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Chemistry · Class 11 Science

Ch 1Some Basic Concepts of Chemistry — Class 11 Chemistry, concept-first.

Chemistry is the branch of science that studies the composition, structure, properties, and reactions of matter. Science as a whole is conventionally divided into disciplines such as chemistry, physics, biology, and geology for convenience -- but the practical knowledge that eventually became chemistry is ancient, and…

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Key concepts

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Chapter contents

The NCERT structure, section by section. Open a section to see its questions, then read the concept-first solution.

Development of Chemistry

Chemistry is the branch of science that studies the composition, structure, properties, and reactions of matter.

1.1

Importance of Chemistry

Chemistry is not an isolated subject. It sits at the heart of science, constantly interacting with physics, biology, geology, and even computer science.

1.2

Nature of Matter

Anything which has mass and occupies space is called matter. Everything around us — a book, a pen, a pencil, water, air, and all living beings — is composed of matter: each has mass, and each occupies…

1.2.1

States of Matter

Matter around us exists in three familiar physical forms: solid, liquid, and gas. What distinguishes these states is not the kind of particles (atoms or molecules) they are made of, but how those part…

1.2.2

Classification of Matter

At the macroscopic level — the level we can see and handle — matter is first divided into two broad categories: pure substances and mixtures.

1.3

Properties of Matter and their Measurement

Every substance around us has unique physical and chemical characteristics that define its identity. To study these systematically, we measure properties like mass, volume, temperature, and density us…

1.3.1

Physical and Chemical Properties

Every substance possesses a set of properties that are unique to it — these are what allow us to identify one substance from another.

1.3.2

Measurement of Physical Properties

Quantitative measurement of properties is required for scientific investigation. Many properties of matter — length, area, volume and so on — are quantitative in nature, and any quantitative observati…

1.3.3

The International System of Units (SI)

Science depends on measurement, and measurement depends on a consistent system of units. Before 1960, different countries used different systems — the British Imperial system, the CGS (centimetre-gram…

1.3.4

Mass and Weight

Mass and weight are often used interchangeably in daily life, but in science they describe fundamentally different properties.

1.3.5

Volume

Volume is the amount of three-dimensional space that a substance occupies. Since space is measured in three dimensions, the fundamental unit of volume is the cube of a length unit.

1.3.6

Density

The two properties discussed just before this — mass (1.3.4) and volume (1.3.5) — are related through density:

1.3.7

Temperature

Temperature is a measure of how hot or cold an object is. It is a fundamental physical quantity, and in chemistry, controlling and measuring temperature is essential because reaction rates, equilibriu…

1.4

Uncertainty in Measurement

Many a time in the study of chemistry, one has to deal with experimental data as well as theoretical calculations.

1.4.1

Scientific Notation

Chemistry deals with numbers that span an extraordinary range. A single gram of hydrogen contains roughly 602,200,000,000,000,000,000,000 molecules, while the mass of a single hydrogen atom is about 0…

1.4.2

Significant Figures

Every measurement you make in a laboratory carries some uncertainty. The source of this uncertainty is twofold: the limitations of the instrument you are using, and the skill of the person making the…

1.4.3

Dimensional Analysis

When you work through numerical problems in chemistry, you often need to convert a quantity expressed in one set of units into the equivalent quantity in another set of units.

1.5

Laws of Chemical Combinations

Chemistry is the science of change, and at its heart lies the question: how much? The Laws of Chemical Combinations provide the foundational rules that govern how elements and compounds react in fixed…

1.5.1

Law of Conservation of Mass

The law of conservation of mass was put forward by the French chemist Antoine Lavoisier in 1789. Before Lavoisier, chemistry was largely qualitative — alchemists and early chemists had not yet develop…

1.5.2

Law of Definite Proportions

This law — which the book notes is sometimes also referred to as the Law of Definite Composition (equivalently, of constant composition) — states that a given chemical compound always contains its con…

1.5.3

Law of Multiple Proportions

This law was proposed by Dalton in 1803. According to it, if two elements can combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element are…

1.5.4

Gay Lussac's Law of Gaseous Volumes

In 1808, Joseph Louis Gay Lussac published a law that described a striking pattern in the way gases react.

