Q.If the concentration of glucose (C6H12O6) in blood is 0.9 g L−1, what will be the molarity of glucose in blood?
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Molality: The Concentration That Ignores Temperature
Imagine you're making a cup of sweet tea. You add sugar to hot water, stir, and taste. If you let the tea cool to room temperature, the amount of sugar hasn't changed — but the volume of the liquid has shrunk slightly. If you measured concentration as "grams of sugar per litre of solution," that number would change just because the temperature changed. That's annoying if you're a chemist who needs a reliable, temperature-independent way to describe how much solute is present.
Molality was invented to solve exactly this problem.
The Intuition
Instead of measuring the volume of the solution (which expands and contracts with temperature), molality measures the mass of the solvent. Mass doesn't change with temperature. So molality gives you a concentration that stays the same whether your solution is hot or cold.
Think of it this way:
- Molarity = moles of solute per litre of solution (temperature-sensitive)
- Molality = moles of solute per kilogram of solvent (temperature-independent)
The solvent is the substance doing the dissolving — usually water. The solute is what gets dissolved — sugar, salt, etc.
The Precise Definition
Molality (m)=kilograms of solventmoles of solute
The symbol for molality is a lowercase m (not to be confused with M for molarity).
Key points to remember:
- The denominator is solvent mass, not solution mass
- The unit is mol/kg (often written as simply "m")
- It is independent of temperature because mass doesn't change with temperature
Worked Example
Problem: 36 g of glucose (C6H12O6, molar mass = 180 g/mol) is dissolved in 500 g of water. Calculate the molality of the solution.
Step 1: Find moles of solute
Moles of glucose=180 g/mol36 g=0.2 mol
Step 2: Convert solvent mass to kilograms
500 g=0.5 kg
Step 3: Apply the formula
m=0.5 kg0.2 mol=0.4 m
The answer is 0.4 m (or 0.4 mol/kg). Notice we used the mass of water (500 g), not the mass of the solution (which would be 536 g).
Common Mistake to Avoid
Do not use the mass of the solution in the denominator. The formula specifically asks for the mass of the solvent alone. If the problem gives you the total mass of the solution, subtract the mass of the solute to find the solvent mass.
When Do You Use Molality?
Molality is the star in two important situations: …
Why this formula?
Molality Calculation: Why the Formula Works
Molality is a measure of concentration that is temperature-independent — this is its key advantage over molarity. Let's understand why the formula takes the form it does.
The Definition First
Molality (m) is defined as:
m=mass of solvent in kgmoles of solute
The unit is mol/kg, often written as m (e.g., 0.5 m glucose solution).
Why Mass of Solvent, Not Solution?
This is the critical conceptual point.
The Reasoning
- Molarity uses volume of solution → volume changes with temperature (expansion/contraction). So molarity changes with temperature.
- Molality uses mass of solvent → mass is invariant with temperature. So molality remains constant regardless of temperature changes.
Key insight: By using the solvent's mass (not the solution's volume), we eliminate temperature dependence. This is why molality is preferred for colligative properties (boiling point elevation, freezing point depression) — these properties depend on the number of solute particles, not on temperature.
Deriving the Formula Step-by-Step
Step 1: Moles of Solute
If you have wsolute grams of solute with molar mass Msolute (g/mol):
moles of solute=Msolutewsolute
Step 2: Mass of Solvent in kg
If the solvent mass is Wsolvent grams:
mass of solvent in kg=1000Wsolvent
Step 3: Putting It Together
m=1000WsolventMsolutewsolute
Simplifying:
m=Msolute×Wsolventwsolute×1000
The Final Formula (Exam-Ready)
m=Msolute×Wsolventwsolute×1000
Where:
- wsolute = mass of solute in grams
- Msolute = molar mass of solute in g/mol
- Wsolvent = mass of solvent in grams
Why the ×1000 Factor? …
The key idea is molarity calculation: molarity (M) = moles of solute per litre of solution.
Step 1: Find the molar mass of glucose (C6H12O6).
6×12+12×1+6×16=72+12+96=180 g mol−1.
Step 2: Convert the given concentration to moles per litre.
Moles of glucose in 1 L = 180 g mol−10.9 g=0.005 mol. …
Molarity is moles per litre. Given 0.9 g L−1 of glucose (molar mass 180 g mol−1), the molarity is 0.9/180=0.005 M. The correct option is (iii).
