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Chemistry · Ch 15 — Chemistry in Everyday Life

Detergents

15.3.2

Detergents

Synthetic detergents are manufactured products built from either the sodium salt of an alkyl hydrogen sulphate or the sodium salt of a long-chain alkyl benzene sulphonic acid, and they come in three distinct types depending on the charge carried by the cleaning (surfactant) ion. Anionic detergents carry a negatively charged head -- sodium lauryl sulphate (SLS) is the example, a twelve-carbon alkyl chain ending in a sulphate ester group. Cationic detergents instead carry a positively charged head -- n-hexadecyltrimethyl ammonium chloride is the example, a sixteen-carbon alkyl chain ending in a quaternary ammonium group. Non-ionic detergents carry no charge at all -- pentaerythrityl stearate is the example, an ester linking a fatty-acid chain to a polyol bearing free hydroxyl groups. …

Table 15.2Types of synthetic detergents

Detergent Type | Example

Anionic detergent | Sodium lauryl sulphate (SLS) -- a C12 alkyl chain terminating in a -OSO3- Na+ sulphate ester group.

Cationic detergent | n-hexadecyltrimethyl ammonium chloride (also named N,N,N-trimethylhexadecan-1-aminium chloride) -- a C16 alkyl chain terminating in a positively charged -N+(CH3)3 quaternary ammonium group, paired with a Cl- counter-ion. …