Physics · Ch 7 — Thermal Properties of Matter
Ideal Gas Equation
Ideal Gas Equation
The relationship among a gas's pressure, volume and (absolute) temperature is called the ideal gas equation. Using absolute temperature, the classical gas laws take particularly simple forms:
Charles' law: at constant pressure, the volume-temperature graph (Fig. 7.2(b)) passes exactly through the origin if temperature is measured on the Kelvin scale, so , i.e. --- (7.4). In words: the volume of a fixed mass of gas is directly proportional to its absolute temperature, at constant pressure.
Pressure law (Gay Lussac's law): similarly, , i.e. --- (7.5) -- the pressure of a fixed mass of gas is directly proportional to its absolute temperature, at constant volume.
Boyle's law: at constant temperature, pressure and volume of a fixed mass of gas are inversely proportional, , i.e. --- (7.6). …
Worked out. A constant-volume gas thermometer reads pressure P = 1.367x10^3 Pa at the steam point (373.15 K); using the linear relationship between pressure and absolute temperature, P_triple/P = 273.16/T, the example scales this reading down to find the pressure the same thermometer would read at the triple point of water (273.16 K), getting P_triple = 1.000x10^3 Pa. …