Q.If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
Concept understanding — Faradays Laws Electrolysis
Faraday's Laws of Electrolysis
Imagine you're trying to plate a copper spoon with silver. You drop the spoon into a solution containing silver ions, connect it to a battery, and wait. How much silver actually deposits? Does it depend on how long you wait? On how strong the battery is? On what metal you're using?
Faraday's laws answer exactly these questions. They connect the invisible world of electrons flowing through a wire to the visible world of atoms depositing on a surface.
The Intuition First
Think of electrolysis as a counting problem. Each silver ion (Ag+) needs exactly one electron to become a neutral silver atom (Ag). So if you push a certain number of electrons through the circuit, you should get exactly that many silver atoms deposited.
The first law says: more charge → more mass deposited. Double the charge, double the mass. It's a direct proportionality.
The second law says: different elements need different amounts of charge per atom. A copper ion (Cu2+) needs two electrons to become neutral copper, so for the same amount of charge, you get half as many copper atoms as silver atoms.
The Precise Statements
First Law: The mass of a substance liberated at an electrode is directly proportional to the quantity of electric charge passed through the electrolyte.
m∝Qorm=ZQ
where Z is the electrochemical equivalent of the substance.
Second Law: When the same quantity of charge is passed through different electrolytes, the masses of substances liberated are proportional to their chemical equivalents (equivalent weights).
E1m1=E2m2
Here E is the equivalent weight: atomic mass divided by the number of electrons transferred per ion (n). For silver (Ag+, n=1), E=107.87 g. For copper (Cu2+, n=2), E=63.55/2=31.77 g.
The Combined Law
These two laws merge into one powerful equation:
m=FQ×E
where F is Faraday's constant — the charge carried by one mole of electrons: F=96485 coulombs per mole.
Since Q=I×t (current × time), you can write:
m=FI×t×E
This is the working formula for every electrolysis calculation in your exams.
To avoid confusion: equivalent weight E is always atomic mass divided by n (the number of electrons gained or lost per ion). For Al3+, n=3; for O2 gas (from water), each oxygen atom loses 2 electrons, but the molecule has 2 atoms, so n=4 per O2 molecule.
A Worked Example
Problem: How much copper deposits when a current of 2.0 A flows through a copper sulfate solution for 30 minutes? (Atomic mass of Cu = 63.5 g/mol, n=2)
Step 1: Find the equivalent weight.
E=263.5=31.75 g/mol
Step 2: Find total charge.
Q=I×t=2.0×(30×60)=3600 C
Step 3: Apply the combined law.
m=FQ×E=964853600×31.75=1.185 g
So about 1.2 grams of copper deposits.
A common mistake: forgetting to convert time to seconds. If time is given in minutes, multiply by 60. If in hours, multiply by 3600.
Why This Matters
Faraday's laws are not just exam problems. They govern:
- Electroplating (jewellery, car bumpers)
- Metal refining (pure copper from ore)
- Electrolysis of water (hydrogen fuel)
- Battery charging and discharging
Every time you charge a phone battery, Faraday's laws determine how much lithium moves from one electrode to the other.
The Big Picture
Faraday discovered these laws in 1834, decades before anyone knew about electrons. He measured charge and mass, and found the relationship. Today we understand it as simple counting: each electron carries a fixed charge (1.6×10−19 C), and each ion needs a fixed number of electrons. The laws are just conservation of charge and conservation of mass, written in a practical form.
Final takeaway: m=FItE — memorize it, understand it, and you can solve any electrolysis problem.
Faraday's laws of electrolysis are a numerical-heavy part of the NCERT/CBSE Class 12 Chemistry Electrochemistry chapter, and ‘Faraday's laws of electrolysis formula’ or ‘Faraday's laws numericals class 12’ are frequent important-question searches for board exams as well as JEE Main and NEET. These laws also form the quantitative basis for many electroplating and metal-extraction questions in competitive exams.
Why this formula?
Faraday's Laws of Electrolysis: Why the Formulas Hold
Faraday's Laws of Electrolysis describe the quantitative relationship between the amount of electricity passed through an electrolyte and the mass of substance liberated at the electrodes. Let's build the reasoning step-by-step.
1. The Core Idea: Charge Carries Matter
Electrolysis works because ions (charged particles) move toward electrodes and undergo redox reactions.
- At the cathode (negative electrode), cations gain electrons (reduction).
- At the anode (positive electrode), anions lose electrons (oxidation).
