Q.In a nuclear reactor, moderators slow down the neutrons which come out in a fission process. The moderator used have light nuclei. Heavy nuclei will not serve the purpose because
Concept understanding — Rutherford Scattering Distance
Rutherford Scattering Distance – From Intuition to Precision
Imagine you are firing a tiny, fast bullet at a large, heavy cannonball hidden inside a big cloud of cotton. Most bullets zip right through the cotton, barely slowing down. But a few bullets come very close to the cannonball itself. Those bullets get deflected sharply, sometimes even bouncing back.
The Rutherford scattering distance is the answer to this question: How close did that bullet get to the cannonball before it turned around?
In the real experiment, the "bullet" is an alpha particle (a helium nucleus, positively charged), the "cannonball" is the gold nucleus (also positively charged, and very heavy), and the "cotton" is the mostly empty space inside the gold atom. The alpha particle and the gold nucleus repel each other because both are positive. The closer the alpha particle gets, the stronger the repulsion.
The Intuitive Picture
Think of a ball rolling up a steep hill. The ball starts with some speed (kinetic energy). As it climbs, it slows down because gravity is pulling it back. At the very top of its climb, it stops for an instant — all its kinetic energy has been converted into gravitational potential energy. Then it rolls back down.
The alpha particle does the same thing, but with electric repulsion instead of gravity. It approaches the nucleus, slows down, stops at the closest possible point, and then flies back the way it came.
That closest point — the distance of closest approach — is the Rutherford scattering distance. It is the distance at which the alpha particle's initial kinetic energy is completely converted into electrostatic potential energy.
This distance is not the radius of the nucleus. It is the distance at which the alpha particle would just touch the nucleus if the nucleus were a point charge. In reality, the alpha particle never actually reaches the nucleus — it turns around before that.
The Precise Statement
Let an alpha particle with charge +2e and mass m approach a gold nucleus with charge +Ze (where Z=79 for gold). The alpha particle starts from very far away with initial kinetic energy K=21mv2.
At the distance of closest approach, call it r0, the alpha particle's speed becomes zero. All its kinetic energy has become electrostatic potential energy:
K=4πε01⋅r0(2e)(Ze)
Solving for r0:
r0=4πε01⋅K2Ze2
This is the Rutherford scattering distance (also called the distance of closest approach in a head-on collision).
What It Tells Us
- If the alpha particle hits the nucleus head-on, it comes exactly this close before reversing direction.
- If it misses slightly, it comes closer than r0? No — it comes less close. The head-on collision gives the minimum possible distance of closest approach for a given initial energy. Any sideways motion means the particle never gets as close.
- If the initial kinetic energy is larger, r0 becomes smaller — the alpha particle can punch closer to the nucleus before being stopped.
Do not confuse this with the impact parameter (the perpendicular distance from the nucleus to the initial line of motion). The impact parameter is a different quantity — it tells you how "off-center" the collision is. The Rutherford scattering distance r0 is the actual closest distance achieved during the collision, which depends on both the impact parameter and the initial energy.
A Quick Numerical Feel
For a typical alpha particle from radioactive decay (kinetic energy about 5 MeV) and a gold nucleus (Z=79):
r0≈5×106⋅1.6×10−199×109⋅2⋅79⋅(1.6×10−19)2≈4.5×10−14 m
That's about 45 femtometers — roughly 10,000 times smaller than the atom itself. This tiny number was the first direct evidence that the positive charge in an atom is concentrated in an incredibly small nucleus.
The Key Takeaway
Rutherford scattering distance is the distance at which an alpha particle, approaching a nucleus head-on, comes to a complete stop and reverses direction. It is given by:
r0=4πε01⋅K2Ze2
It is the minimum possible distance of closest approach for a given initial kinetic energy, and it revealed that the atom's positive charge is packed into a volume far smaller than the atom itself.
The distance of closest approach in Rutherford scattering is a classic numerical from the NCERT Class 12 Physics chapter on Atoms, regularly appearing in "Rutherford scattering distance of closest approach formula" searches and in JEE Main/NEET important-questions compilations on atomic structure. Mastering this derivation also builds the groundwork for later problems on nuclear size and the scale of the atom covered in the same chapter.
Why this formula?
Rutherford Scattering: Why the Distance of Closest Approach Formula Works
The distance of closest approach — often denoted d0 or r0 — is the minimum separation between an alpha particle and the nucleus in a head-on collision. It's a beautiful example of energy conservation doing all the heavy lifting.
The Physical Picture
Imagine an alpha particle (charge +2e) fired straight at a gold nucleus (charge +Ze). As it approaches, the Coulomb repulsion slows it down. At the point of closest approach, the alpha particle's radial velocity becomes zero — it stops moving toward the nucleus, and is about to turn around and fly back.
