Q.A sphere of 0.047 kg aluminium is placed for sufficient time in a vessel containing boiling water, so that the sphere is at 100 ∘C. It is then immediately transferred to 0.14 kg copper calorimeter containing 0.25 kg water at 20 ∘C. The temperature of water rises and attains a steady state at 23 ∘C. Calculate the specific heat capacity of aluminium.
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What is Specific Heat Capacity?
Imagine you have two identical stoves, two identical pots, and you put 1 kg of water in one pot and 1 kg of iron in the other. You turn both stoves to the same flame. After 2 minutes, the iron is scorching hot — you can't touch it. The water is still lukewarm.
Why? Because different substances need different amounts of heat to raise their temperature by the same amount. That's the core idea behind specific heat capacity.
The Intuition
Think of heat as "energy currency" and temperature rise as "buying a degree." Some materials are "cheap" — a little heat buys a big temperature rise. Others are "expensive" — you need to spend a lot of heat to get even a small rise.
- Iron is cheap: a small heat input → large temperature jump.
- Water is expensive: a large heat input → small temperature jump.
This "expensiveness" is what we call specific heat capacity. It tells you how much heat energy is needed to raise the temperature of 1 kg of a substance by 1 °C (or 1 K).
The Precise Definition
c=mΔTQ
Where:
- c = specific heat capacity (J/kg·°C or J/kg·K)
- Q = heat energy supplied (J)
- m = mass of the substance (kg)
- ΔT = change in temperature (°C or K)
In words: Specific heat capacity is the amount of heat required to raise the temperature of one kilogram of a substance by one degree Celsius (or one Kelvin).
Key Points to Remember
-
It's a property of the material, not the object. A small iron nail and a giant iron beam have the same c value — but the beam needs more total heat because it has more mass.
-
Units matter. Common values:
- Water: c=4186 J/kg⋅°C (or ≈ 4200 J/kg·°C in many problems)
- Iron: c≈450 J/kg⋅°C
- Copper: c≈390 J/kg⋅°C
Notice water's value is about 10 times that of iron — that's why water heats up so slowly compared to metals.
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The formula works both ways. If a substance cools down, it releases the same amount of heat it would absorb to warm up by the same ΔT.
A Common Mistake to Avoid
Don't confuse specific heat capacity (c) with heat capacity (C). Heat capacity is for an entire object: C=mc. A large iron block can have a higher heat capacity than a small cup of water, even though iron's c is much smaller. Always check: are we talking about per kg or for the whole thing?
Worked Example (Exam-Style)
Problem: How much heat is needed to raise the temperature of 2 kg of water from 20 °C to 50 °C? (Take cwater=4200 J/kg⋅°C)
Solution:
- m=2 kg
- ΔT=50−20=30 °C
- c=4200 J/kg⋅°C
Q=mcΔT=2×4200×30=252000 J=252 kJ
Answer: 252 kJ of heat is required.
Why This Matters …
Heat lost by the hot aluminium sphere equals heat gained by the water plus the copper calorimeter.
mAl=0.047 kg cools 100°C→23°C (ΔTAl=77 K). Water (mw=0.25 kg, sw=4.18×103) and copper calorimeter (mCu=0.14 kg, sCu=0.386×103) both warm by ΔTw=3 K:
0.047cAl(77)=(0.25×4180+0.14×386)(3)=1099.04×3=3297.12. …
Using the principle of calorimetry (heat lost by the hot aluminium = heat gained by the water and the copper calorimeter), the specific heat capacity of aluminium works out to about 913 J kg−1K−1.
When the hot aluminium sphere is dropped into the cooler water-filled calorimeter, heat flows from the sphere until everything reaches the same final temperature. No heat is assumed lost to the surroundings, so:
Heat lost by aluminium=Heat gained by water+Heat gained by the copper calorimeter.
Setting up the numbers
- Aluminium: mAl=0.047 kg, cools from 100∘C to 23∘C, so ΔTAl=77 K.
- Water: mw=0.25 kg, warms from 20∘C to 23∘C, so ΔTw=3 K; cw=4186 J kg−1K−1.
- Copper calorimeter: mCu=0.14 kg, also warms by 3 K; cCu≈390 J kg−1K−1.
Heat balance
mAlcAlΔTAl=(mwcw+mCucCu)ΔTw
0.047×cAl×77=(0.25×4186+0.14×390)×3
Compute the right-hand side:
0.25×4186=1046.5,0.14×390=54.6,sum=1101.1. …
A cleaner way to organize the calculation is to lump the water and calorimeter into a single effective heat capacity, since both undergo the same 3 K rise: Ceff=mwcw+mCucCu=(0.25)(4186)+(0.14)(390)≈1101 J/K. The heat balance then collapses to one line, mAlcAlΔTAl=CeffΔTw, instead of tracking water and copper as two separate additive terms throughout. As a sanity check, the recovered value $ …
- KEAM 2026Set eng-2026-04184 marksMCQQ.The heat required to convert 2 kg of ice at -10° C to water at 10° C at standard atmospheric pressure is (specific heat capacity of ice = 2100Jkg−1 K−1 specific heat capacity of water = 4200Jkg−1 K−1 Latent heat of fusion of ice = 3.35×105 Jkg−1) (A) 210 kJ (B) 335 kJ (C) 398 kJ (D) 420 kJ (E) 796 kJ
›Reveal solutionSolution
Sum the three stages: warm ice to 0∘C (42 kJ), melt (670 kJ), warm water to 10∘C (84 kJ) =796 kJ.
