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Physics · Ch 8 — Atomic and Nuclear Physics

Determination of charge of an electron - Millikan's oil drop experiment

8.2.2

Determination of charge of an electron - Millikan's oil drop experiment

Once the specific charge e/me/m of the electron was known from Thomson's experiment, the next step was to measure the electron's actual charge ee itself. This was accomplished by R.A. Millikan using his celebrated oil drop experiment.

Apparatus. Two horizontal circular metal plates A and B, each about 20 cm in diameter and 1.5 cm apart, are enclosed in a glass-walled chamber and connected to a potential difference of about 10 kV, so the electric field between them points vertically. An atomizer sprays a fine mist of a highly viscous oil (such as glycerine) through a small hole in the upper plate; some droplets pick up a small negative charge from friction with air or from exposure to X-rays. The chamber is lit from the side, and a microscope perpendicular to the light lets an observer track a single chosen drop.

Step 1 - radius of the drop (field off). With the electric field switched off, the drop falls under gravity, opposed by buoyancy and by Stokes' viscous drag, quickly reaching a constant terminal velocity vv. Balancing forces, Fg=Fb+FvF_g=F_b+F_v, i.e. 43πr3ρg=43πr3σg+6πrηv\tfrac{4}{3}\pi r^3\rho g=\tfrac{4}{3}\pi r^3\sigma g+6\pi r\eta v (where ρ\rho is the oil's density, σ\sigma the density of air and η\eta the viscosity of air), gives the droplet's radius:

r=[9ηv2g(ρ−σ)]1/2(8.11)r=\left[\frac{9\eta v}{2g(\rho-\sigma)}\right]^{1/2}\qquad (8.11)

Step 2 - charge of the drop (field on). The field is switched on and adjusted so the same drop hovers stationary in the field of view, meaning there is no viscous force and the net upward electric force exactly balances the drop's weight minus buoyancy: qE=43πr3(ρ−σ)gqE=\tfrac{4}{3}\pi r^3(\rho-\sigma)g, so

q=4πr3(ρ−σ)g3E(8.12)q=\frac{4\pi r^3(\rho-\sigma)g}{3E}\qquad (8.12)

Substituting the radius found in Step 1 gives the working formula

q=18π[η3v32g(ρ−σ)]1/21Eq=18\pi\left[\frac{\eta^3v^3}{2g(\rho-\sigma)}\right]^{1/2}\frac{1}{E} …

Figure 8.6Millikan's experiment (a) real picture and schematic picture (b) side view picture

What this figure shows. This figure shows the Millikan apparatus: two horizontal circular metal plates A and B, each about 20 cm in diameter and separated by roughly 1.5 cm, enclosed in a glass-walled chamber, with an atomizer above a small hole in the upper plate to spray a fine mist of viscous oil, a light source illuminating the chamber horizontally, and a microscope placed perpendicular to the light beam so individual oil droplets can be tracked. Part (a) shows the physical apparatus and its schematic circuit, while part (b) is a side-view diagram highlighting how the plates A and B are connected to a high potential difference of about 10 kV so that the electric field between them acts vertically. This is the setup within which individual charged oil drops were made to rise, fall, or h …

Figure 8.7Free body diagram of the oil drop - (a) without electric field (b) with electric field

What this figure shows. This figure shows the forces acting on a single oil droplet in the two stages of the experiment: in (a), with the electric field switched off, the droplet falls under gravity (F_g downward) opposed by the buoyant force F_b and the viscous drag force F_v (both upward), and it quickly reaches a constant terminal velocity; in (b), with the electric field switched on and adjusted so the chosen droplet is held stationary, the upward electric force F_e on the droplet's charge exactly balances the combined downward gravitational force and the (now absent, since velocity is zero) viscous force, so only F_e, F_g and F_b remain in equilibrium. Comparing the force balance in these two diagrams is exactly how Millikan's two governing equations - one for the drop's radius from its terminal fall, and one for it …