Q.What are the properties of interstitial compounds ?
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Start your 14-day free trial to unlock the full solution →Interstitial compounds (small non-metal atoms trapped in the voids of a transition-metal lattice) are extremely hard, high-melting, chemically unreactive, and retain the metallic conductivity and lustre of the parent metal.
Transition metals possess vacant interstitial spaces (voids) between the atoms of their close-packed crystal lattices. When small atoms of non-metals such as hydrogen, carbon, nitrogen or boron are trapped inside these voids (either during formation of the metal or by later diffusion into it), non-stoichiometric or near-stoichiometric compounds called interstitial compounds are formed, e.g. , , , , .
Properties:
- High melting points: interstitial compounds usually have melting points even higher than that of the pure parent metal, because the interstitial atoms strengthen the metallic lattice.
- Extreme hardness: they are very hard, in some cases (e.g. tungsten carbide, ) approaching the hardness of diamond, making them useful for cutting tools and abrasives.
- Retain metallic conductivity: since the metallic bonding/delocalised electron structure of the parent lattice is largely preserved, these compounds continue to conduct heat and electricity like metals. …
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