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Choose the Best Answer · Q20

Q.Glucose is an aldose. Which one of the following reactions is not expected with glucose?

a) It does not form oxime
b) It does not react with Grignard reagent
c) It does not form osazones
d) It does not reduce Tollens reagent
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Step 1. This question lists four negatively-phrased statements about glucose and asks which one is actually TRUE (i.e. which reaction genuinely is 'not expected'); the other three, though phrased as denials, describe reactions that DO in fact occur.

Step 2. Option (a) 'does not form oxime' is FALSE as a denial -- §14.1.3 states directly that glucose reacts with hydroxylamine to form an oxime, confirming its aldehyde group; the reaction is expected. Option (c) 'does not form osazones' is also FALSE as a denial -- glucose's free aldehyde and adjacent -OH react with excess phenylhydrazine in the classic osazone-formation test used to identify sugars; the reaction is expected. Option (d) 'does not reduce Tollens reagent' is FALSE as a denial -- §14.1.3 states explicitly that glucose reduces Tollens' reagent to metallic silver (the silver-mirror test); the reaction is expected. …

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