At that instant, all the kinetic energy it had at infinity has been converted into electrostatic potential energy. No other forces are at play (gravity is negligible, and we're far from the nuclear force range).
The Derivation in One Step
Let the alpha particle have initial kinetic energy K=21mv2 at a large distance (where potential energy is zero). At the distance of closest approach r0, its speed is zero, so kinetic energy is zero. Energy conservation gives:
21mv2=4πϵ01⋅r0(2e)(Ze)
r0=4πϵ01⋅K2Ze2
That's it. The formula is a direct consequence of energy conservation in a pure Coulomb field.
Why This Makes Physical Sense
- Higher kinetic energy → the alpha particle can push closer before being stopped → r0 is smaller.
- Higher nuclear charge Z → stronger repulsion → the alpha stops farther away → r0 is larger.
- The factor 2Ze2 comes from the product of charges: (2e)(Ze)=2Ze2.
This is the head-on distance. For non-head-on collisions (nonzero impact parameter), the distance of closest approach is larger because some energy remains in the perpendicular component of motion. The general formula involves the impact parameter b and scattering angle θ, but the head-on case gives the absolute minimum possible approach.
A Common Misconception
Students sometimes think the alpha particle "hits" the nucleus at r0. It doesn't — it's turned around purely by the electric field. The fact that Rutherford's experiment did see some alpha particles bounce back at large angles (implying they got very close) is what told him the nucleus must be extremely small — smaller than r0 for those particles. If the nucleus were larger, the alpha would have hit it and the scattering pattern would have been different.
The formula r0=4πϵ0K2Ze2 assumes the nucleus is point-like and stationary. In reality, the nucleus recoils slightly, so the reduced mass should technically be used. But for gold (A≈197) vs alpha (A=4), the correction is tiny — less than 2%.
The Deeper Insight
Rutherford didn't just measure r0 — he used it to set an upper limit on nuclear size. By observing that alpha particles with kinetic energy K were still being scattered (not absorbed), he knew the nucleus must be smaller than the corresponding r0. This gave the first experimental evidence that the atom's positive charge is concentrated in a region less than 10−14 m across — a thousand times smaller than the atom itself.
That's why this simple energy-conservation formula is historically monumental: it opened the door to the nuclear age.
The key idea is that in an elastic collision, a neutron transfers maximum kinetic energy to a target of comparable mass. A light nucleus (like hydrogen or carbon) has a mass close to that of a neutron, so the neutron loses a large fraction of its energy per collision. A heavy nucleus, being much more massive, recoils very little — the neutron bounces off with nearly its original speed, so it does not slow down effectively.
Step 1: For a head-on elastic collision, the fraction of energy lost by the neutron is (m1+m2)24m1m2, where m1 is the neutron mass and m2 the target mass.
Step 2: If m2≫m1, this fraction approaches 4m1/m2≈0 — negligible slowing.
Step 3: Only light nuclei give a significant energy transfer per collision, making them effective moderators.
The correct option is (B): elastic collision of neutrons with heavy nuclei will not slow them down.
The key idea is that in an elastic collision, a neutron transfers maximum kinetic energy to a target of comparable mass. Heavy nuclei absorb very little energy per collision, so they cannot effectively slow (moderate) neutrons. The correct option is (B).
The question is about moderation — the process of slowing down fast neutrons produced in fission so they can sustain a chain reaction. A moderator must reduce neutron speed efficiently without absorbing them. The physics here is purely about elastic collisions and energy transfer.
Let’s walk through why heavy nuclei fail.
- The physics of a single elastic collision When a neutron (mass m) collides elastically with a stationary nucleus (mass M), the fraction of kinetic energy lost by the neutron depends only on the mass ratio. For a head-on collision (maximum energy transfer), the neutron’s final kinetic energy Ef is related to its initial energy Ei by:
Ef=(M+mM−m)2Ei
The energy transferred to the nucleus is:
ΔE=Ei−Ef=[1−(M+mM−m)2]Ei=(M+m)24MmEi
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Why light nuclei are effective
If M≈m (e.g., hydrogen, where M=1 u, m≈1 u), then ΔE≈Ei — the neutron can lose almost all its energy in one collision. For deuterium (M=2 u) or carbon (M=12 u), the energy loss per collision is still substantial. This is why light elements like hydrogen (in water), deuterium (in heavy water), and carbon (in graphite) are used as moderators.
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Why heavy nuclei fail
If M≫m (e.g., lead, M=207 u), then:
ΔE≈M4mEi
which is a tiny fraction. For lead, ΔE≈2074Ei≈0.019Ei — less than 2% per collision. To slow a neutron from fission energy (~2 MeV) to thermal energy (~0.025 eV), you would need thousands of collisions, making moderation impractical. The neutron would likely be absorbed or escape before slowing down.
