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Exercises · 8.13

Q.What is the density of water at a depth where pressure is 80.0 atm, given that its density at the surface is 1.03×103 kg m−31.03 \times 10^{3}\ \text{kg m}^{-3}?

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The density of water increases slightly under high pressure due to compression, a phenomenon quantified by the Bulk Modulus. By applying the Bulk Modulus formula, we find the new density. The density of water at a depth where pressure is 80.0 atm is 1.034×103 kg m−3\boxed{1.034 \times 10^3 \text{ kg m}^{-3}}.

When a fluid like water is subjected to increased pressure, its volume decreases slightly, leading to a corresponding increase in its density. This resistance to compression is characterized by a material property called the Bulk Modulus (BB). The Bulk Modulus essentially tells us how much pressure is needed to cause a certain fractional change in volume.

The higher the Bulk Modulus, the more resistant the material is to compression. Water has a relatively high Bulk Modulus, meaning it is not easily compressible, but a measurable change in density does occur under significant pressure.

Here's how we approach this problem:

  1. We identify the initial density and the change in pressure.
  2. We use the definition of Bulk Modulus, which relates the pressure change to the fractional volume change.
  3. We then relate the fractional volume change to the fractional density change, as mass remains constant.
  4. Finally, we calculate the new density.

Let's work through the steps.

  1. Identify Given Values and Target

    • Initial density of water at the surface, ρ0=1.03×103 kg m−3\rho_0 = 1.03 \times 10^3 \text{ kg m}^{-3}.
    • Pressure at depth, P=80.0 atmP = 80.0 \text{ atm}.
    • Surface pressure, P0=1.0 atmP_0 = 1.0 \text{ atm}.
    • We need to find the new density, ρ\rho.

    The change in pressure (ΔP\Delta P) experienced by the water from the surface to the depth is the difference between the pressure at depth and the surface pressure:

    ΔP=P−P0=80.0 atm−1.0 atm=79.0 atm\Delta P = P - P_0 = 80.0 \text{ atm} - 1.0 \text{ atm} = 79.0 \text{ atm}.

    To use the Bulk Modulus, we must convert this pressure change to SI units (Pascals):

    1 atm=1.013×105 Pa1 \text{ atm} = 1.013 \times 10^5 \text{ Pa}.

    ΔP=79.0×(1.013×105 Pa)=7.999×106 Pa\Delta P = 79.0 \times (1.013 \times 10^5 \text{ Pa}) = 7.999 \times 10^6 \text{ Pa}.

  2. Recall the Bulk Modulus Formula

    The Bulk Modulus (BB) is defined as:

    B=−ΔPΔV/V0B = - \frac{\Delta P}{\Delta V / V_0}

    Where:

    • ΔP\Delta P is the change in pressure.
    • ΔV\Delta V is the change in volume.
    • V0V_0 is the initial volume.
    • The negative sign indicates that an increase in pressure (ΔP>0\Delta P > 0) leads to a decrease in volume (ΔV<0\Delta V < 0), keeping BB positive.
  3. Relate Volume Change to Density Change

    The mass (mm) of the water remains constant. We know that mass is related to density (ρ\rho) and volume (VV) by m=ρVm = \rho V.

    So, m=ρ0V0=ρVm = \rho_0 V_0 = \rho V.

    Taking the differential of m=ρVm = \rho V (assuming mm is constant):

    d(ρV)=0d(\rho V) = 0

    ρdV+Vdρ=0\rho dV + V d\rho = 0

    Dividing by ρV\rho V:

    dVV+dρρ=0\frac{dV}{V} + \frac{d\rho}{\rho} = 0

    dVV=−dρρ\frac{dV}{V} = - \frac{d\rho}{\rho}

    For small changes, we can approximate this as:

    ΔVV0≈−Δρρ0\frac{\Delta V}{V_0} \approx - \frac{\Delta \rho}{\rho_0}

    Where Δρ=ρ−ρ0\Delta \rho = \rho - \rho_0 is the change in density. …

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