Question of 87
Q.In the Bouveault-Blanc reduction of >C=O group the reagent required is:
(a) LiAlH4
(b) LiBH4
(c) Na - C2H5OH
(d) H2 / Ni-powder
Odisha ChseOdisha CHSE +2 Science Board Exam 2025MCQ· 1mImportance★★★★★
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Start your 14-day free trial to unlock the full solution →The Bouveault-Blanc reduction uses sodium metal in ethanol to reduce a carbonyl group (classically an ester) to the corresponding alcohol, via a dissolving-metal (single-electron transfer) mechanism, before LiAlH4/NaBH4 became common.
Before complex metal hydrides like LiAlH4 were developed, esters (and other carbonyl compounds) were reduced using sodium metal dissolved in absolute ethanol — sodium donates electrons to the C=O group and ethanol supplies protons, converting >C=O ultimately to >CH-OH. This is called the Bouveault-Blanc reduction. The other listed reagents reduce carbony …
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