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Physics · Ch 7 — Thermal Properties of Matter

Ideal Gas Equation

7.4.2

Ideal Gas Equation

The relationship among a gas's pressure, volume and (absolute) temperature is called the ideal gas equation. Using absolute temperature, the classical gas laws take particularly simple forms:

Charles' law: at constant pressure, the volume-temperature graph (Fig. 7.2(b)) passes exactly through the origin if temperature is measured on the Kelvin scale, so V∝TV \propto T, i.e. V/T=constantV/T = \text{constant} --- (7.4). In words: the volume of a fixed mass of gas is directly proportional to its absolute temperature, at constant pressure.

Pressure law (Gay Lussac's law): similarly, P∝TP \propto T, i.e. P/T=constantP/T = \text{constant} --- (7.5) -- the pressure of a fixed mass of gas is directly proportional to its absolute temperature, at constant volume.

Boyle's law: at constant temperature, pressure and volume of a fixed mass of gas are inversely proportional, P∝1/VP \propto 1/V, i.e. PV=constantPV = \text{constant} --- (7.6). …

Misc Ex.7Pressure reading at the triple point from the steam-point reading

Worked out. A constant-volume gas thermometer reads pressure P = 1.367x10^3 Pa at the steam point (373.15 K); using the linear relationship between pressure and absolute temperature, P_triple/P = 273.16/T, the example scales this reading down to find the pressure the same thermometer would read at the triple point of water (273.16 K), getting P_triple = 1.000x10^3 Pa. …