Chemistry · Ch 5 — Chemical Bonding
Ionic bond
Ionic bond
An ionic (or electrovalent) bond forms when one atom transfers one or more valence electrons completely to another atom, and the resulting oppositely-charged ions are then held together purely by electrostatic (coulombic) attraction. In sodium chloride, sodium (, configuration ) has only one electron in its outer shell and readily loses it to reach neon's stable configuration; chlorine (, configuration ) has seven outer electrons and readily gains one to reach argon's stable configuration. The transfer converts neutral Na into Na⊕ and neutral Cl into Cl⊖, and the resulting electrostatic attraction between these ions is the ionic bond in Na⊕Cl⊖ (NaCl). The same idea extends to ions of different charge, as in calcium chloride: calcium (configuration ) has two valence electrons to lose and transfers one each to two separate chlorine atoms, giving Ca²⊕ plus two Cl⊖ ions, written Ca²⊕(Cl⊖)₂ or CaCl₂. In general, an element with a LOW ionisation entha …
What this figure shows. Na (Z=11, configuration 2,8,1) has one lone electron in its valence shell and loses it to reach Ne's stable configuration (2,8); Cl (Z=17, configuration 2,8,7) has seven valence electrons and gains the one electron Na loses, reaching Ar's stable configuration (2,8,8). The transfer converts the neutral atoms into Na⊕ (configuration 2,8) and Cl⊖ (configuration 2,8,8), and the two oppositely charged ions are then held together by a strong electrostatic force of attraction, wr …
What this figure shows. Ca (configuration 2,8,8,2) has two valence electrons and loses both, one to each of two separate Cl atoms (each configuration 2,8,7), to become Ca²⊕ (configuration 2,8,8). Each Cl atom that gains an electron becomes Cl⊖ (configuration 2,8,8). The resulting formula unit is written Ca²⊕(Cl⊖)2, i.e. CaCl2, with one doubly-charged calcium cation electrostatically bonded to two singly-ch …