For m=2 kg:
Warm ice −10∘→0∘C: mciceΔT=2×2100×10=42000 J.
Melt ice: mL=2×3.35×105=670000 J. …
- KEAM 2026Set eng-2026-04204 marksMCQQ.Two different liquids of having same mass at temperatures T1 and T2 and of specific heat capacities, S and 1.2S, respectively, are mixed in an insulated system. If T1>T2, then the temperature of the mixture is (A) 115T1+6T2 (B) 116T1+5T2 (C) T1+T2 (D) T1−T2 (E) 2T1+T2
›Reveal solutionSolution
Equate heat lost by the hotter liquid to heat gained by the cooler; solve the mixture temperature.
With equal masses m and specific heats S and 1.2S, the equilibrium temperature T satisfies energy conservation (weighted average): …
- KEAM 2026Set pha-2026-0418F4 marksMCQQ.If Cv is the specific heat capacity at constant volume of a gas, then the amount of heat required to increase the temperature of 2 moles of the gas from 27 0C to 127 0C at constant volume is (A) 100Cv (B) 50Cv (C) 500Cv (D) 300Cv (E) 200Cv
›Reveal solutionSolution
Q=nCvΔT=2×Cv×100=200Cv.
Heat added at constant volume is Q=nCvΔT. The temperature change ΔT=127∘C−27∘C=100K (a Celsius interval equals the same Kelvin interval) …
- KEAM 2025Set eng-2025-04254 marksMCQQ.The amount of heat to be withdrawn from 3 kg of water at 0∘C to obtain 3 kg of ice at 0∘C in an icemaker is (latent heat of fusion of ice is 80 kcal/kg) (A) 400 kcal (B) 160 kcal (C) 320 kcal (D) 80 kcal (E) 240 kcal
›Reveal solutionSolution
Converting water at 0∘C to ice at 0∘C removes only the latent heat of fusion: Q=mL=3×80=240 kcal.
Since both the water and the ice are at the same temperature (0∘C), no sensible heat is involved — only the latent heat of solidification is withdrawn. …
- KEAM 2025Set eng-2025-04264 marksMCQQ.Specific heat capacity of a substance depends on the (A) material of the substance only (B) volume of the substance only (C) mass of the substance only (D) material and temperature of the substance (E) mass and volume of the substance
›Reveal solutionSolution
Specific heat capacity is defined per unit mass, so it is independent of the amount of substance; it depends on what the substance is (material) and on its temperature.
Reasoning. Specific heat c=mΔTQ is heat per unit mass per unit temperature rise, so mass and volume cancel out — they do not determine c. …
- KEAM 2024Set eng-2024-06064 marksMCQQ.1 g of ice at 0 °C is converted into water by supplying a heat of 418.72 J. The quantity of heat that is used to increase the temperature of water from 0∘C is (Latent heat of fusion of ice =3.35×105 Jkg−1) (A) 83.72 J (B) 33.52 J (C) 335.72 J (D) 837.24 J (E) 418.72 J
›Reveal solutionSolution
Subtract the latent heat of fusion from the total heat; the remainder raises the water's temperature.
Heat needed to melt 1 g of ice at 0 °C:
Qfusion=mL=(1×10−3 kg)(3.35×105 J kg−1)=335 J.
Of the 418.72 J supplied, this melts the ice, leaving …
- KEAM 2024Set pha-2024-06104 marksMCQQ.When two different liquids of same mass but at two different temperatures $27^\circ C$ and $47^\circ C$ are mixed together, the resulting temperature of the mixture is $35^\circ C$. The ratio of their specific heat capacities is (A) 1 : 3 (B) 5 : 3 (C) 3 : 2 (D) 4 : 1 (E) 2 : 7
›Reveal solutionSolution
Heat gained by cooler liquid = heat lost by hotter liquid.
Mixture temperature 35∘C lies between 27∘C and 47∘C. Equal masses m:
mc1(35−27)=mc2(47−35) …
- KEAM 2023Set eng-2023-P1-A14 marksMCQQ.A metallic bullet with an initial velocity of 500 m/s penetrates a solid object and melts. The initial temperature of the bullet is 30∘C and its melting point is 280∘C. The ratio of total heat generated to the initial kinetic energy of the bullet will be: [Latent heat of fusion of metal =3.0×104 J/kg and specific heat capacity of metal =200 J/kg-K] (A) 0.5 (B) 1.0 (C) 0.81 (D) 0.36 (E) 0.64
›Reveal solutionSolution
The ratio of heat generated (to just melt the bullet) to its initial KE is 0.64.
Concept and Intuition
The bullet's kinetic energy is converted to heat. The heat needed to melt it is the sensible heat to reach the melting point plus the latent heat of fusion; comparing this to the initial KE per unit mass gives the ratio.
Step-by-Step Solution
- Initial KE per unit mass =21v2=21(500)2=1.25×105 J/kg.
- Heat to melt per unit mass =cΔT+L=200(280−30)+3.0×104=5.0×104+3.0×104=8.0×104 J/kg. …
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