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NCERT Exemplar · Q22

Q.A particle A with a mass mAm_A is moving with a velocity vv and hits a particle B (mass mBm_B) at rest (one dimensional motion). Find the change in the de Broglie wavelength of the particle A. Treat the collision as elastic.

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In an elastic collision, the de Broglie wavelength of a particle changes because its momentum changes. For particle A hitting stationary B, the final velocity of A is vA′=mA−mBmA+mBvv_A' = \frac{m_A - m_B}{m_A + m_B} v, so the change in wavelength is Δλ=hmAv(mA+mBmA−mB−1)\Delta \lambda = \frac{h}{m_A v} \left( \frac{m_A + m_B}{m_A - m_B} - 1 \right).

The de Broglie wavelength of any moving particle is inversely proportional to its momentum: λ=h/p\lambda = h/p. When particle A collides elastically with stationary B, A's velocity — and therefore its momentum — changes. Since the collision is elastic, both momentum and kinetic energy are conserved, which lets us find A's final velocity exactly.

The key insight: you don't need to compute the wavelength after collision from scratch. Instead, find the change in momentum, then translate that into a change in wavelength using the de Broglie relation.

  1. Write the initial de Broglie wavelength of A. Before collision, A moves with velocity vv, so its momentum is pA=mAvp_A = m_A v.

λi=hmAv\lambda_i = \frac{h}{m_A v}

  1. Find A's velocity after an elastic collision with stationary B. For a one-dimensional elastic collision, the standard result (derived from conservation of momentum and kinetic energy) gives:

vA′=mA−mBmA+mB vv_A' = \frac{m_A - m_B}{m_A + m_B} \, v

This is a formula worth remembering — it comes directly from solving the two conservation equations.

›Proof

Derivation of vA′v_A'

Conservation of momentum: mAv=mAvA′+mBvB′m_A v = m_A v_A' + m_B v_B'

Conservation of kinetic energy: 12mAv2=12mAvA′2+12mBvB′2\frac12 m_A v^2 = \frac12 m_A v_A'^2 + \frac12 m_B v_B'^2

From momentum, vB′=mAmB(v−vA′)v_B' = \frac{m_A}{m_B}(v - v_A'). Substitute into the energy equation and simplify. The quadratic yields two solutions: vA′=vv_A' = v (no collision) and vA′=mA−mBmA+mBvv_A' = \frac{m_A - m_B}{m_A + m_B} v (the physical one).

  1. Compute the final de Broglie wavelength of A. After collision, A's momentum is pA′=mAvA′=mA⋅mA−mBmA+mBvp_A' = m_A v_A' = m_A \cdot \frac{m_A - m_B}{m_A + m_B} v. So:

λf=hmAvA′=hmAv⋅mA+mBmA−mB\lambda_f = \frac{h}{m_A v_A'} = \frac{h}{m_A v} \cdot \frac{m_A + m_B}{m_A - m_B}

  1. Find the change in wavelength.

Δλ=λf−λi=hmAv(mA+mBmA−mB−1)\Delta \lambda = \lambda_f - \lambda_i = \frac{h}{m_A v} \left( \frac{m_A + m_B}{m_A - m_B} - 1 \right)

Simplify the bracket:

mA+mBmA−mB−1=mA+mB−(mA−mB)mA−mB=2mBmA−mB\frac{m_A + m_B}{m_A - m_B} - 1 = \frac{m_A + m_B - (m_A - m_B)}{m_A - m_B} = \frac{2 m_B}{m_A - m_B}

Therefore:

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