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Chemistry · Ch 6 — Gaseous State

Compressibility factor for real gases

6.5.2

Compressibility factor for real gases

The compressibility factor can be rewritten in a form that makes its physical meaning even more direct. Starting from Z=PVrealnRTZ=\dfrac{PV_{real}}{nRT} (6.17), and noting that the ideal molar volume under the same P and T would be Videal=nRTPV_{ideal}=\dfrac{nRT}{P} (6.18), substituting (6.18) into (6.17) gives simply

Z=VrealVideal(6.19)Z=\frac{V_{real}}{V_{ideal}}\qquad(6.19) …