1.5.5

Avogadro's Law

In 1811, Amedeo Avogadro put forward a bold idea that would eventually become one of the cornerstones of chemical science.

1.6

Dalton's Atomic Theory

The idea that matter is made of tiny, indivisible particles is ancient — the Greek philosopher Democritus called them atomos, meaning “uncuttable” or “indivisible”.

1.7

Atomic and Molecular Masses

The journey from the microscopic world of atoms to the measurable quantities in a laboratory begins with understanding their masses.

1.7.1

Atomic Mass

Atoms are unimaginably small. A single hydrogen atom has a mass of roughly grams — a decimal so small it is nearly impossible to work with directly.

1.7.2

Average Atomic Mass

Most elements in nature are not composed of atoms that are all identical. Instead, they exist as a mixture of isotopes — atoms of the same element that have the same number of protons but different nu…

1.7.3

Molecular Mass

Molecular mass is the sum of the atomic masses of the elements present in a molecule. It is obtained by multiplying the atomic mass of each element by the number of its atoms and adding them together.

1.7.4

Formula Mass

Some substances, such as sodium chloride, do not contain discrete molecules as their constituent units.

1.8

Mole Concept and Molar Masses

Atoms and molecules are extremely small in size, and their numbers in even a small amount of any substance are really very large.

1.9

Percentage Composition

So far we were dealing with the number of entities present in a given sample; many a time, information regarding the percentage of a particular element present in a compound is required.

1.9.1

Empirical Formula for Molecular Formula

An empirical formula represents the simplest whole-number ratio of various atoms present in a compound.

1.10

Stoichiometry and Stoichiometric Calculations

The word stoichiometry is derived from two Greek words — stoicheion (meaning element) and metron (meaning measure).

1.10.1

Limiting Reagent

In any chemical reaction, the reactants are rarely present in the exact ratio demanded by the balanced chemical equation.

1.10.2

Reactions in Solutions

A majority of reactions in the laboratories are carried out in solutions. Therefore, it is important to understand how the amount of substance is expressed when it is present in a solution.

1

Mass Per Cent

Mass per cent is the simplest way to express concentration. It is obtained by using the following relation:

2

Mole Fraction

Mole fraction is the ratio of the number of moles of one component to the total number of moles of all components in the solution. If substance A dissolves in substance B, with and moles respectively:

3

Molarity

Molarity is the most widely used concentration unit in the laboratory, denoted by M. It is defined as the number of moles of solute per litre of solution:

4

Molality

Molality is defined as the number of moles of solute present in 1 kg of solvent. It is denoted by m:

NCERT Textbook Exercises -- Supplementary Data Tables

A handful of the chapter's end-of-chapter exercise questions come with their own data table printed as part of the question.

Summary

- Matter is anything with mass and volume; classified as mixtures (homogeneous/heterogeneous) or pure substances (elements/compounds).