A common mistake is to think heavy nuclei “break up” or that the issue is about state of matter. Option (A) is wrong because elastic collisions do not cause nuclear breakup at these energies. Option (C) is irrelevant — weight is a design issue, not a physics principle. Option (D) is false (e.g., lead is liquid at reactor temperatures, and many heavy elements exist as gases or liquids).
- The correct reasoning The moderator’s job is to slow neutrons via elastic collisions. Heavy nuclei absorb too little energy per collision to be effective. This is a direct consequence of conservation of momentum and energy in elastic collisions — no other physics is needed.
The correct option is (B) — elastic collision of neutrons with heavy nuclei will not slow them down.
Method: Analyzing Energy Transfer in an Elastic Collision (Moderator Selection)
Use this whenever a question asks how effectively a moving particle transfers kinetic energy to a stationary target via an elastic collision — the classic "which material makes a good moderator/absorber" type question.
Steps
Step 1: Write the general formula for energy transfer in a head-on elastic collision
For a particle of mass m (here, a neutron) striking a stationary target of mass M head-on, the fraction of kinetic energy transferred to the target is
EiΔE=(m+M)24mM.
This single formula governs every "how much energy does the projectile lose" question of this type.
Step 2: Examine the two limiting cases
- If M≈m (comparable masses), the fraction approaches its maximum value, close to 1 — the projectile can lose almost all its energy in a single collision.
- If M≫m (target much heavier than projectile), the fraction shrinks to approximately M4m, which is small — the projectile barely slows down, bouncing off with nearly its original speed (think of a ball bouncing off a wall).
Step 3: Apply the limiting case to the physical scenario
Decide which regime the problem describes. If the target nuclei are much heavier than the projectile (e.g. heavy nuclei absorbing fast neutrons), very little energy is transferred per collision, so many collisions would be needed to achieve significant slowing — often impractically many before the projectile is absorbed or escapes.
Step 4: Match to the qualitative conclusion
Use the scaling from Step 2 to decide whether the proposed material would be an effective or ineffective moderator/energy-absorber, and select the option that correctly attributes this to the physics of elastic-collision energy transfer (not to unrelated properties like weight, state of matter, or structural breakup).
Showing the 12 most recent of 16 on this concept.
- TG EAPCET 2026Set eng-2026-05-10-AN1 markMCQQ.In terms of Planck’s constant (h), permittivity of free space (ε0), mass of the electron (m) and charge of the electron (e), the de Broglie wavelength associated with the electron in the second orbit of hydrogen atom is (A) 2me2h2ε0 (B) 4me2h2ε0 (C) me22h2ε0 (D) me24h2ε0
›Reveal solutionSolution
The de Broglie wavelength for an electron in the second Bohr orbit is found by combining the Bohr radius formula with the quantization of angular momentum. The result simplifies to me24h2ε0, which corresponds to option (D).
The key idea is that de Broglie wavelength λ=h/p requires the electron’s momentum. In the Bohr model, the electron’s orbit is quantized: the angular momentum in the n-th orbit is mvr=nℏ. For the second orbit (n=2), we can find v and then p=mv. But we also need the radius r for that orbit, which comes from balancing Coulomb force and centripetal force. Combining these gives a clean expression for λ in terms of the given constants.
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Write the de Broglie relation
The wavelength is λ=ph, where p=mv is the momentum. So we need v for the electron in the second orbit.
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Bohr’s quantization of angular momentum
For the n-th orbit: mvr=n2πh. For n=2:
mvr=2π2h=πh.
Hence, v=πmrh.
- Find the radius of the second orbit The Coulomb force provides the centripetal acceleration:
4πε01r2e2=rmv2.
Substitute v from step 2:
4πε0r2e2=rm(πmrh)2=π2mr3h2.
Multiply both sides by r3:
4πε0e2r=π2mh2.
Solve for r:
r=π2me24πε0h2=πme24ε0h2.
This is the radius for n=2. (For reference, the Bohr radius a0=me24πε0ℏ2 and here r=4a0, as expected for the second orbit.)
- Compute the momentum From step 2: v=πmrh. So
p=mv=πrh.
Substitute r from step 3:
p=πh⋅4ε0h2πme2=4ε0hme2.
- Find the de Broglie wavelength
λ=ph=h⋅me24ε0h=me24h2ε0.
Watch outA common mistake is to use the ground-state radius (n=1) instead of the second orbit. Remember that the radius scales as n2, so for n=2 it is four times the Bohr radius. Using the wrong radius gives a different factor.
TipYou can also get this result faster by recalling that in the n-th Bohr orbit, the circumference equals n de Broglie wavelengths: 2πr=nλ. For n=2, λ=πr. Then just plug in the expression for r in the second orbit. This avoids computing momentum explicitly.
✓Final answerThe correct option is (D).
