Q.Why does the solubility of alkaline earth metal hydroxides in water increase down the group?
Step 1: Recall what governs solubility
Dissolution of an ionic solid is favoured when the hydration enthalpy released is comparable to or exceeds the lattice enthalpy that must be overcome.
Step 2: Compare how each term changes down the group
As we move from Be(OH) to Ba(OH), the cationic radius increases steadily, while the OH ion stays the same (small) size. For such a small, fixed-size anion paired with a growing cation, the lattice enthalpy falls off sharply with increasing cationic size, whereas the hydration enthalpy of the cation falls off more gradually.
Step 3: Net effect
Since lattice enthalpy decreases faster than hydration enthalpy down the group, the energy balance becomes progressively more favourable for dissolution.
Solubility of Group 2 hydroxides increases down the group (Be(OH) least soluble, Ba(OH) most soluble) because lattice enthalpy falls faster than hydration enthalpy as the cation grows.
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