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Worked Examples · Example 10.4

Q.Why does the solubility of alkaline earth metal hydroxides in water increase down the group?

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✓ Free question

Step 1: Recall what governs solubility

Dissolution of an ionic solid is favoured when the hydration enthalpy released is comparable to or exceeds the lattice enthalpy that must be overcome.

Step 2: Compare how each term changes down the group

As we move from Be(OH)2_2 to Ba(OH)2_2, the cationic radius increases steadily, while the OH−^- ion stays the same (small) size. For such a small, fixed-size anion paired with a growing cation, the lattice enthalpy falls off sharply with increasing cationic size, whereas the hydration enthalpy of the cation falls off more gradually.

Step 3: Net effect

Since lattice enthalpy decreases faster than hydration enthalpy down the group, the energy balance becomes progressively more favourable for dissolution.

✓Final answer

Solubility of Group 2 hydroxides increases down the group (Be(OH)2_2 least soluble, Ba(OH)2_2 most soluble) because lattice enthalpy falls faster than hydration enthalpy as the cation grows.

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