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Chemistry · Ch 5 — Coordination Chemistry

Limitations of Werner's Theory

5.2.1

Limitations of Werner's Theory

The one major gap Werner's otherwise powerful theory left open: even though it explains primary/secondary valence, ionisable versus non-ionisable groups, and the geometry implied by a given secondary valence, it has nothing to say about why coordination compounds are coloured or why they show the magnetic properties they do -- the two properties that Valence Bond Theory and, more …