Exercises · 9.29
Q.What properties of water make it useful as a solvent? What types of compound can it
(i) dissolve, and
(ii) hydrolyse ?
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Start your 14-day free trial to unlock the full solution →Properties of water making it a good solvent:
- A high dipole moment (highly polar O–H bonds and a bent molecular shape) allows strong electrostatic interaction with charged and polar species.
- A high dielectric constant weakens the electrostatic attraction between oppositely-charged ions in an ionic lattice once immersed, helping the lattice dissociate.
- Its ability to form extensive hydrogen bonds lets it interact strongly with polar covalent molecules bearing –OH, –NH, or similar groups.
(i) What it dissolves:
- Ionic (electrovalent) compounds — e.g., NaCl, KCl — water molecules surround and hydrate the individual cations and anions (ion–dipole interaction), overcoming the lattice energy and dispersing the ions into solution.
- Polar covalent (molecular) compounds capable of hydrogen bonding — e.g., sugars, alcohols, ammonia — dissolve because their polar groups hydrogen-bond with water molecules.
(ii) What it hydrolyses:
Water hydrolyses covalent compounds that have sufficiently polar/polarisable bonds, especially halides of non-metals (or metalloids) with available low-lying orbitals or high electronegativity differences — e.g.:
…
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