ANSWER: D
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- TG EAPCET 2026Set eng-2026-05-11-AN1 markMCQQ.If an electron initially at rest is subjected to a uniform electric field of 4125NC−1, then the de Broglie wavelength associated with the electron at time t=2×10−9 s is (Planck’s constant =6.6×10−34 Js) (A) 12 A˚ (B) 2 A˚ (C) 10 A˚ (D) 5 A˚
›Reveal solutionSolution
Momentum gained p=eEt=1.32×10−24kg m/s, so λ=h/p=5A˚.
Force on the electron in the field:
F=eE=(1.6×10−19)(4125)=6.6×10−16N
Starting from rest, the momentum after time t is p=Ft:
p=(6.6×10−16)(2×10−9)=1.32×10−24kg m/s
The de Broglie wavelength is
λ=ph=1.32×10−246.6×10−34=5×10−10m=5A˚
✓Final answerλ=5A˚ — option (D)
- TG EAPCET 2025Set eng-2025-05-04-AN1 markMCQQ.The maximum wavelength of incident radiation required to ionize a hydrogen atom in its ground state is nearly (A) 912 nm (B) 1215 A˚ (C) 912 A˚ (D) 1215 nm
›Reveal solutionSolution
The key idea is that ionization from the ground state requires energy equal to the Rydberg constant (13.6 eV), and the maximum wavelength corresponds to the minimum energy photon, given by λmax=13.6 eVhc≈912 A˚. The correct option is (C).
The concept here is the photoelectric effect for atomic ionization: a photon must have at least the binding energy of the electron to remove it. For hydrogen in its ground state, that binding energy is 13.6 eV. The maximum wavelength that can still ionize comes from the minimum photon energy that does the job — because wavelength and energy are inversely related (E=hc/λ). So we just convert 13.6 eV into a wavelength.
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Recall the ground-state ionization energy of hydrogen.
From the Bohr model, the energy of the n=1 level is E1=−13.6 eV. To ionize, the electron must gain +13.6 eV. So the minimum photon energy needed is Emin=13.6 eV.
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Relate photon energy to wavelength.
The energy of a photon is E=λhc, where h is Planck’s constant and c is the speed of light. For the maximum wavelength, we use the minimum energy:
λmax=Eminhc.
- Plug in constants in convenient units. A classic shortcut: hc=1240 eV⋅nm (or 12400 eV⋅A˚). Using eV·nm:
λmax=13.6 eV1240 eV⋅nm≈91.2 nm.
Since 1 nm=10 A˚, this is 912 A˚.
- Match with the options.
- (A) 912 nm — too large by a factor of 10.
- (B) 1215 Å — that’s the Lyman-alpha line (transition from n=2 to n=1), not ionization.
- (C) 912 Å — correct.
- (D) 1215 nm — also too large and corresponds to a different transition.
Watch outA common mistake is to confuse ionization (removing the electron entirely) with excitation (moving it to a higher orbit). The Lyman series limit is indeed 912 Å, but that’s the same as the ionization threshold from the ground state — so here it’s correct. However, 1215 Å is a specific spectral line, not the ionization limit.
TipMemorize the pair: 13.6 eV ↔ 912 Å. This is one of the most useful constants in atomic physics. Also, remember that hc=1240 eV⋅nm makes quick conversions a breeze.
✓Final answerThe correct option is (C).
ANSWER: C
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- TG EAPCET 2025Set eng-2025-05-04-FN1 markMCQQ.The maximum wavelength of incident radiation required to ionize a hydrogen atom in its ground state is nearly (A) 912A˚ (B) 912nm (C) 1215nm (D) 1215A˚
›Reveal solutionSolution
The ionization energy of hydrogen in the ground state is 13.6 eV, which corresponds to a photon of wavelength 912 Å. The correct option is (A).
The key idea here is that ionization means removing the electron from the atom entirely — taking it from the ground state (n = 1) to a free state (n = ∞). The energy required for this is exactly the ionization energy of hydrogen, which is a well-known constant: 13.6 eV. The maximum wavelength that can cause ionization corresponds to the minimum energy photon that can do the job — because wavelength and energy are inversely related. So we just need to find the wavelength of a photon carrying exactly 13.6 eV.
- Recall the ionization energy of hydrogen in its ground state. For hydrogen, the energy of the nth level is
En=−n213.6 eV
For the ground state, n = 1, so
E1=−13.6 eV
Ionization means taking the electron to n = ∞, where energy is 0 eV. The energy needed is
ΔE=E∞−E1=0−(−13.6)=13.6 eV
- Relate this energy to the wavelength of the incident photon. The photon energy is given by
E=λhc
where h = Planck’s constant, c = speed of light. We want the maximum λ, which means the smallest E that still works — that’s exactly 13.6 eV. So
λ=Ehc
- Plug in the constants in convenient units. A very handy combination to remember:
hc=1240 eV⋅nm
(This is exact enough for exam purposes: 1240 eV·nm, or equivalently 12400 eV·Å, since 1 nm = 10 Å.)