The question asks for molarity, not molality — a common point of confusion. Molarity (M) is defined as the number of moles of solute per litre of solution. Here, the concentration is already given in grams per litre (g L−1), which is a mass concentration. Converting that to molarity is straightforward: divide by the molar mass of glucose.
Glucose has the formula C6H12O6. Let’s calculate its molar mass quickly:
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
- Total: 72+12+96=180 g mol−1
Now, the given mass concentration is 0.9 g L−1. That means every litre of blood contains 0.9 grams of glucose.
-
Find moles of glucose per litre
Moles = mass / molar mass = 0.9 g/180 g mol−1=0.005 mol.
-
Molarity is moles per litre
Since we already have the mass per litre, the moles per litre is exactly 0.005 mol L−1, which is 0.005 M. …
Method: Molarity from Mass Concentration
Concept first: Molarity (M) tells us the number of moles of solute per litre of solution.
We are given mass per litre (0.9 g L−1). To convert to moles per litre, we need the molar mass of glucose.
Steps
Step 1 — Find molar mass of glucose (C6H12O6)
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
Molar mass = 72+12+96=180 g mol−1
Step 2 — Convert mass concentration to molarity
Molarity (M) = molar mass (g/mol)mass per litre (g/L) …
Step 1: Understand what is being asked
We are given:
- Solute: glucose, C6H12O6
- Concentration: 0.9 g L−1 (mass per volume)
- We need: Molarity (moles per litre)
Molarity =volume of solution in litresmoles of solute
So the first step is to convert grams per litre into moles per litre.
Step 2: Calculate molar mass of glucose
Glucose: C6H12O6
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
Molar mass =72+12+96=180 g mol−1
Step 3: Convert given concentration to molarity
Given: 0.9 g L−1
Moles per litre =1800.9=0.005 mol L−1
So molarity =0.005 M
Correct answer: (iii) 0.005 M
Common Mistakes & How to Avoid Them
✗ Mistake 1: Confusing molality with molarity
- What students do: They try to use mass of solvent or density, which is not given.
- Why it’s wrong: Molarity uses volume of solution (given as 1 L here). Molality uses mass of solvent (in kg).
- How to avoid: Read the unit carefully — g L−1 is a mass/volume concentration, directly convertible to molarity.
✗ Mistake 2: Forgetting to convert grams to moles
- What students do: They take 0.9 g L−1 and think it’s already moles.
- Why it’s wrong: Molarity is moles per litre, not grams per litre.
- How to avoid: Always ask: “Is this in grams or moles?” If grams, divide by molar mass.
✗ Mistake 3: Incorrect molar mass of glucose
- What students do: Use C6H12O6 as 6+12+6=24 or forget to multiply atomic masses.
- Why it’s wrong: Each element’s atomic mass must be multiplied by its subscript.
- How to avoid: Write out the calculation step-by-step: 6×12=72, 12×1=12, 6×16=96, then sum.
✗ Mistake 4: Decimal error in division
- What students do: 0.9÷180=0.005 but they write 0.05 or 0.5.
- Why it’s wrong: Misplacing the decimal changes the answer by a factor of 10 or 100. …
- KEAM 2026Set eng-2026-04174 marksMCQQ.If 'c' is the molarity of a solution, 'm' the molality, M2 the molecular weight of the solute in a binary solution and 'ρ', is the density of the solution in g/cm3, then the relationship between molality 'm' and molarity 'c' is given by (A) m = c/[ρ-cM2/1000] mol kg−1 (B) m = 1000c/[ρ-cM2] mol kg−1 (C) m = cρ/[1+cM2/100] mol kg−1 (D) m = 1000c/ρmol kg−1 (E) m = 1000c/[1000ρ+cM2]
›Reveal solutionSolution
Convert molarity to molality by finding the mass of solvent in 1 L of solution; the result is m=1000ρ−cM21000c, identical to option (A).
Take exactly 1 litre (1000 cm3) of solution.
Mass of solution =volume×density=1000ρ g.
Moles of solute in 1 L =c (definition of molarity), so mass of solute =cM2 g.
Mass of solvent =(1000ρ−cM2) g =10001000ρ−cM2 kg. …
- KEAM 2026Set eng-2026-04194 marksMCQQ.What is the mass of ethanoic acid required to prepare 0.5 m solution containing 100 g of be water? (Molar mass of ethanoic acid = 60 g mol−1). (A) 3 g (B) 6 g (C) 0.3 g (D) 7.5 g (E) 2 g
›Reveal solutionSolution
A 0.5m solution in 100g water needs 0.05mol (3g) of ethanoic acid.
