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Chemistry · Ch 8 — Redox Reactions

Combination reactions

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Combination reactions

A combination reaction has the general form:

A+B→CA + B \rightarrow C

For this to be a redox reaction, at least one of the reactants (A or B, or both) must be in its elemental form (oxidation number zero). When elements combine, their oxidation numbers change — one element gets oxidised (its oxidation number increases) and another gets reduced (its oxidation number decreases).

All combustion reactions that use elemental dioxygen (O2O_2) are redox combination reactions. But the category is broader — any reaction where an element combines with another substance qualifies.

Examples with oxidation numbers shown:

C0(s)+O20(g)→ΔC+4O2−2(g)(7.24) \overset{0}{C}(s) + \overset{0}{O_2}(g) \xrightarrow{\Delta} \overset{+4}{C}\overset{-2}{O_2}(g) \qquad(7.24)

Carbon goes from 0 to +4 (oxidation), oxygen goes from 0 to –2 (reduction).

3Mg0(s)+N20(g)→ΔMg3+2N2−3(s)(7.25) 3\overset{0}{Mg}(s) + \overset{0}{N_2}(g) \xrightarrow{\Delta} \overset{+2}{Mg_3}\overset{-3}{N_2}(s) \qquad(7.25)

Magnesium is oxidised (0 → +2), nitrogen is reduced (0 → –3).

C−4H4+1(g)+2O20(g)→ΔC+4O2−2(g)+2H2+1O−2(l) \overset{-4}{C}\overset{+1}{H_4}(g) + 2\overset{0}{O_2}(g) \xrightarrow{\Delta} \overset{+4}{C}\overset{-2}{O_2}(g) + 2\overset{+1}{H_2}\overset{-2}{O}(l) …