Skip to content

Chemistry · Ch 4 — Hydrogen

Uses of Hydrogen

4.4

Uses of Hydrogen

Hydrogen's uses span synthesis, metallurgy, energy and beyond:

  1. Ammonia synthesis (Haber process). Over 90% of the hydrogen produced industrially goes into synthetic applications, the single largest of which is the Haber process, used to manufacture ammonia at large scale:

N2+3 H2⇌380-450∘C200 atm/Fe2 NH3N_2 + 3\,H_2 \underset{200\ \text{atm/Fe}}{\overset{380\text{-}450^\circ C}{\rightleftharpoons}} 2\,NH_3

Ammonia made this way is, in turn, the feedstock for nitric acid, fertilizers and explosives.

  1. Methanol manufacture. Hydrogen is used to convert carbon monoxide into the industrial solvent methanol, over a copper catalyst:

CO+2 H2→CuCH3OHCO + 2\,H_2 \xrightarrow{Cu} CH_3OH

  1. Hydrogenation of oils. Unsaturated fatty oils are converted into saturated fats -- Vanaspati (margarine) -- by catalytic reduction with Pt/H₂.

  2. Metallurgy. At high temperatures, hydrogen reduces many metal oxides to the free metal:

CuO+H2→Cu+H2OCuO + H_2 \rightarrow Cu + H_2O

WO3+3 H2→W+3 H2OWO_3 + 3\,H_2 \rightarrow W + 3\,H_2O

  1. Cutting and welding. Atomic hydrogen and oxy-hydrogen torches, which burn at very high temperatures, are used for metal cutting and welding.

  2. Rocket fuel. Liquid hydrogen is used as a rocket propellant (Figure 4.3), burnt with liquid oxygen to deliver a very high energy release per unit mass.

  3. Fuel cells and hydrogen storage. Hydrogen is used in fuel cells to generate electrical energy directly and cleanly from the H₂ + O₂ → H₂O reaction. The same reversible-uptake behaviour of hydrogen in certain metals that makes metallic (interstitial) hydrides useful for storage (Section 4.8) is also attractive for rechargeable metal-hydride batteries. …

Figure 4.3Application of rocket fuel

What this figure shows. A photograph of a two-stage rocket (ISRO-style launch vehicle) lifting off its pad, with a bright orange exhaust flame at the base and a large plume of white smoke/steam billowing around the launch gantry; a clear blue sky and tree line form the background -- illustrating the use of liquid hydrogen …

Misc ~box-hydrogen-future-fuelThe Hydrogen -- Future Fuel

Worked out. An info box arguing that the depletion of fossil-fuel reserves and the threat of global warming are pushing the world toward alternative fuels, with hydrogen a strong candidate because it is clean-burning and produces no pollutants on combustion. It can be used directly (replacing petrol/diesel/kerosene engines) or indirectly with oxygen in fuel cells to generate electricity. The box is honest about the difficulties still to be overcome: production cost is high and still relies on fossil fuels; being volatile, flammable and the smallest molecule of all, hydrogen is hard to store and transport and is prone to leakage. Alongside is a schematic of a hydrogen fuel-cell vehicle powertrain: a Hydrogen Storage Tank feeds H2 gas across a metal interface into a Fuel Cell Stack, which powers a Power C …