Q.(a)
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Start your 14-day free trial to unlock the full solution →(a) A mineral is any natural metal compound; only the subset that is economically extractable is an 'ore' — and in copper smelting, silica is added as a flux to remove the iron-oxide gangue as slag. (b) Boric acid has antiseptic/industrial uses, and silicates are the -tetrahedron-based mineral family.
(a)(i) Minerals vs. ores: A mineral is any naturally occurring inorganic substance, of a fairly definite chemical composition, found in the earth's crust. An ore is specifically that mineral (or mixture of minerals) from which a metal can be extracted conveniently and at a profit, using existing technology and current economics. So every ore is a mineral, but not every mineral is an ore — a mineral only becomes an ore when extraction from it is both technically feasible and commercially worthwhile (e.g. clay is a mineral of aluminium, but not an ore of it, since extraction is currently uneconomical; bauxite, by contrast, is both a mineral and the ore of aluminium).
(a)(ii) Role of silica in copper extraction: During the roasting/smelting of copper ores such as copper pyrites (), the iron present is oxidised to iron(II) oxide () as an unwanted gangue-derived impurity. Silica () is deliberately added as a flux; it combines with this FeO to form a low-melting, fusible slag of iron(II) silicate: Being less dense and immiscible with the molten copper matte (), this slag floats on top and is skimmed off, leaving the copper matte to be processed further (in the Bessemer converter) to blister copper.
OR (b)(i) Uses of boric acid: (1) as a mild antiseptic, in eye lotions/washes and as a mild disinfectant; (2) in the manufacture of borosilicate (heat-resistant) glass and enamels/glazes; (3) as a flux in soldering and metallurgical operations, helping to remove oxide films from metal surfaces; (4) for fireproofing wood and fabrics; (5) as a starting material for preparing other boron compounds (e.g. borax, boron nitride).
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