Q.a) Match the items of Column I with items of Column II.
Column I: i) Aluminium ii) Iron iii) Copper iv) Zinc
Column II: a) Malachite b) Bauxite c) Limestone d) Haematite e) Calamine
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Start your 14-day free trial to unlock the full solution →Aluminium's chief ore is bauxite, iron's is haematite, copper's is malachite, and zinc's is calamine. In an Ellingham diagram, a metal turning liquid during reduction gives a large increase in entropy, which makes the free-energy change more negative and favours reduction.
a) Matching ores to metals
i) Aluminium — b) Bauxite (Al2O3·2H2O)
ii) Iron — d) Haematite (Fe2O3)
iii) Copper — a) Malachite (CuCO3·Cu(OH)2)
iv) Zinc — e) Calamine (ZnCO3)
(Limestone, item 'c', is not an ore of any of these four metals — it is used as a flux in metallurgy, e.g. in the blast furnace, so it is left unmatched.)
b) Why reduction is easier when the metal formed is liquid
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