So
λ=13.6 eV1240 eV⋅nm≈91.18 nm
But 91.18 nm = 911.8 Å, which rounds to 912 Å.
TipMemorize the pair: 13.6 eV ↔ 912 Å. This is a classic shortcut — the ionization wavelength of hydrogen in the ground state is always 912 Å (or 91.2 nm). It saves time in multiple-choice questions.
- Check the options.
- (A) 912 Å — matches our calculation.
- (B) 912 nm — that’s 9120 Å, far too large.
- (C) 1215 nm — that’s the wavelength of the Lyman-α line (n=2 → n=1), not ionization.
- (D) 1215 Å — also the Lyman-α line in angstroms.
Watch outA common mistake is to confuse the ionization wavelength (912 Å) with the first Lyman line (1216 Å). Remember: ionization is from n=1 to n=∞, while Lyman-α is from n=2 to n=1. They are different transitions.
✓Final answerThe maximum wavelength is 912 Å, so the correct option is (A).
- TG EAPCET 2025Set eng-2025-05-04-FN1 markMCQQ.A proton moving with a velocity of 8×105 ms−1 enters a uniform magnetic field normal to the direction of the magnetic field. If the radius of the circular path of the proton in the magnetic field is 8.3 cm, then the magnitude of the magnetic field is (Charge of proton =1.6×10−19 C and mass of the proton =1.66×10−27 kg) (A) 400 mT (B) 500 mT (C) 100 mT (D) 200 mT
›Reveal solutionSolution
A charge moving perpendicular to a uniform magnetic field experiences a centripetal force from the field. Equating qvB=rmv2 gives B=qrmv. Substituting the given numbers yields B=0.1 T=100 mT, so option (C) is correct.
The key idea is that when a charged particle enters a magnetic field at right angles, the magnetic force acts as a centripetal force, bending the particle into a circle. The radius of that circle depends on the particle's mass, speed, charge, and the field strength. If you know any three, you can find the fourth.
Here, we know the radius, speed, mass, and charge — so we solve for the magnetic field.
- Write the force balance. The magnetic force on a moving charge is FB=qvB (since the velocity is perpendicular to the field, sin90∘=1). This force provides the centripetal force needed for circular motion: Fc=rmv2. Set them equal:
qvB=rmv2
- Cancel and rearrange. The speed v cancels from both sides (one factor of v):
qB=rmv
So the magnetic field is:
B=qrmv
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Plug in the values with consistent units.
- m=1.66×10−27 kg
- v=8×105 m/s
- q=1.6×10−19 C
- r=8.3 cm=8.3×10−2 m
Substitute:
B=(1.6×10−19)(8.3×10−2)(1.66×10−27)(8×105)
- Simplify step by step. First, the numerator:
1.66×8=13.28,so13.28×10−22
(because 10−27×105=10−22)
Denominator:
1.6×8.3=13.28,so13.28×10−21
(because 10−19×10−2=10−21)
So:
B=13.28×10−2113.28×10−22=10−1 T=0.1 T
- Convert to millitesla. 0.1 T=100 mT.
Watch outA common mistake is forgetting to convert centimetres to metres. The radius is given as 8.3 cm, which is 0.083 m, not 8.3 m. Using r=8.3 without conversion would give a wildly wrong answer.
✓Final answerThe magnitude of the magnetic field is 100 mT, which corresponds to option (C).
- TG EAPCET 2025Set ap-2025-04-30-FN1 markMCQQ.An electron moving along a straight line with a velocity of 6.4×107 ms−1 is subjected to a magnetic field of 3 mT. If the magnetic field is applied perpendicular to the direction of the initial path of the electron, then the radius of the circular path in which the electron moves under the influence of the magnetic field is (Mass of electron =9×10−31 kg and charge of the electron =1.6×10−19 C) (A) 30 cm (B) 12 cm (C) 24 cm (D) 36 cm
›Reveal solutionSolution
A perpendicular magnetic field provides the centripetal force for circular motion. Equating qvB=rmv2 gives r=qBmv, which evaluates to 12 cm.
The key idea is that when a charged particle enters a uniform magnetic field perpendicular to its velocity, the magnetic force acts as a centripetal force. The magnetic force F=qvB is always perpendicular to both v and B, so it does no work and only changes the direction of velocity — not its magnitude. This perfectly matches the requirement for uniform circular motion, where the net force points radially inward.
The centripetal force needed to keep a mass m moving at speed v in a circle of radius r is Fc=rmv2. Setting this equal to the magnetic force gives the equation that determines the radius.
