Concept understanding — Magnetic Materials Magnetization
From a Paperclip to a Magnet: The Intuition
You already know that a magnet can pick up iron nails. But what is actually happening inside that nail when it gets near the magnet? And why does a plastic comb, rubbed on hair, pick up tiny bits of paper — but never iron filings?
The answer lies in magnetization — the process by which a material becomes magnetic.
Think of a piece of iron as a chaotic crowd of tiny compass needles. Each needle is an atomic magnetic moment (a tiny magnet, arising from the spin of electrons). In unmagnetized iron, these needles point in random directions. Their magnetic effects cancel out, so the iron as a whole shows no net magnetism.
Now bring a strong magnet close. Its magnetic field acts like a command: "Line up!" The tiny compass needles inside the iron start rotating, aligning themselves with the external field. The more they align, the stronger the iron's own magnetic field becomes. This alignment is magnetization.
Note
Magnetization is not the same as inducing a current. It is a purely magnetic reorientation of atomic dipoles inside a material.
The Precise Definition
Magnetization (M) is the net magnetic dipole moment per unit volume of a material. It tells you how strongly a material is magnetized — how many tiny atomic magnets are aligned, and in which direction.
If a material has N atoms per unit volume, each with an average magnetic moment μavg, then:
M=Nμavg
The SI unit of M is amperes per metre (A/m). Why? Because a magnetic dipole moment has units of A·m², and dividing by volume (m³) gives A/m.
M=volumetotal magnetic dipole moment
How Magnetization Connects to the Magnetic Field
When a material gets magnetized, it produces its own magnetic field. The total magnetic field B inside the material is the sum of:
The external applied fieldH (caused by free currents, like the current in a solenoid)
The material's response — the magnetization M
The fundamental relation is:
B=μ0(H+M)
where μ0=4π×10−7T⋅m/A is the permeability of free space.
Watch out
Do not confuse H (magnetic field intensity, or "magnetizing field") with B (magnetic flux density). H is what you apply; M is what the material does; B is the total field you measure.
The Three Kinds of Magnetic Materials
Not all materials respond the same way to an external field. The magnetization M is proportional to H for most materials (at least for small fields):
M=χmH
where χm is the magnetic susceptibility — a dimensionless number that tells you how easily a material magnetizes.
Material Type
χm
Behaviour
Example
Diamagnetic
Small and negative (≈−10−5)
Weakly repelled by a magnet; M opposes H
Water, copper, bismuth
Paramagnetic
Small and positive (≈10−5 to 10−3)
Weakly attracted; M aligns with H
Aluminium, oxygen gas
Ferromagnetic
Large and positive (≫1)
Strongly attracted; M can be huge and persists even after H is removed
Iron, nickel, cobalt
Why this formula?
Magnetic Materials & Magnetization: Why the Key Formulas Hold
Let's build this from the ground up — starting with what magnetization physically means, then deriving the formulas step by step.
1. What is Magnetization (M)?
Magnetization is the net magnetic dipole moment per unit volume of a material.
Inside a material, atoms act like tiny magnetic dipoles (due to electron spin and orbital motion).
Without an external field, these dipoles point randomly → net M=0.
When an external field H is applied, dipoles align partially → net M=0.
Definition:
M=volumenet magnetic dipole moment
Units: A/m (same as H).
2. The Fundamental Relation: B=μ0(H+M)
This is the master equation linking the three magnetic fields:
B = magnetic flux density (the total field inside the material)
H = applied magnetic field (due to free currents)
M = magnetization (response of the material)
μ0 = permeability of free space (4π×10−7 H/m)
Why this form?
Step 1: In vacuum, there is no material, so M=0. Then:
B=μ0H
Step 2: Inside a material, the dipoles themselves produce an additional field. The total B is the sum of:
The field due to free currents (μ0H)
The field due to bound currents (from aligned dipoles), which is μ0M
Hence:
B=μ0H+μ0M=μ0(H+M)
Key insight:M is not an independent field — it's the material's response to H.
3. Magnetic Susceptibility (χm) and Permeability (μ)
For linear, isotropic, homogeneous materials (most common in exams), magnetization is proportional to the applied field:
M=χmH
χm = magnetic susceptibility (dimensionless)
χm>0 for paramagnetic materials
χm<0 for diamagnetic materials
χm≫1 for ferromagnetic materials (but not linear!)
Derivation of relative permeability μr:
Substitute M=χmH into the master equation:
B=μ0(H+χmH)=μ0(1+χm)H
Define:
μr=1+χm(relative permeability)
μ=μ0μr(absolute permeability)
Thus:
B=μH
Why this matters: It shows that the material simply scales the applied field by a factor μr.
4. Why χm Has Different Signs (Physical Reasoning)
Material Type
χm
Why?
Diamagnetic
χm<0 (small, ~10−5)
Applied field induces opposing dipole moments (Lenz's law at atomic level). M opposes H.
Paramagnetic
χm>0 (small, ~10−3)
Permanent atomic dipoles align partially with H. Thermal agitation fights alignment.
Cooled in liquid nitrogen the ball is superconducting, so it is a perfect diamagnet (Meissner effect, χ=−1): it expels all magnetic flux and sets up surface currents whose field exactly opposes the applied field inside it.
(i) A diamagnet is pushed toward weaker field. A bar magnet's field is strongest near its pole and weakens with distance, so the ball is repelled — it moves away from the magnet. …
A superconductor is a perfect diamagnet (Meissner effect), so it is repelled by the bar magnet — it moves away toward weaker field — and its induced magnetic moment points opposite to the external field.
Why a superconductor is special
Below its critical temperature a superconductor enters the Meissner state and expels all magnetic flux from its interior. It behaves as a perfect diamagnet with susceptibility χ=−1: whatever field is applied, screening surface currents arise that cancel it inside the material.
(i) Direction of motion
Induced moment opposes the field. The screening currents produce a magnetic moment m antiparallel to the applied field Bext.
Force in a non-uniform field. A dipole feels F=∇(m⋅Bext). Since m is antiparallel to Bext, the product m⋅Bext<0, so the force points toward decreasing∣Bext∣.
A bar magnet's field is strongest at the pole and weakens outward, so the ball is pushed toward weaker field — it is repelled and moves away from the magnet.
Watch out
Do not confuse this with a piece of iron, which is ferromagnetic and is attracted. A diamagnet — and a superconductor is the perfect case — is always repelled.
Method: Predicting Motion and Induced Moment of a Diamagnet (or Perfect Diamagnet) in a Non-Uniform Field
Use this for any "will it be attracted or repelled, and which way does its induced moment point" question involving a diamagnetic sample (including the special case of a superconductor) near a magnet.
Steps
Step 1: Identify the material's magnetic response
Determine (from the material or the physical scenario) whether the induced moment will be parallel to the applied field (paramagnetic/ferromagnetic, χ>0) or antiparallel to it (diamagnetic, χ<0). A superconductor below its critical temperature is the extreme case: the Meissner effect makes it a perfect diamagnet, χ=−1, expelling the field entirely and inducing a moment exactly opposite to the applied field.
Step 2: Recall the force on a dipole in a non-uniform field
F=∇(m⋅Bext)
This is the general rule: a dipole is pushed in the direction that increasesm⋅Bext.
Step 3: Combine sign of χ with the force law
If m is antiparallel to Bext (diamagnetic case), the dot product m⋅Bext<0 and gets less negative as ∣Bext∣ decreases — so the force points toward weaker field. The sample is repelled from any source (like a bar magnet's pole) where the field is strongest. …