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Chemistry · Ch 6 — Gaseous State

The Gas Laws

6.2

The Gas Laws

Gas laws describe how the physical properties of a gas -- pressure, volume, temperature and amount -- relate to one another, and they were arrived at almost entirely by careful experimental study of these properties. Before taking up the individual laws, it helps to be precise about what "pressure" means and how it is measured.

Pressure is defined as force divided by the area over which that force acts:

Pressure=ForceArea=N or kg m s−2m2\text{Pressure}=\frac{\text{Force}}{\text{Area}}=\frac{N\ \text{or}\ kg\,m\,s^{-2}}{m^2} …

Table 6.1Units of pressure
UnitSymbolValue (Nm−2^{-2} or kg m−1^{-1}s−2^{-2})
pascalPa1 Pa = 1 Nm−2^{-2}
atmosphereatm1 atm = 101325 Pa
millimeter of mercurymmHg1 mmHg = 133.322 Pa
barbar1 bar = 105^5 Pa
torrTorr1 Torr = 133.322 Pa