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Chemistry · Ch 5 — Chemical Bonding

Ionic bond

5.2.1

Ionic bond

An ionic (or electrovalent) bond forms when one atom transfers one or more valence electrons completely to another atom, and the resulting oppositely-charged ions are then held together purely by electrostatic (coulombic) attraction. In sodium chloride, sodium (Z=11Z=11, configuration 2,8,12,8,1) has only one electron in its outer shell and readily loses it to reach neon's stable 2,82,8 configuration; chlorine (Z=17Z=17, configuration 2,8,72,8,7) has seven outer electrons and readily gains one to reach argon's stable 2,8,82,8,8 configuration. The transfer converts neutral Na into Na⊕ and neutral Cl into Cl⊖, and the resulting electrostatic attraction between these ions is the ionic bond in Na⊕Cl⊖ (NaCl). The same idea extends to ions of different charge, as in calcium chloride: calcium (configuration 2,8,8,22,8,8,2) has two valence electrons to lose and transfers one each to two separate chlorine atoms, giving Ca²⊕ plus two Cl⊖ ions, written Ca²⊕(Cl⊖)₂ or CaCl₂. In general, an element with a LOW ionisation entha …

Figure 5.2.1-aFormation of sodium chloride (NaCl)

What this figure shows. Na (Z=11, configuration 2,8,1) has one lone electron in its valence shell and loses it to reach Ne's stable configuration (2,8); Cl (Z=17, configuration 2,8,7) has seven valence electrons and gains the one electron Na loses, reaching Ar's stable configuration (2,8,8). The transfer converts the neutral atoms into Na⊕ (configuration 2,8) and Cl⊖ (configuration 2,8,8), and the two oppositely charged ions are then held together by a strong electrostatic force of attraction, wr …

Figure 5.2.1-bFormation of calcium chloride (CaCl2)

What this figure shows. Ca (configuration 2,8,8,2) has two valence electrons and loses both, one to each of two separate Cl atoms (each configuration 2,8,7), to become Ca²⊕ (configuration 2,8,8). Each Cl atom that gains an electron becomes Cl⊖ (configuration 2,8,8). The resulting formula unit is written Ca²⊕(Cl⊖)2, i.e. CaCl2, with one doubly-charged calcium cation electrostatically bonded to two singly-ch …