Chemistry · Ch 10 — States of Matter
Viscosity
Viscosity
Viscosity measures the internal friction within a flowing liquid -- how strongly its layers resist sliding past one another. When a liquid flows through a tube in an orderly, layer-by-layer way (laminar flow), the layer touching the tube's inner wall is essentially stationary due to friction, while the central layer, furthest from the wall, moves fastest; this sets up a velocity gradient across the tube's cross-section. Strong intermolecular forces resist the layers slipping past each other, producing friction between the layers -- this internal friction is viscosity, formally defined via the coefficient of viscosity (eta): the tangential frictional force per unit area, per unit velocity gradient, needed to keep the flow laminar. Its SI unit is N s m; the older CGS unit is the poise, where poise g cm s kg m s. Viscosity is temperature-dependent, roughly -- it falls as temperature rises, because increased thermal motion partly overcomes the intermolecular attraction resisting flow. Viscosity also depends on molecular size and shape: larger molecules are generally more viscous, while more compact, spherical molecules offer less resistance to flow and are therefore less viscous than long, spread-out ones of similar mass; the greater a liquid's viscosity, the more slowly it flows. Practical illustrations include the grading of lubricating oils by viscosity (a good lubricant keeps a steady viscosity across a temperature range), raised blood viscosity as a marker of car …
What this figure shows. A cross-section of a cylindrical tube/pipe with liquid flowing through it, drawn with several concentric flow-velocity arrows of different lengths: the arrow right against the tube's inner wall is essentially zero length (stationary layer), the arrows grow progressively longer moving inward, and the longest arrow is at the very centre of the tube (fastest-moving layer) -- illustrating the velocity gradient set up across the tube's cross-section by viscosity, with the outer layers dragged back by friction against the stationary wall layer and the cen …