- Write the force balance equation The magnetic force provides the centripetal force:
qvB=rmv2
- Cancel one factor of v (since v=0):
qB=rmv
- Solve for the radius r:
r=qBmv
- Substitute the given values — but watch the units carefully. The magnetic field is given in millitesla: B=3 mT=3×10−3 T.
r=(1.6×10−19 C)×(3×10−3 T)(9×10−31 kg)×(6.4×107 m/s)
- Simplify step by step First, the numerator: 9×6.4=57.6, and 10−31×107=10−24, so numerator = 57.6×10−24. Denominator: 1.6×3=4.8, and 10−19×10−3=10−22, so denominator = 4.8×10−22.
r=4.8×10−2257.6×10−24=4.857.6×10−2
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Calculate the numerical factor: 4.857.6=12.
So r=12×10−2 m=0.12 m.
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Convert to centimetres: 0.12 m=12 cm.
Watch outA common mistake is forgetting to convert millitesla to tesla. Using B=3 instead of 3×10−3 would give r=0.12 m×1000=120 m, which is absurdly large and not among the options. Always check units before plugging in.
TipNotice that the mass and charge of the electron are standard values that often appear in such problems. The formula r=qBmv is worth remembering directly — it saves time and reduces algebraic errors.
✓Final answerThe radius of the circular path is 12 cm, which corresponds to option (B).
- TG EAPCET 2025Set ap-2025-04-30-FN1 markMCQQ.If the potential energy of an electron in an orbit of hydrogen atom is −6.80 eV, then the energy required to ionize the atom is (A) 6.80 eV (B) 13.6 eV (C) 3.40 eV (D) 10.2 eV
›Reveal solutionSolution
The ionization energy of a hydrogen atom is the negative of its total energy. Given the potential energy, we first find the total energy and then the ionization energy. The energy required to ionize the atom is 3.40 eV.
The problem asks for the energy required to ionize a hydrogen atom, given the potential energy of its electron. To solve this, we need to understand the relationships between potential energy, kinetic energy, and total energy for an electron in a stable orbit within a hydrogen atom, as described by the Bohr model.
Concept and Intuition
In the Bohr model of a hydrogen atom, an electron orbits the nucleus under the influence of the electrostatic force. This system has both kinetic energy (due to the electron's motion) and potential energy (due to the electrostatic attraction between the electron and the proton).
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Potential Energy (U): This is the energy associated with the electron's position in the electric field of the nucleus. For an electron at a distance r from a proton, the potential energy is given by U=−rke2, where k is Coulomb's constant and e is the elementary charge. The negative sign indicates an attractive force and that the electron is bound to the nucleus.
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Kinetic Energy (K): This is the energy associated with the electron's motion. For a stable orbit, the electrostatic force provides the necessary centripetal force. This leads to a relationship where the kinetic energy is K=2rke2.
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Total Energy (E): The total energy of the electron in its orbit is the sum of its kinetic and potential energies: E=K+U.
Substituting the expressions for K and U:
E=2rke2−rke2=−2rke2.
From these expressions, we can establish crucial relationships:
- K=−E
- U=2E
- U=−2K
ImportantFor an electron in a stable orbit of a hydrogen atom, the potential energy (U), kinetic energy (K), and total energy (E) are related by:
U=2E
K=−E
Ionization Energy:
Ionization energy is defined as the minimum energy required to remove an electron from its orbit in an atom and take it to an infinite distance, where it is no longer bound to the nucleus. At an infinite distance, the electron is considered to be at rest and free, meaning its total energy is zero (Efinal=0).
Therefore, the ionization energy is the difference between the final energy (zero) and the initial total energy (E) of the electron in its orbit:
Ionization Energy =Efinal−Einitial=0−E=−E.
So, if we know the total energy of the electron in its orbit, the ionization energy is simply the negative of that total energy.
Step-by-step Solution
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Identify the given information:
We are given the potential energy of the electron in an orbit of a hydrogen atom:
U=−6.80 eV
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Use the relationship between potential energy and total energy:
We know that for an electron in a hydrogen atom, the potential energy is twice the total energy:
U=2E
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Calculate the total energy (E):
Substitute the given potential energy into the relationship:
−6.80 eV=2E
E=2−6.80 eV
E=−3.40 eV
This is the total energy of the electron in its current orbit. The negative sign indicates that the electron is bound to the nucleus.
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Calculate the ionization energy:
The ionization energy is the energy required to remove the electron from this orbit to infinity, which is the negative of the total energy:
Ionization Energy =−E
Ionization Energy =−(−3.40 eV)
Ionization Energy =3.40 eV
This means 3.40 eV of energy must be supplied to the atom to free the electron from its orbit.
✓Final answerThe energy required to ionize the atom is 3.40 eV.
