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Worked Examples · Example 10.3

Q.A sphere of 0.047 kg0.047\ \text{kg} aluminium is placed for sufficient time in a vessel containing boiling water, so that the sphere is at 100 ∘C100\ ^\circ\text{C}. It is then immediately transferred to 0.14 kg0.14\ \text{kg} copper calorimeter containing 0.25 kg0.25\ \text{kg} water at 20 ∘C20\ ^\circ\text{C}. The temperature of water rises and attains a steady state at 23 ∘C23\ ^\circ\text{C}. Calculate the specific heat capacity of aluminium.

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Using the principle of calorimetry (heat lost by the hot aluminium = heat gained by the water and the copper calorimeter), the specific heat capacity of aluminium works out to about 913 J kg−1K−1913\ \text{J kg}^{-1}\text{K}^{-1}.

When the hot aluminium sphere is dropped into the cooler water-filled calorimeter, heat flows from the sphere until everything reaches the same final temperature. No heat is assumed lost to the surroundings, so:

Heat lost by aluminium=Heat gained by water+Heat gained by the copper calorimeter.\text{Heat lost by aluminium} = \text{Heat gained by water} + \text{Heat gained by the copper calorimeter}.

Setting up the numbers

  • Aluminium: mAl=0.047m_{\text{Al}} = 0.047 kg, cools from 100∘100^\circC to 23∘23^\circC, so ΔTAl=77\Delta T_{\text{Al}} = 77 K.
  • Water: mw=0.25m_w = 0.25 kg, warms from 20∘20^\circC to 23∘23^\circC, so ΔTw=3\Delta T_w = 3 K; cw=4186 J kg−1K−1c_w = 4186\ \text{J kg}^{-1}\text{K}^{-1}.
  • Copper calorimeter: mCu=0.14m_{\text{Cu}} = 0.14 kg, also warms by 33 K; cCu≈390 J kg−1K−1c_{\text{Cu}} \approx390\ \text{J kg}^{-1}\text{K}^{-1}.

Heat balance

mAl cAl ΔTAl=(mwcw+mCucCu) ΔTwm_{\text{Al}}\,c_{\text{Al}}\,\Delta T_{\text{Al}} = (m_w c_w + m_{\text{Cu}} c_{\text{Cu}})\,\Delta T_w

0.047×cAl×77=(0.25×4186+0.14×390)×30.047 \times c_{\text{Al}} \times77 = (0.25\times4186 + 0.14\times390)\times3

Compute the right-hand side:

0.25×4186=1046.5,0.14×390=54.6,sum=1101.1.0.25\times4186 = 1046.5, \qquad 0.14\times390 = 54.6, \qquad \text{sum} = 1101.1. …

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