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Answer the following in one sentence · Q3

Q.Draw the flow chart diagram to show classification of polymers based on type of polymerisation.

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✓ Free question

Step 1. At the top of the flow chart is 'Polymerization', the general process converting monomers to a high molecular mass polymer.

Step 2. It branches into three modes: Addition (chain-growth) polymerization -- monomers with a C=C double bond add on one after another without losing any small molecule (e.g. polythene from ethylene, via free-radical initiation/propagation/termination).

Step 3. Condensation (step-growth) polymerization -- polyfunctional monomers react in a series of steps, each eliminating a small molecule such as water, HCl, methanol or ammonia (e.g. terylene from ethylene glycol + terephthalic acid, eliminating water).

Step 4. Ring-opening polymerization -- a cyclic monomer (lactam/cyclic ether/lactone) has its ring opened by acid or base catalysis and adds on one unit at a time (e.g. nylon 6 from caprolactam).

✓Final answer

Polymerization

|-- Addition (chain-growth): e.g. polythene, PVC, teflon

|-- Condensation (step-growth): e.g. terylene, nylon 6,6, bakelite

|-- Ring-opening: e.g. nylon 6

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