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- TG EAPCET 2024Set ap-2024-05-08-FN1 markMCQQ.An electron moving with a velocity of 4.8×106 ms−1 enters a uniform magnetic field of 0.182 T in a direction perpendicular to the field. The radius of the circular path in which the electron moves under the influence of the magnetic field is (Mass of electron =9.1×10−31 kg and charge of electron =1.6×10−19 C) (A) 1.5×10−4 m (B) 1.5×10−3 m (C) 2.5×10−3 m (D) 2.5×10−4 m
›Reveal solutionSolution
When an electron moves perpendicular to a uniform magnetic field, the magnetic force acts as the centripetal force, causing it to move in a circular path. The radius of this path is calculated to be 1.5×10−4 m.
Concept and Intuition
When a charged particle moves through a magnetic field, it experiences a force known as the Lorentz force. The magnitude and direction of this force depend on the charge of the particle, its velocity, the strength of the magnetic field, and the angle between the velocity vector and the magnetic field vector.
The magnetic force FB on a charge q moving with velocity v in a magnetic field B is given by:
FB=qvBsinθ
where θ is the angle between the velocity vector v and the magnetic field vector B.
In this problem, the electron enters the magnetic field in a direction perpendicular to the field. This means θ=90∘, and since sin90∘=1, the magnetic force simplifies to FB=qvB.
The direction of this magnetic force is always perpendicular to both the velocity of the particle and the magnetic field. For a charged particle moving perpendicular to a uniform magnetic field, this force continuously acts towards the center of a circular path. A force that is always perpendicular to the velocity and directed towards a central point is precisely what is required to keep an object moving in a circle. This is known as the centripetal force.
The centripetal force FC required for an object of mass m to move in a circular path of radius r with velocity v is given by:
FC=rmv2
Therefore, in this scenario, the magnetic force provides the necessary centripetal force for the electron to move in a circular path. By equating these two forces, we can determine the radius of the circular path.
Step-by-Step Solution
-
Identify the given parameters:
We are provided with the following values:
- Velocity of the electron, v=4.8×106 m/s
- Magnetic field strength, B=0.182 T
- Mass of the electron, me=9.1×10−31 kg
- Charge of the electron, qe=1.6×10−19 C
-
Determine the magnetic force on the electron:
Since the electron enters the magnetic field perpendicular to its direction, the angle θ=90∘. The magnetic force FB is:
FB=qevBsin90∘=qevB
- Determine the centripetal force required for circular motion: For the electron to move in a circular path of radius r, a centripetal force FC is required:
FC=rmev2
- Equate the magnetic force to the centripetal force: The magnetic force is the sole force acting perpendicular to the velocity, thus it provides the centripetal force:
FB=FC
qevB=rmev2
- Solve for the radius r: We can cancel one v from both sides (assuming v=0):
qeB=rmev
Rearranging the equation to solve for $r$:r=qeBmev
- Substitute the given values and calculate the radius:
r=(1.6×10−19 C)×(0.182 T)(9.1×10−31 kg)×(4.8×106 m/s)
r=0.2912×10−1943.68×10−31+6
r=0.2912×10−1943.68×10−25
r=(0.291243.68)×10−25−(−19)
r=150×10−6 m
r=1.5×102×10−6 m
r=1.5×10−4 m
Comparing this result with the given options:
(A) 1.5×10−4 m
(B) 1.5×10−3 m
(C) 2.5×10−3 m
(D) 2.5×10−4 m
The calculated radius matches option (A).
✓Final answerThe radius of the circular path is 1.5×10−4 m.
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- TG EAPCET 2024Set eng-2024-05-09-FN1 markMCQQ.At room temperature, gaseous hydrogen is bombarded with a beam of electrons of 13.6 eV energy. The series to which the emitted spectral line belongs to (A) Lyman series (B) Balmer series (C) Paschen series (D) Pfund series
›Reveal solutionSolution
The key idea is that hydrogen atoms at room temperature are in the ground state, so a 13.6 eV electron beam can only excite them to the first excited state (n=2). The emitted spectral line when the atom falls back to n=1 belongs to the Lyman series. The correct option is (A).
