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Q.The density of mercury is 13.6 gcm−313.6\,gcm^{-3} at 0∘C0^{\circ}C and its coefficient of cubical expansion is 1.82×10−4 ∘C−11.82\times10^{-4}\,^{\circ}C^{-1} then density of mercury at 50∘C50^{\circ}C is

(a) 13.48 gcm−313.48\,gcm^{-3}
(b) 14 gcm−314\,gcm^{-3}
(c) 13.48×10−2 gcm−313.48\times10^{-2}\,gcm^{-3}
(d) none of these.
Nagaland NbseNagaland Board of School Education (Class XI) 2024MCQ· 1mImportance★★★★★
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As mercury expands on heating, its density falls by a factor (1−γΔT)(1 - \gamma\Delta T), giving 13.48 gcm−313.48\,gcm^{-3}.

Since mass is conserved while volume increases on heating, density decreases as ρ(T)=ρ01+γΔT≈ρ0(1−γΔT)\rho(T) = \dfrac{\rho_0}{1+\gamma\Delta T} \approx \rho_0(1-\gamma\Delta T) for small γΔT\gamma\Delta T, where γ\gamma is the coefficient of cubical (volume) expansion. Here ρ0=13.6 gcm−3\rho_0 = 13.6\,gcm^{-3}, γ=1.82×10−4 ∘C−1\gamma = 1.82\times10^{-4}\,^{\circ}C^{-1}, ΔT=50∘C−0∘C=50∘C\Delta T = 50^{\circ}C - 0^{\circ}C = 50^{\circ}C.

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