Skip to content

Chemistry · Ch 11 — The Solid State

Packing Efficiency in Simple Cubic Lattice

11.7.3

Packing Efficiency in Simple Cubic Lattice

In a simple cubic lattice the atoms sit only at the corners of the cube and touch each other along the edge (Fig. 1.26). So the edge length aa and the radius rr are related by:

a=2ra = 2r

The volume of the cubic unit cell is:

a3=(2r)3=8r3a^3 = (2r)^3 = 8r^3

A simple cubic unit cell contains only 1 atom, whose volume is 43πr3\tfrac{4}{3}\pi r^3. Hence:

Packing efficiency=43πr38r3×100=π6×100=52.36%≈52.4%\text{Packing efficiency} = \frac{\frac{4}{3}\pi r^3}{8r^3} \times 100 = \frac{\pi}{6} \times 100 = 52.36\% \approx 52.4\% …

Figure 1.26Simple cubic unit cell. The spheres are in contact with each other along the edge of the cube.

What this figure shows. A simple cubic unit cell with eight corner spheres shown in contact along the cube edge, illustrating a = 2r used in the simple-cubic packing-efficiency derivation (52.4%). …