The key insight: Each ion that reacts carries a fixed amount of charge.
- For a monovalent ion (e.g., Na+), charge = 1.602×10−19C (the elementary charge e).
- For a divalent ion (e.g., Cu2+), charge = 2e.
Thus, the total charge passed (Q) is directly proportional to the number of ions that have reacted (N):
Q=N⋅ze
where:
- z = valency (number of electrons transferred per ion)
- e = elementary charge (1.602×10−19C)
2. From Number of Ions to Mass
The number of ions N is related to the mass (m) of substance liberated via Avogadro's number (NA) and molar mass (M):
N=Mm⋅NA
Substitute into Q=Nze:
Q=(Mm⋅NA)⋅ze
3. Introducing Faraday's Constant
The product NAe appears repeatedly — it's called Faraday's constant (F):
F=NAe≈96485C mol−1
So:
Q=Mm⋅zF
Rearrange for mass:
m=zFQM
This is the unified formula for both of Faraday's laws.
4. Why Two "Laws"? — They Are the Same Idea
Faraday originally stated two laws, but they are logical consequences of the same charge–mass relationship:
First Law (Direct Proportionality)
Mass liberated is directly proportional to the charge passed.
From m=zFQM, if M, z, and F are constant, then:
m∝Q
Why? Because each ion needs a fixed charge to react — more charge means more ions, hence more mass.
Second Law (Electrochemical Equivalent)
For the same charge, masses liberated are proportional to equivalent weights.
Equivalent weight E=zM (mass per mole of electrons transferred).
From m=FQ⋅zM=FQ⋅E, if Q is fixed:
m∝E
Why? For the same charge, the number of electrons transferred is fixed. A substance with a smaller z (fewer electrons per ion) will liberate more moles of substance, hence more mass per mole.
5. Practical Formula for Exams
In numerical problems, you often use:
m=FZItorm=FEIt
where:
- I = current (A), t = time (s), so Q=It
- Z=zFM = electrochemical equivalent (mass per coulomb)
- E=zM = equivalent weight
Example: For copper deposition (Cu2++2e−→Cu):
- z=2, M=63.5g/mol
- E=263.5=31.75g/eq
- F=96500C/mol
If I=2A for 30 minutes (t=1800s):
m=9650031.75×2×1800≈1.185g
6. Key Takeaways
| Concept | Why It Holds |
|---|---|
| m∝Q | Each ion needs a fixed charge ze to react |
| m∝E | Same charge → same number of electrons → more mass if z is smaller |
| F=NAe | Connects microscopic charge (e) to macroscopic charge per mole |
Remember: The formula m=zFQM is derived from charge quantization — it's not arbitrary. Every electrolysis problem reduces to counting electrons.
Need to apply this to a specific problem? Let me know the context — I'll walk through the reasoning step by step.
The key idea is that electric current is the flow of charge, and the total charge is quantised in units of the electron charge.
Step 1 – Total charge passed
Current I=0.5 A, time t=2 hours=2×3600=7200 s.
Charge Q=I×t=0.5×7200=3600 C.
Step 2 – Charge per electron
Charge on one electron e=1.6×10−19 C.
Step 3 – Number of electrons
Number n=eQ=1.6×10−193600=2.25×1022.
The number of electrons that flow through the wire is 2.25×1022.
The total charge passing through the wire is found using Q=I×t, then divided by the charge per electron (1.6×10−19C) to get the number of electrons. The answer is 2.25×1022 electrons.
This is a straightforward application of the relation between current, charge, and time — a fundamental idea in electricity. Current is simply the rate of flow of charge: I=tQ. So if you know how much current flows and for how long, you can find the total charge that has passed. Then, since each electron carries a fixed amount of charge (the elementary charge e), dividing the total charge by e gives the number of electrons.
Let’s work it out step by step.
-
Convert time to seconds.
The current is given in amperes (coulombs per second), so time must be in seconds.
t=2hours=2×60×60=7200s.
-
Calculate total charge Q.
Using Q=I×t:
Q=0.5A×7200s=3600C.
-
Recall the charge of one electron.
The elementary charge e=1.6×10−19C (this is a standard value you must remember for exams).
-
Find the number of electrons n.
n=eQ=1.6×10−193600.
Compute:
1.63600=2250, and 2250×1019=2.25×1022.
A common mistake is to forget converting hours to seconds. If you use t=2 directly, you get Q=1C and n≈6.25×1018 — which is wrong by a factor of 3600. Always check units: current in amperes means time in seconds.
