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Worked Examples · Example 11.3

Q.What is the de Broglie wavelength associated with

(a) an electron moving with a speed of 5.4×106 m/s5.4 \times 10^{6}\ \text{m/s}, and
(b) a ball of mass 150 g150\ \text{g} travelling at 30.0 m/s30.0\ \text{m/s}?
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The de Broglie wavelength is given by λ=h/p\lambda = h/p. For the electron, λ≈1.35×10−10 m\lambda \approx 1.35 \times 10^{-10}\ \text{m}; for the ball, λ≈1.47×10−34 m\lambda \approx 1.47 \times 10^{-34}\ \text{m} — the ball’s wavelength is utterly negligible because its mass is huge on the quantum scale.

The core idea here is wave-particle duality. Louis de Broglie proposed that every moving particle has an associated wavelength, just like a photon does. The wavelength is inversely proportional to the particle’s momentum — the heavier or faster the object, the shorter its wavelength. For macroscopic objects like a cricket ball, this wavelength is so tiny that it’s impossible to detect; for electrons, it’s comparable to atomic spacings, which is why electron microscopes work.

The de Broglie wavelength is

λ=hp=hmv\lambda = \frac{h}{p} = \frac{h}{mv}

where h=6.63×10−34 J⋅sh = 6.63 \times 10^{-34}\ \text{J·s} is Planck’s constant, mm is mass in kg, and vv is speed in m/s.

Let’s apply this to both cases.


(a) Electron moving at 5.4×106 m/s5.4 \times 10^{6}\ \text{m/s}

  1. Identify the mass. The electron’s rest mass is me=9.11×10−31 kgm_e = 9.11 \times 10^{-31}\ \text{kg}. This is a standard value you must remember for such problems.

  2. Compute momentum.

p=mv=(9.11×10−31)(5.4×106)p = m v = (9.11 \times 10^{-31})(5.4 \times 10^{6})

Multiply: 9.11×5.4=49.1949.11 \times 5.4 = 49.194, and 10−31×106=10−2510^{-31} \times 10^{6} = 10^{-25}.

So p=4.9194×10−24 kg⋅m/sp = 4.9194 \times 10^{-24}\ \text{kg·m/s}.

  1. Apply de Broglie relation.

λ=hp=6.63×10−344.9194×10−24\lambda = \frac{h}{p} = \frac{6.63 \times 10^{-34}}{4.9194 \times 10^{-24}}

Divide: 6.63/4.9194≈1.3476.63 / 4.9194 \approx 1.347, and 10−34/10−24=10−1010^{-34} / 10^{-24} = 10^{-10}.

So λ≈1.35×10−10 m\lambda \approx 1.35 \times 10^{-10}\ \text{m}.

Note

This wavelength (1.35 A˚1.35\ \text{Å}) is about the size of an atom. That’s why electron diffraction off crystals is possible — the wavelength matches the spacing between atomic planes.


(b) Ball of mass 150 g150\ \text{g} at 30.0 m/s30.0\ \text{m/s}

  1. Convert mass to kg. 150 g=0.150 kg150\ \text{g} = 0.150\ \text{kg}. This is a common slip — always use SI units.

  2. Compute momentum.

p=mv=(0.150)(30.0)=4.50 kg⋅m/sp = m v = (0.150)(30.0) = 4.50\ \text{kg·m/s}

  1. Apply de Broglie relation.

λ=6.63×10−344.50\lambda = \frac{6.63 \times 10^{-34}}{4.50}

6.63/4.50=1.47336.63 / 4.50 = 1.4733, so

λ≈1.47×10−34 m\lambda \approx 1.47 \times 10^{-34}\ \text{m} …

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