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Question 26 of 34

Q.Give any three differences between nucleophiles and electrophiles.

Puducherry TnboardTamil Nadu HSC First Year (DGE) Board 2022Subjective· 3mImportance★★★★★
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Nucleophiles and electrophiles are opposite in their electronic behaviour: a nucleophile is electron-rich and donates an electron pair to form a new bond, while an electrophile is electron-deficient and accepts an electron pair.

Three key differences:

  1. Nature/electron count: A nucleophile ('nucleus-loving') is a species that is rich in electrons — it may be neutral with a lone pair, or negatively charged. An electrophile ('electron-loving') is a species that is deficient in electrons — it may be neutral with an incomplete octet, or positively charged.

  2. Role in bond formation: A nucleophile DONATES an electron pair to form a new covalent bond with an electron-deficient centre. An electrophile ACCEPTS an electron pair from an electron-rich centre to form the new bond.

  3. Examples: Common nucleophiles include OH-, CN-, NH3, H2O, alkoxide ions (RO-), and halide ions (Cl-, Br-) — species with a lone pair or negative charge to donate. Common electrophiles include H+, NO2+ (nitronium ion), carbocations (R+), and Lewis acids such as AlCl3 or BF3 — species that are positively charged or have an incomplete octet. …

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