Molality =kg of solventmoles of solute. For 0.5m in 100g=0.100kg water:
n=0.5×0.100=0.05mol. …
- KEAM 2026Set eng-2026-04224 marksMCQQ.3.0 g of a salt of molecular weight 30 is dissolved in 250 mL of water. The molarity of the solution is (A) 0.1 M (B) 0.2 M (C) 0.3 M (D) 0.4 M (E) 0.5 M
›Reveal solutionSolution
Moles = mass/MW =3.0/30=0.1 mol in 0.25 L, so molarity =0.4 M.
n=30 g mol−13.0 g=0.1 mol …
- KEAM 2026Set pha-2026-0418F4 marksMCQQ.The molarity of an aqueous solution containing 0.4g of NaOH (molar mass=40g/mol) in 250mL of a solution is (A) 0.04M (B) 0.02M (C) 0.20M (D) 0.40M (E) 0.08M
›Reveal solutionSolution
0.4 g NaOH is 0.01 mol; in 0.250 L that is 0.04 M.
Reasoning
Moles of NaOH =40 g mol−10.4 g=0.01 mol.
Volume =250 mL=0.250 L. …
- KEAM 2025Set eng-2025-04234 marksMCQQ.The density of 3 M aqueous solution of a solute 'X' is 1.86 g mL−1. The molality of the solution is (Molar mass of solute 'X' is 120 g mol−1) (A) 3 m (B) 4 m (C) 2 m (D) 5 m (E) 1 m
›Reveal solutionSolution
The molality of the 3 M solution is 2 m.
Concept and Intuition
Molarity is per litre of solution; molality is per kilogram of solvent. Using the density to get the mass of 1 L of solution, subtracting the solute mass gives the solvent mass, from which molality follows.
Step-by-Step Solution
- Mass of 1 L solution = 1000 mL * 1.86 g/mL = 1860 g.
- Solute in 1 L (3 mol) = 3 * 120 = 360 g.
- Solvent mass = 1860 - 360 = 1500 g = 1.5 kg. …
- KEAM 2024Set eng-2024-06084 marksMCQQ.260 g of an aqueous solution contains 60 g of urea (Molar mass = 60 g mol−1). The molality of the solution is (A) 2m (B) 3m (C) 4m (D) 5m (E) 6m
›Reveal solutionSolution
Molality = moles of solute per kg of solvent. Here 1 mol urea in 0.2 kg water gives 5 m.
The number of moles of urea is
n=60 g mol−160 g=1 mol.
The solvent (water) mass is the total solution mass minus the solute mass:
260−60=200 g=0.2 kg. …
- KEAM 2024Set eng-2024-06084 marksMCQQ.The molarity of a solution containing 8 g of NaOH (Molar mass = 40 g mol−1) in 250 mL solution is (A) 0.8M (B) 0.4M (C) 0.2M (D) 0.5M (E) 0.6M
›Reveal solutionSolution
Molarity = moles of solute per litre of solution: 0.2 mol in 0.25 L gives 0.8 M.
The number of moles of NaOH is
n=40 g mol−18 g=0.2 mol.
The solution volume is 250 mL=0.25 L, so the molarity is …
- KEAM 2024Set eng-2024-06094 marksMCQQ.The molarity of sodium hydroxide in the solution prepared by dissolving 6 g in 600 mL of water is (molar mass of NaOH = 40 g mol−1) (A) 0.5 M (B) 0.4 M (C) 0.25 M (D) 0.1 M (E) 0.2 M
›Reveal solutionSolution
6 g NaOH is 0.15 mol; in 0.6 L this is 0.25 M.
Moles of NaOH:
n=406=0.15 mol.
Molarity: …
- KEAM 2024Set eng-2024-06094 marksMCQQ.The volume of ethanol required to prepare 3 L of 0.25 M aqueous solution is (density of ethanol= 0.36 kg L−1, molar mass = 60 g mol−1) (A) 125 mL (B) 25mL (C) 75mL (D) 50mL (E) 12.5mL
›Reveal solutionSolution
3 L of 0.25 M needs 0.75 mol=45 g ethanol; at density 360 gL−1 that is 125 mL.
Moles required:
n=M×V=0.25×3=0.75 mol.
Mass:
m=n×Mmolar=0.75×60=45 g. …
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