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NCERT Exemplar · Q8

Q.The number of radial nodes for 3p orbital is __________.

(i) 3
(ii) 4
(iii) 2
(iv) 1
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Radial nodes depend only on nn and ℓ\ell, following the formula (n−ℓ−1)(n - \ell - 1). For a 3p orbital, n=3n = 3 and ℓ=1\ell = 1, giving 1 radial node.

The wave function of an electron in an atom has regions where its probability density drops to zero. These zeros come in two flavors: radial nodes (spherical surfaces where the radial part vanishes) and angular nodes (planes or cones where the angular part vanishes). The question asks specifically about radial nodes.

Every orbital is labeled by two quantum numbers that matter here: the principal quantum number nn (the "shell") and the azimuthal quantum number ℓ\ell (the "subshell type"). For a p orbital, ℓ=1\ell = 1; for a 3p orbital, n=3n = 3.

Number of radial nodes=n−ℓ−1\text{Number of radial nodes} = n - \ell - 1

This formula captures a beautiful pattern: as you move to higher shells with the same subshell type, you add radial nodes—regions where the wave function oscillates through zero as you move outward from the nucleus.

Let me show you why this makes physical sense before we calculate.

The total number of nodes in any orbital is always n−1n - 1. These nodes split into two types:

  • Angular nodes: determined entirely by ℓ\ell, always equal to ℓ\ell
  • Radial nodes: the remainder, equal to (n−1)−ℓ=n−ℓ−1(n - 1) - \ell = n - \ell - 1

For a 3p orbital specifically:

  1. Identify the quantum numbers: The "3" tells us n=3n = 3, and "p" tells us ℓ=1\ell = 1.

  2. Apply the radial node formula: …

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