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Physics · Ch 7 — Thermal Properties of Matter

Relation between Coefficients of Expansion

7.5.4

Relation between Coefficients of Expansion

Because α\alpha, β\beta and γ\gamma all describe the same underlying phenomenon (the same linear stretching of interatomic spacing) viewed along one, two, or three dimensions respectively, they are not independent -- they are fixed multiples of each other.

Relation between β\beta and α\alpha: consider a square plate of side l0l_0 at 0 °C, becoming lTl_T at T °CT\,°\text{C}, so lT=l0(1+αT)l_T = l_0(1+\alpha T) from Eq. (7.11). Its area at 0 °C is A0=l02A_0 = l_0^2, and at T °CT\,°\text{C}, AT=lT2=l02(1+αT)2=A0(1+αT)2A_T = l_T^2 = l_0^2(1+\alpha T)^2 = A_0(1+\alpha T)^2 --- (7.19). But also, directly from the areal-expansion definition, AT=A0(1+βT)A_T = A_0(1+\beta T) --- (7.20). Equating the two and expanding: 1+2αT+α2T2=1+βT1 + 2\alpha T + \alpha^2 T^2 = 1 + \beta T. Since α\alpha is very small, the α2T2\alpha^2T^2 term is negligible, leaving

β=2α— (7.21)\beta = 2\alpha \quad \text{--- (7.21)}

This holds generally, since any flat solid can be thought of as built from many small squares.

Relation between γ\gamma and α\alpha: by an identical argument for a cube of side l0l_0, volume at 0 °C is V0=l03V_0 = l_0^3, and at T °CT\,°\text{C}, VT=lT3=l03(1+αT)3=V0(1+αT)3V_T = l_T^3 = l_0^3(1+\alpha T)^3 = V_0(1+\alpha T)^3 --- (7.22); also directly, VT=V0(1+γT)V_T = V_0(1+\gamma T) --- (7.23). Equating and expanding, and again neglecting the tiny higher-power-of-α\alpha terms, gives …

Misc Ex.12Coefficient of linear expansion of brass from its areal expansion

Worked out. A 50 cm x 8 cm brass sheet (area 400 cm^2 at 0 °C) has area 401.57 cm^2 at 100 °C; using A2 = A1[1+beta(T2-T1)] the example first solves for beta = 1.962x10^-4/°C, then applies beta = 2*alpha to find alpha(brass) = 1.962x10^-5/°C. …