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Choose the Best Answer · Q17

Q.The reaction H₃PO₂ + D₂O → H₂DPO₂ + HDO indicates that hypo-phosphorus acid is

(a) tribasic acid
(b) dibasic acid
(c) mono basic acid
(d) none of these
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Step 1. The reaction H3PO2+D2O→H2DPO2+HDOH_3PO_2 + D_2O \rightarrow H_2DPO_2 + HDO shows that only ONE of hypophosphorous acid's three hydrogen atoms exchanges with deuterium from D₂O.

Step 2. In such deuterium-exchange experiments, only IONISABLE (acidic, O-H type) hydrogens exchange readily; hydrogens bonded directly to a non-oxygen atom (here, P-H bonds) do not exchange under these conditions. …

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