourteen elements from thorium (Z=90Z = 90) to lawrencium (Z=103Z = 103) in which the 5f5f subshell is progressively filled. Terbium (Z=65Z = 65) lies in the lanthanoid series, not the actinoid series. The answer is (D).

The actinoid series is defined by the progressive filling of the 5f5f orbitals, just as the lanthanoid series is characterized by the filling of 4f4f orbitals. Understanding where these series begin and end in the periodic table immediately tells us which elements belong to each family.

The actinoids span from thorium (Z=90Z = 90) to lawrencium (Z=103Z = 103), occupying the bottom row of the f-block. These elements follow actinium (Z=89Z = 89) and are characterized by electrons entering the 5f5f subshell (though there are some irregularities in electron configurations due to the close energy levels of 5f5f, 6d6d, and 7s7s orbitals).

Let me examine each option:

  1. Curium (Z=96Z = 96): This element falls squarely in the middle of the actinoid series. With 96 protons, it lies between americium (Z=95Z = 95) and berkelium (Z=97Z = 97), well within the Z=90Z = 90 to 103103 range. Curium is definitely an actinoid.

  2. Californium (Z=98Z = 98): Similarly, californium sits comfortably within the actinoid series. Named after California (where it was first synthesized), it continues the 5f5f filling pattern. This is an actinoid.

  3. Uranium (Z=92Z = 92): The most famous actinoid, uranium is the heaviest naturally occurring element in significant quantities. At Z=92Z = 92, it's the third member of the actinoid series (after thorium and protactinium). Uranium is certainly an actinoid.

  4. Terbium (Z=65Z = 65): Here's the outlier. With only 65 protons, terbium falls far short of the actinoid range. In fact, Z=65Z = 65 places it in the lanthanoid series (also called the rare earth elements), which runs from cerium (Z=58Z = 58) to lutetium (Z=71Z = 71). Terbium belongs to the 4f4f block, not the 5f5f block.

Note

The lanthanoids occupy the first row of the f-block (elements 58–7158–71), while the actinoids occupy the second row (elements 90–10390–103). The two series are often placed below the main periodic table to keep the table compact.

✓Final answer

The correct option is (D) — Terbium is a lanthanoid, not an actinoid.

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