Q.State Bohr's postulates for hydrogen atom. Use these to derive expressions for radius of allowed orbits and total energy of electron in those orbits. (2+3+2=7)
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Start your 14-day free trial to unlock the full solution →Combining Coulomb attraction (= centripetal force) with Bohr's quantised-angular-momentum postulate gives r_n ∝ n² and E_n ∝ −1/n² for hydrogen-like atoms.
Bohr's postulates:
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Stationary orbits: an electron revolves around the nucleus only in certain allowed circular orbits, called stationary states, in which it does NOT radiate energy even though it is accelerating — the electrostatic (Coulomb) force of attraction between the nucleus and electron provides the necessary centripetal force for this circular motion.
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Quantisation of angular momentum: the electron can revolve only in those orbits for which its orbital angular momentum is an integral multiple of h/2π:
L = mvr = nh/(2π), n = 1, 2, 3, ... (n is the principal quantum number)
- Frequency condition (radiative transitions): an electron can jump from a higher energy orbit (E_i) to a lower one (E_f), emitting a photon whose energy equals the energy difference; conversely it can absorb a photon of exactly this energy to jump up. hν = E_i − E_f.
Derivation of the radius of the n-th orbit:
For an electron of mass m, charge −e, orbiting a nucleus of charge +Ze at radius r with speed v, equating the Coulomb force to the centripetal force:
(1/4πε_0)(Ze²/r²) = mv²/r ⟹ mv² = Ze²/(4πε_0 r) ...(i)
From the quantisation postulate: v = nh/(2π m r) ...(ii)
Substituting (ii) into (i):
m × [nh/(2πmr)]² = Ze²/(4πε_0 r)
n²h²/(4π²mr²) = Ze²/(4πε_0 r)
Solving for r:
r_n = (ε_0 n² h²)/(π m Z e²)
For hydrogen (Z = 1), this gives r_n = n² × 0.529 Å — i.e. r_1 = 0.529 Å (the Bohr radius), and successive orbits' radii grow as n².
Derivation of the total energy of the electron in the n-th orbit:
Kinetic energy: KE = ½mv² = Ze²/(8πε_0 r) (from equation (i))
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