Question 67 of 76
Q. on heating with periodic acid gives :
(a) Methanal
(b) Methanoic acid
(c)
(d) Glyoxal
Puducherry TnboardTamil Nadu HSC (DGE) Board 2022MCQ· 1mImportance★★★★★
88% · 67/76 Questions
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Start your 14-day free trial to unlock the full solution →Periodic acid cleaves the C–C bond of the vicinal diol , converting each carbon into , so the product is methanal (HCHO); itself is reduced to .
The general reaction of a 1,2-diol with periodic acid is , cleaving the bond between the two hydroxyl-bearing carbons. For ethylene glycol, , both carbons are (each bearing 2 H, 1 OH, and the C–C bond to be cleaved), so cleavage converts each into , i.e. methanal. No further oxidation to methanoic acid or occurs under these specific cleavage conditions, and glyoxal (OHC–CHO) would only …
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