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Chemistry · Ch 2 — Introduction to Analytical Chemistry

Rules for deciding significant figures

2.3.4

Rules for deciding significant figures

Deciding how many digits in a written number are 'significant' — that is, meaningfully measured rather than just placeholders — follows five rules. First, every non-zero digit in a number is significant; for example, 127.34 g has five significant figures (1, 2, 7, 3 and 4). Second, any zero sandwiched between two non-zero digits is significant; for example, 120.007 m has six significant figures. Third, zeros to the left of the first non-zero digit are never significant, because their only job is to fix the position of the decimal point rather than to record a measured value; for example, 0.025 has just two significant figures (2 and 5), and 0.005 has just one (5). Fourth, zeros at the very end of a number ARE significant if they sit to the right of the decimal point, because a decimal point in a measurement signals a genuinely finer least count of the instrument that produced it; but terminal zeros in a number with no decimal point shown are NOT taken as significant. For example, 0.400 g has three significant figures, since it implies the value was read on a balance with a least count of 0.001 g; but plain 400 g has only one significant figure, while 4.0×1024.0 \times 10^2 g (two significant figures) and 4.00×1024.00 \times 10^2 g (three significant figures) show how scientific notation is used to state the intended precision unambiguously, corresponding to instrument least counts of 1 g, 0.1 g and 0.01 g respectively. Fifth, in a number already written in scientific notation, every digit of the coefficient counts as significant; for example, 2.035×1022.035 \times 10^2 has four significant figures, a …

Table 2.1The five significant-figure rules with examples

Rule 1 — All non-zero digits are significant. Example: 127.34 g has five significant figures (1, 2, 7, 3, 4).

Rule 2 — All zeros between two non-zero digits are significant. Example: 120.007 m has six significant figures.

Rule 3 — Zeros to the left of the first non-zero digit are NOT significant; such a zero only fixes the position of the decimal point. Example: 0.025 has two significant figures; 0.005 has one significant figure.

Rule 4 — Zeros at the end of a number ARE significant if they are to the right of the decimal point (this is because the instrument's least count itself contains a decimal point). Terminal zeros with no decimal point shown are NOT significant. Example: 0.400 g has three significant figures (measured on a balance of least count 0.001 g); plain 400 g has one significant figure; 4.0×1024.0 \times 10^2 g has two significant figures; 4.00×1024.00 \times 10^2 g has three significant figures — the zeros after the decimal point each signal a finer least count (1 g, 0.1 g and 0.01 g respectively). …