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Q.(i) Write the statement and significance of Heisenberg's uncertainty principle.

(2)
(ii) An electron in an atom can be located within a distance of 0.1 Angstrom. What is the uncertainty involved in the measurement of its velocity? (mass of electron = 9.1 x 10^-31 kg) (2)
Kerala DhseKerala DHSE Plus One Board 2025Subjective· 4mImportance★★★★★
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Uncertainty principle: cannot know position and momentum together (delta x . delta p >= h/4pi). With delta x = 0.1 A, delta v = h/(4 pi m delta x) = 5.79 x 10^6 m/s.

(i) Statement: It is impossible to measure simultaneously, with unlimited accuracy, both the position and the momentum (velocity) of a small moving particle such as an electron. Mathematically: delta x . delta p >= h/(4 pi), or delta x . delta v >= h/(4 pi m).

Significance: For microscopic particles the product of uncertainties is significant, so the electron cannot have a fixed orbit of exactly known radius and speed (as Bohr assumed); instead we speak of the probability of finding the electron in a region (orbital). For large (macroscopic) objects the uncertainty is negligibly small.

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