Exercises

+Show 36 questions36 questions
  1. 1.1Calculate the molar mass of the following: (i) $H_2O$ (ii) $CO_2$ (iii) $CH_4$Free
  2. 1.2Calculate the mass per cent of different elements present in sodium sulphate ($Na_2SO_4$).Free
  3. 1.3Determine the empirical formula of an oxide of iron, which has 69.9% iron and 30.1% dioxygen by mass.Free
  4. 1.4Calculate the amount of carbon dioxide that could be produced when (i) 1 mole of carbon is burnt in air. (ii) 1 mole of carbon is burnt in 1…Preview
  5. 1.5Calculate the mass of sodium acetate ($CH_3COONa$) required to make 500 mL of 0.375 molar aqueous solution. Molar mass of sodium acetate is…Preview
  6. 1.6Calculate the concentration of nitric acid in moles per litre in a sample which has a density, $1.41\ g\ mL^{-1}$ and the mass per cent of n…Preview
  7. 1.7How much copper can be obtained from 100 g of copper sulphate ($CuSO_4$)?Preview
  8. 1.8Determine the molecular formula of an oxide of iron, in which the mass per cent of iron and oxygen are 69.9 and 30.1, respectively.Preview
  9. 1.9Calculate the atomic mass (average) of chlorine using the following data: | | % Natural Abundance | Molar Mass | |---|---|---| | $^{35}Cl$ |…Preview
  10. 1.10In three moles of ethane ($C_2H_6$), calculate the following: (i) Number of moles of carbon atoms. (ii) Number of moles of hydrogen atoms. (…Preview
  11. 1.11What is the concentration of sugar ($C_{12}H_{22}O_{11}$) in $mol\ L^{-1}$ if its 20 g are dissolved in enough water to make a final volume…Preview
  12. 1.12If the density of methanol is $0.793\ kg\ L^{-1}$, what is its volume needed for making 2.5 L of its 0.25 M solution?Preview
  13. 1.13Pressure is determined as force per unit area of the surface. The SI unit of pressure, pascal is as shown below: $1\ Pa = 1\ N\ m^{-2}$. If…Preview
  14. 1.14What is the SI unit of mass? How is it defined?Preview
  15. 1.15Match the following prefixes with their multiples: | Prefixes | Multiples | |---|---| | (i) micro | $10^6$ | | (ii) deca | $10^9$ | | (iii)…Preview
  16. 1.16What do you mean by significant figures?Preview
  17. 1.17A sample of drinking water was found to be severely contaminated with chloroform, $CHCl_3$, supposed to be carcinogenic in nature. The level…Preview
  18. 1.18Express the following in the scientific notation: (i) 0.0048 (ii) 234,000 (iii) 8008 (iv) 500.0 (v) 6.0012Preview
  19. 1.19How many significant figures are present in the following? (i) 0.0025 (ii) 208 (iii) 5005 (iv) 126,000 (v) 500.0 (vi) 2.0034Preview
  20. 1.20Round up the following upto three significant figures: (i) 34.216 (ii) 10.4107 (iii) 0.04597 (iv) 2808Preview
  21. 1.21The following data are obtained when dinitrogen and dioxygen react together to form different compounds: | | Mass of dinitrogen | Mass of di…Preview
  22. 1.22If the speed of light is $3.0 \times 10^8\ m\ s^{-1}$, calculate the distance covered by light in 2.00 ns.Preview
  23. 1.23In a reaction $A + B_2 \rightarrow AB_2$ identify the limiting reagent, if any, in the following reaction mixtures. (i) 300 atoms of A + 200…Preview
  24. 1.24Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical equation: $N_2 (g) + H_2 (g) \rightar…Preview
  25. 1.25How are 0.50 mol $Na_2CO_3$ and 0.50 M $Na_2CO_3$ different?Preview
  26. 1.26If 10 volumes of dihydrogen gas reacts with five volumes of dioxygen gas, how many volumes of water vapour would be produced?Preview
  27. 1.27Convert the following into basic units: (i) 28.7 pm (ii) 15.15 pm (iii) 25365 mgPreview
  28. 1.28Which one of the following will have the largest number of atoms? (i) 1 g Au (s) (ii) 1 g Na (s) (iii) 1 g Li (s) (iv) 1 g of $Cl_2$ (g)Preview
  29. 1.29Calculate the molarity of a solution of ethanol in water, in which the mole fraction of ethanol is 0.040 (assume the density of water to be…Preview
  30. 1.30What will be the mass of one $^{12}C$ atom in g?Preview
  31. 1.31How many significant figures should be present in the answer of the following calculations? (i) $\dfrac{0.02856 \times 298.15 \times 0.112}{…Preview
  32. 1.32Use the data given in the following table to calculate the molar mass of naturally occuring argon isotopes: | Isotope | Isotopic molar mass…Preview
  33. 1.33Calculate the number of atoms in each of the following (i) 52 moles of Ar (ii) 52 u of He (iii) 52 g of He.Preview
  34. 1.34A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water a…Preview
  35. 1.35Calcium carbonate reacts with aqueous HCl to give $CaCl_2$ and $CO_2$ according to the reaction, $CaCO_3 (s) + 2 HCl (aq) \rightarrow CaCl_2…Preview
  36. 1.36Chlorine is prepared in the laboratory by treating manganese dioxide ($MnO_2$) with aqueous hydrochloric acid according to the reaction $4 H…Preview

