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Exercises · 2.1

Q.(i) Calculate the number of electrons which will together weigh one gram.

(ii) Calculate the mass and charge of one mole of electrons.
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The mass of a single electron is 9.11×10−289.11 \times 10^{-28} g. To get one gram, we need about 1.098×10271.098 \times 10^{27} electrons. One mole of electrons has a mass of 5.486×10−45.486 \times 10^{-4} g (or 0.54860.5486 mg) and a charge of −96485-96485 C (one Faraday).


The key to both parts is knowing the mass and charge of a single electron. These are fundamental constants, and once you have them, the rest is just careful unit handling and using Avogadro's number.

Mass of one electron: me=9.11×10−28m_e = 9.11 \times 10^{-28} g (or 9.11×10−319.11 \times 10^{-31} kg).

Charge of one electron: e=−1.602×10−19e = -1.602 \times 10^{-19} C.

The negative sign on the charge tells us the direction of the force, but for calculations of magnitude, we often just use the absolute value 1.602×10−191.602 \times 10^{-19} C.


(i) Number of electrons weighing one gram

1. Set up the relation.

If one electron has mass mem_e, then NN electrons have total mass M=N×meM = N \times m_e. We want M=1M = 1 g.

2. Solve for NN.

N=Mme=1 g9.11×10−28 g/electronN = \frac{M}{m_e} = \frac{1 \text{ g}}{9.11 \times 10^{-28} \text{ g/electron}}

3. Do the division.

N=19.11×1028≈0.1098×1028=1.098×1027N = \frac{1}{9.11} \times 10^{28} \approx 0.1098 \times 10^{28} = 1.098 \times 10^{27}

So about 1.1×10271.1 \times 10^{27} electrons are needed to make one gram.

Watch out

A common mistake is to forget that the mass is in grams. If you use 9.11×10−319.11 \times 10^{-31} kg (the SI value), you must convert 1 g to 10−310^{-3} kg first. Doing that gives the same answer, but mixing units will give a wrong result.


(ii) Mass and charge of one mole of electrons

A mole is just a specific number of particles: NA=6.022×1023N_A = 6.022 \times 10^{23} particles per mole. So one mole of electrons means 6.022×10236.022 \times 10^{23} electrons.

1. Mass of one mole of electrons.

Multiply the mass of one electron by Avogadro's number:

Mmole=me×NA=(9.11×10−28 g)×(6.022×1023)M_{\text{mole}} = m_e \times N_A = (9.11 \times 10^{-28} \text{ g}) \times (6.022 \times 10^{23})

Mmole=(9.11×6.022)×10−28+23=54.86×10−5 gM_{\text{mole}} = (9.11 \times 6.022) \times 10^{-28+23} = 54.86 \times 10^{-5} \text{ g}

Mmole=5.486×10−4 gM_{\text{mole}} = 5.486 \times 10^{-4} \text{ g}

That's 0.54860.5486 milligrams — a tiny mass, as you'd expect for something as light as an electron.

Tip

You can also do this in kg: 9.11×10−31×6.022×1023=5.486×10−79.11 \times 10^{-31} \times 6.022 \times 10^{23} = 5.486 \times 10^{-7} kg. Same number, just different units.

2. Charge of one mole of electrons.

Multiply the charge of one electron by Avogadro's number:

Qmole=e×NA=(1.602×10−19 C)×(6.022×1023)Q_{\text{mole}} = e \times N_A = (1.602 \times 10^{-19} \text{ C}) \times (6.022 \times 10^{23})

Qmole=(1.602×6.022)×10−19+23=9.647×104 CQ_{\text{mole}} = (1.602 \times 6.022) \times 10^{-19+23} = 9.647 \times 10^{4} \text{ C}

Qmole=96470 CQ_{\text{mole}} = 96470 \text{ C}

This number is famous: it's the Faraday constant (FF), the charge carried by one mole of electrons. The accepted value is 9648596485 C/mol (our slight difference is due to rounding the constants).

F=e×NA=1.602×10−19×6.022×1023≈96485 C/molF = e \times N_A = 1.602 \times 10^{-19} \times 6.022 \times 10^{23} \approx 96485 \text{ C/mol}


✓Final answer

  1. 1.098×10271.098 \times 10^{27} electrons weigh one gram.
  2. One mole of electrons has a mass of 5.486×10−45.486 \times 10^{-4} g and a charge of −96485-96485 C (or +96485+96485 C if considering the magnitude).

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