Chemistry · Ch 14 — Basic Principles of Organic Chemistry
Classification of organic compounds
Classification of organic compounds
With so many different organic structures to keep track of, chemists needed a systematic way to relate a molecule's structure to its chemical behaviour -- and that need is exactly what motivates classifying organic compounds in the first place. The book sets out two broad, independent classification schemes, developed one at a time in the two sections that follow: classification by CARBON SKELETON (the pattern in which the molecule's carbon atoms are themselves connected to one another -- open chains versus rings, and so on) and classification by FUNCTIONAL GROUP (which particular reactive group of atoms the molecule carries, regardless of how its carbon skeleton happens to be arranged). Before developing either scheme in detail, it is worth noting that chemists also build and use physical or computer-graphic MODELS of organic molecules to visualise their true three-dimensional shape more directly than any flat 2-D formula can -- a framework (skeletal) model that shows only the pattern of bonds and ignores atomic size, a ball-and-stick model that shows both connectivi …
What this figure shows. Three common physical/graphical ways of modelling a 3-D organic molecule, shown side by side: (a) the framework (skeletal) model, which emphasises only the pattern of bonds and ignores the actual size of the atoms; (b) the ball-and-stick model, in which each atom is shown as a small ball and each bond as a connecting stick, giving a clearer sense of both connectivity and approximate bond angles/geometry; (c) the space-filling model, which emphasises the true relative size of each atom (drawn as large overlapping spheres) and conveys the actual volume the molecule occupies, at the cost of making individual bonds hard to see. The text notes that computer graphics are now c …