NCERT Exemplar

Higher-order thinking problems from the NCERT Exemplar.

+Show 45 questions45 questions
  1. Q1Two students performed the same experiment separately and each one of them recorded two readings of mass which are given below. Correct read…Free
  2. Q2A measured temperature on Fahrenheit scale is 200 °F. What will this reading be on Celsius scale? (i) 40 °C (ii) 94 °C (iii) 93.3 °C (iv) 30…Free
  3. Q3What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL? (i) $4\ \text{mol L}^{-1}$ (ii) $20\ \text{mol L}^{-1}…Free
  4. Q4If 500 mL of a 5M solution is diluted to 1500 mL, what will be the molarity of the solution obtained? (i) 1.5 M (ii) 1.66 M (iii) 0.017 M (i…Preview
  5. Q5The number of atoms present in one mole of an element is equal to Avogadro number. Which of the following element contains the greatest numb…Preview
  6. Q6If the concentration of glucose ($C_6H_{12}O_6$) in blood is $0.9\ \text{g L}^{-1}$, what will be the molarity of glucose in blood? (i) 5 M…Preview
  7. Q7What will be the molality of the solution containing 18.25 g of HCl gas in 500 g of water? (i) 0.1 m (ii) 1 M (iii) 0.5 m (iv) 1 mPreview
  8. Q8One mole of any substance contains $6.022 \times 10^{23}$ atoms/molecules. Number of molecules of $H_2SO_4$ present in 100 mL of 0.02M $H_2S…Preview
  9. Q9What is the mass percent of carbon in carbon dioxide? (i) 0.034% (ii) 27.27% (iii) 3.4% (iv) 28.7%Preview
  10. Q10The empirical formula and molecular mass of a compound are $CH_2O$ and 180 g respectively. What will be the molecular formula of the compoun…Preview
  11. Q11If the density of a solution is $3.12\ \text{g mL}^{-1}$, the mass of 1.5 mL solution in significant figures is ______. (i) 4.7 g (ii) $4680…Preview
  12. Q12Which of the following statements about a compound is incorrect? (i) A molecule of a compound has atoms of different elements. (ii) A compou…Preview
  13. Q13Which of the following statements is correct about the reaction given below: $4Fe(s) + 3O_2(g) \rightarrow 2Fe_2O_3(g)$ (i) Total mass of ir…Preview
  14. Q14Which of the following reactions is not correct according to the law of conservation of mass. (i) $2Mg(s) + O_2(g) \rightarrow 2MgO(s)$ (ii)…Preview
  15. Q15Which of the following statements indicates that law of multiple proportion is being followed. (i) Sample of carbon dioxide taken from any s…Preview
  16. Q16One mole of oxygen gas at STP is equal to ______. (Note: this is a multiple-correct question; two or more options may be correct.) (i) $6.02…Preview
  17. Q17Sulphuric acid reacts with sodium hydroxide as follows: $H_2SO_4 + 2NaOH \rightarrow Na_2SO_4 + 2H_2O$ When 1 L of 0.1M sulphuric acid solut…Preview
  18. Q18Which of the following pairs have the same number of atoms? (Note: this is a multiple-correct question; two or more options may be correct.)…Preview
  19. Q19Which of the following solutions have the same concentration? (Note: this is a multiple-correct question; two or more options may be correct…Preview
  20. Q2016 g of oxygen has same number of molecules as in (Note: this is a multiple-correct question; two or more options may be correct.) (i) 16 g…Preview
  21. Q21Which of the following terms are unitless? (Note: this is a multiple-correct question; two or more options may be correct.) (i) Molality (ii…Preview
