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Physics · Ch 8 — Atomic and Nuclear Physics

Carbon dating

8.6.6

Carbon dating

One of the most striking practical applications of beta decay is radiocarbon (carbon) dating, a technique for estimating the age of ancient organic material.

The physical basis. All living organisms continuously absorb carbon dioxide from the air to build organic molecules. The overwhelming majority of this absorbed carbon is stable 612C^{12}_{6}C, but a tiny, nearly constant fraction (1.3×10−121.3\times10^{-12}) is the radioactive isotope 614C^{14}_{6}C, whose half-life is 5730 years. Carbon-14 in the atmosphere is continuously decaying away, but it is simultaneously being continuously replenished as cosmic rays from outer space bombard atoms in the upper atmosphere and produce fresh 614C^{14}_{6}C. This ongoing balance of production and decay keeps the ratio of 614C^{14}_{6}C to 612C^{12}_{6}C in the atmosphere - and hence, through continuous absorption, in every living organism - essentially constant while the organism is alive.

After death. Once an organism dies, it stops absorbing new carbon dioxide, so its 614C^{14}_{6}C content is no longer replenished and simply decays away following the ordinary exponential law; the ratio of 614C^{14}_{6}C to 612C^{12}_{6}C in the dead remains therefore steadily decreases over the following centuries and millennia. By measuring the present-day carbon-14 activity of an ancient sample and comparing it to the activity a similar living sample would have, the elapsed time since death - the sample's age - can be calculated using R=R0e−λtR=R_0e^{-\lambda t}, rearranged to t=1λln⁡(R0/R)t=\tfrac{1}{\lambda}\ln(R_0/R). …

Misc Example 8.14Age of the Keezhadi charcoal sample

Worked out. This worked example, framed around the real Keezhadi archaeological excavation in Sivagangai district on the banks of the river Vaigai in Tamil Nadu, finds the age of a 200 g charcoal sample whose measured carbon-14 activity is 38 decays per second. The decay constant is first found from the known carbon-14 half-life of 5730 years as λ = 0.6931/(5730 times 3.156e7 s) ≈ 3.83e-12 per second. The initial activity R0 is then found from the number of carbon-14 atoms that would have been present when the tree was alive: 200 g of carbon contains about 1e25 carbon atoms, and multiplying by the natural carbon-14 to carbon-12 ratio of 1.3e-12 gives N0 ≈ 1.3e13 carbon-14 atoms, so R0 = λN0 ≈ 50 decays per second. Using t = (1/λ) ln(R0/R) = (1/3.83e-12) ln(50/38) gives t ≈ 7e10 seconds, which converts to roughly 2200 years - matching the archaeological finding that the Keezhadi civilisation flourished in t …