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Q.What are the properties of interstitial compounds ?

Puducherry TnboardTamil Nadu HSC (DGE) Board 2022Subjective· 3mImportance★★★★★
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Interstitial compounds (small non-metal atoms trapped in the voids of a transition-metal lattice) are extremely hard, high-melting, chemically unreactive, and retain the metallic conductivity and lustre of the parent metal.

Transition metals possess vacant interstitial spaces (voids) between the atoms of their close-packed crystal lattices. When small atoms of non-metals such as hydrogen, carbon, nitrogen or boron are trapped inside these voids (either during formation of the metal or by later diffusion into it), non-stoichiometric or near-stoichiometric compounds called interstitial compounds are formed, e.g. TiCTiC, Fe3HFe_3H, Mn4NMn_4N, VH0.56VH_{0.56}, ZrH1.92ZrH_{1.92}.

Properties:

  1. High melting points: interstitial compounds usually have melting points even higher than that of the pure parent metal, because the interstitial atoms strengthen the metallic lattice.
  2. Extreme hardness: they are very hard, in some cases (e.g. tungsten carbide, WCWC) approaching the hardness of diamond, making them useful for cutting tools and abrasives.
  3. Retain metallic conductivity: since the metallic bonding/delocalised electron structure of the parent lattice is largely preserved, these compounds continue to conduct heat and electricity like metals. …

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