Chemistry · Ch 11 — Adsorption and Colloids
Examples of Adsorption
Examples of Adsorption
The book draws a first contrast with absorption before giving worked examples of adsorption itself: when cotton is dipped in water, the cotton becomes wet because water penetrates into the bulk of the fibres -- that is absorption, not adsorption, since the water is not merely sitting on the cotton's surface. (The printed heading for this section is worth flagging: it reads 'Examples of Absorption', but the numbered list underneath it -- and the reference to Table 11.1 that follows -- is entirely about adsorption examples, so this appears to be a heading/labelling slip in the source rather than a deliberate mismatch; this platform has kept the substance of the list, which is unambiguously about adsorption.) Three worked examples of adsorption are given: (i) gases like hydrogen and oxygen being adsorbed by finely divided metals such as platinum, palladium, copper and nickel; (ii) gases like nitrogen and carbon dioxide being adsorbed by activated charcoal; and (iii) removal of colouring matter, such as the organic dye methylene blue, from solution -- when charcoal is added to a methylene blue solution and shaken, the s …
- Adsorbed matter is concentrated only at the surface and does not penetrate through to the bulk of the adsorbent -- adsorption is a surface phenomenon. | Absorbed matter is distributed uniformly throughout the bulk as well as the surface of the substance -- absorption is a bulk phenomenon.
- Concentration of the adsorbate is high only at the surface of the adsorbent. | Concentration of the absorbate is uniform throughout the bulk of the absorbent.
- Adsorption is dependent on temperature and pressure. | Absorption is independent of temperature and pressure.
- Adsorption is accompanied by evolution of heat, known as heat of adsorption. | Absorption is not accompanied by evolution or absorption of heat.
- Adsorption depends on surface area. | Absorption is independent of surface area. …