You can also think of this as: 1 ampere for 1 second gives 1 coulomb, which contains about 6.25×1018 electrons. Here, 0.5 A for 7200 s gives 0.5×7200=3600 times that many electrons — a quick mental check.
The number of electrons that flow through the wire is 2.25×1022.
Method: Direct Charge-Quantization Approach
This method uses the fundamental relation between current, time, and the quantized nature of electric charge.
Step 1: Find total charge (Q) that flows
Current is charge per unit time:
I=tQ
So:
Q=I×t
Given:
- I=0.5A
- t=2hours=2×3600=7200s
Q=0.5×7200=3600C
Total charge flowing = 3600 C
Step 2: Use charge quantization to find number of electrons
Every electron carries a charge of:
e=1.6×10−19C
If n is the number of electrons:
Q=n×e
So:
n=eQ=1.6×10−193600
n=2.25×1022
Final Answer
Number of electrons = 2.25×1022
Key Concept Reminder
- Faraday’s laws deal with electrolysis (chemical change due to current).
- This problem is purely electrical — it uses the quantization of charge (charge is always an integer multiple of e).
- The formula Q=ne is the bridge between macroscopic current and microscopic particle count.
Here are the most common mistakes students make on this Faraday’s Laws / Electrolysis type question, along with how to avoid each.
Mistake 1: Forgetting to convert time to seconds
The mistake:
Students directly use time in hours in the formula Q=I×t, getting a wildly wrong charge.
Why it happens:
The formula Q=It requires time in seconds (SI unit), but the problem gives time in hours.
How to avoid:
Always convert hours → minutes → seconds:
t=2 hours=2×60×60=7200 s.
Correct step:
Q=0.5×7200=3600 C.
Mistake 2: Using the wrong value of Faraday constant or electronic charge
The mistake:
Some students use F=96500 C/mol directly without linking it to the number of electrons.
Why it happens:
They confuse the charge per mole of electrons (Faraday) with the charge on a single electron.
How to avoid:
Remember:
- Charge on one electron = e=1.6×10−19 C
- Number of electrons n=eQ
Correct step:
n=1.6×10−193600=2.25×1022 electrons.
Mistake 3: Mixing up Faraday’s laws for electrolysis with this simple current flow
The mistake:
Students try to use m=FZIt or involve molar mass, thinking it’s an electrolysis cell.
Why it happens:
The problem mentions “metallic wire” — it’s not an electrolytic cell. It’s just conduction through a metal.
How to avoid:
- Metallic wire → electrons flow directly. Use Q=It and n=Q/e.
- Electrolytic cell → ions carry charge. Use Faraday’s laws.
Mistake 4: Incorrect handling of powers of 10 in division
The mistake:
Students miscalculate 3600÷(1.6×10−19) and get 2.25×1017 or 2.25×1021.
Why it happens:
Dividing by 10−19 means multiplying by 1019, but they forget to adjust the exponent correctly.
How to avoid:
Write it step-by-step:
1.6×10−193600=1.63600×1019=2250×1019=2.25×1022.
Mistake 5: Not writing the final answer in scientific notation
The mistake:
Leaving the answer as 22500000000000000000000 or rounding incorrectly.
Why it happens:
They don’t convert to standard form.
How to avoid:
Always express large numbers as a×10b where 1≤a<10.
Final answer:
2.25×1022 electrons
Quick checklist to avoid all mistakes:
| Step | Action |
|---|---|
| 1 | Convert time to seconds |
| 2 | Use Q=I×t |
| 3 | Use n=Q/e (not Faraday’s constant) |
| 4 | Divide carefully with powers of 10 |
| 5 | Write answer in scientific notation |
- KEAM 2026Set eng-2026-04184 marksMCQQ.What volume of O2(g) is produced when 2F current is passed through a very dilute aqueous solution of H2SO4 at STP? (A) 36 dm3 (B) 48.6 dm3 (C) 22.4 dm3 (D) 11.2 dm3 (E) 6 dm3
›Reveal solutionSolution
Oxygen evolution needs 4 F per mole; 2 F therefore gives 0.5 mol O2=11.2dm3 at STP.
At the anode during electrolysis of dilute H2SO4 (effectively water):
2H2O→O2+4H++4e−
So 4F of charge liberates 1molO2. For 2F:
n(O2)=42=0.5mol
Volume at STP:
V=0.5×22.4=11.2dm3
✓Final answerThe correct option is (D).
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