  22. Q22One of the statements of Dalton's atomic theory is given below: "Compounds are formed when atoms of different elements combine in a fixed ra…Preview
  23. Q23What will be the mass of one atom of C-12 in grams?Preview
  24. Q24How many significant figures should be present in the answer of the following calculations? $\dfrac{2.5 \times 1.25 \times 3.5}{2.01}$Preview
  25. Q25What is the symbol for SI unit of mole? How is the mole defined?Preview
  26. Q26What is the difference between molality and molarity?Preview
  27. Q27Calculate the mass percent of calcium, phosphorus and oxygen in calcium phosphate $Ca_3(PO_4)_2$.Preview
  28. Q2845.4 L of dinitrogen reacted with 22.7 L of dioxygen and 45.4 L of nitrous oxide was formed. The reaction is given below: $2N_2(g) + O_2(g)…Preview
  29. Q29If two elements can combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element, a…Preview
  30. Q30Calculate the average atomic mass of hydrogen using the following data: Isotope $^1H$ — % Natural abundance: 99.985, Molar mass: 1 Isotope $…Preview
  31. Q31Hydrogen gas is prepared in the laboratory by reacting dilute HCl with granulated zinc. Following reaction takes place. $Zn + 2HCl \rightarr…Preview
  32. Q32The density of 3 molal solution of NaOH is $1.110\ \text{g mL}^{-1}$. Calculate the molarity of the solution.Preview
  33. Q33Volume of a solution changes with change in temperature, then, will the molality of the solution be affected by temperature? Give reason for…Preview
  34. Q34If 4 g of NaOH dissolves in 36 g of $H_2O$, calculate the mole fraction of each component in the solution. Also, determine the molarity of s…Preview
  35. Q35The reactant which is entirely consumed in reaction is known as limiting reagent. In the reaction $2A + 4B \rightarrow 3C + 4D$, when 5 mole…Preview
  36. Q36Match the following: (i) 88 g of $CO_2$ (ii) $6.022 \times 10^{23}$ molecules of $H_2O$ (iii) 5.6 litres of $O_2$ at STP (iv) 96 g of $O_2$…Preview
  37. Q37Match the following physical quantities with units: Physical quantity: (i) Molarity (ii) Mole fraction (iii) Mole (iv) Molality (v) Pressure…Preview
  38. Q38Assertion (A): The empirical mass of ethene is half of its molecular mass. Reason (R): The empirical formula represents the simplest whole n…Preview
  39. Q39Assertion (A): One atomic mass unit is defined as one twelfth of the mass of one carbon-12 atom. Reason (R): Carbon-12 isotope is the most a…Preview
  40. Q40Assertion (A): Significant figures for 0.200 is 3 where as for 200 it is 1. Reason (R): Zero at the end or right of a number are significant…Preview
  41. Q41Assertion (A): Combustion of 16 g of methane gives 18 g of water. Reason (R): In the combustion of methane, water is one of the products. Ch…Preview
  42. Q42A vessel contains 1.6 g of dioxygen at STP (273.15 K, 1 atm pressure). The gas is now transferred to another vessel at constant temperature,…Preview
  43. Q43Calcium carbonate reacts with aqueous HCl to give $CaCl_2$ and $CO_2$ according to the reaction given below: $CaCO_3(s) + 2HCl(aq) \rightarr…Preview
  44. Q44Define the law of multiple proportions. Explain it with two examples. How does this law point to the existance of atoms?Preview
  45. Q45A box contains some identical red coloured balls, labelled as A, each weighing 2 grams. Another box contains identical blue coloured balls,…Preview