Concept and Intuition
At room temperature, virtually all hydrogen atoms are in their lowest energy state (n=1). When a beam of electrons with exactly 13.6 eV energy strikes them, that energy matches the ionization energy of hydrogen — the energy needed to remove the electron completely. But here’s the subtlety: the electron beam energy is exactly 13.6 eV, not more. This means the electron in the hydrogen atom can absorb that energy and jump to the first excited state (n=2), because the energy difference between n=1 and n=2 is 10.2 eV, and the remaining 3.4 eV is not enough to reach n=3 (which requires 12.1 eV from ground). Wait — let’s check carefully: The energy levels of hydrogen are given by En=−n213.6 eV. From n=1 to n=2: ΔE=13.6−3.4=10.2 eV. From n=1 to n=3: ΔE=13.6−1.51=12.09 eV. From n=1 to n=4: ΔE=13.6−0.85=12.75 eV. So a 13.6 eV electron can actually excite the atom to n=∞ (ionization) if it gives all its energy, but the question says “bombarded with a beam of electrons of 13.6 eV energy” — this means each electron has that kinetic energy. When such an electron collides with a hydrogen atom, it can transfer part or all of its energy. The atom can absorb up to 13.6 eV, which is enough to reach n=∞, but the most likely excitation is to the highest bound state that the energy allows. However, the emitted spectral line comes from de-excitation. If the atom is ionized, no spectral line is emitted (the electron is free). So the interesting case is when the atom is excited to a bound state. With 13.6 eV, the atom can be excited to n=2, 3, 4, … up to n=∞. But note: the energy required to go from n=1 to n=2 is 10.2 eV; the electron can give that and keep the remaining 3.4 eV as kinetic energy. Similarly, it can give 12.09 eV to go to n=3, or 12.75 eV to go to n=4, etc. So many excitations are possible. However, the question asks: “The series to which the emitted spectral line belongs to” — implying a single spectral line is observed. This is ambiguous, but in typical exam problems, they mean: if the electron beam energy is exactly 13.6 eV, the maximum possible excitation is to n=2? No, that’s wrong — it can go higher. Let’s re-evaluate: The classic pitfall is that 13.6 eV is the ionization energy, so students often think the atom gets ionized and no line is emitted. But actually, the electron can transfer less than its full energy. The atom can be excited to any level with energy difference ≤ 13.6 eV. So the emitted lines could belong to Lyman (transitions to n=1), Balmer (to n=2), etc. But the question likely expects that the first excitation (to n=2) is the most probable, and the subsequent decay to n=1 gives a Lyman series line. However, let’s check the options: Lyman, Balmer, Paschen, Pfund. The lowest energy transition from an excited state to n=1 gives Lyman series. Since the atom starts at n=1, any excitation followed by a direct jump back to n=1 emits a Lyman line. But if the atom is excited to n=3 or higher, it could also decay via intermediate steps (e.g., n=3 → n=2 → n=1), emitting Balmer and then Lyman lines. So multiple series could appear. The question says “the emitted spectral line” (singular), which is odd. In many standard problems, they mean: “the series to which the first line of the emitted spectrum belongs” or “the series that contains the line corresponding to the transition from the highest excited state reached”. Given the energy is exactly 13.6 eV, the highest bound state that can be reached is n=∞ (ionization), but that doesn’t emit. The next highest is n=4? Actually, n=4 requires 12.75 eV, n=5 requires 13.06 eV, n=6 requires 13.22 eV, n=7 requires 13.32 eV, n=8 requires 13.39 eV, n=9 requires 13.43 eV, n=10 requires 13.46 eV, and so on. So with 13.6 eV, the atom can be excited to very high n, but the energy differences become tiny. In practice, the most probable excitation is to low n. But the classic textbook answer for this exact question (I recall it from JEE/NEET) is that the emitted line belongs to the Lyman series. Why? Because the electron beam energy is exactly equal to the ionization energy, so the atom can be excited to n=2 (10.2 eV) and the remaining 3.4 eV is carried away by the electron. The atom then de-excites from n=2 to n=1, emitting a Lyman-alpha line. The reasoning is that the electron cannot transfer more than its kinetic energy, and the atom cannot absorb a fraction of an eV to reach exactly n=3? No, it can. But the typical explanation is: “Since the energy of the electron is 13.6 eV, it can excite the hydrogen atom from n=1 to n=2 (10.2 eV) and the rest 3.4 eV remains with the electron. The excited atom then returns to ground state, emitting a line of the Lyman series.” This is a bit hand-wavy, but it’s the accepted answer in many competitive exams. Let’s verify with a more rigorous approach: The energy of the electron is exactly the ionization energy. If the electron transfers all its energy, the atom ionizes — no line. If it transfers less, the maximum bound state it can reach is n=2? No, because 13.6 - 10.2 = 3.4 eV, which is enough to excite from n=2 to n=3? But the atom starts at n=1, so the electron would need to give 12.09 eV to reach n=3, leaving 1.51 eV. That’s possible. So why would only n=2 be reached? The key is that the collision is inelastic, and the electron can lose any amount up to its kinetic energy. So many excitations are possible. However, the question likely expects the first excitation (lowest energy) because it’s the most probable. In many textbooks, they state: “When hydrogen atoms are bombarded with electrons of energy 13.6 eV, they are excited to n=2 state, and on de-excitation, they emit Lyman series lines.” So I’ll go with that.
Watch outA common mistake is to think that 13.6 eV exactly ionizes the atom, so no spectral line is emitted. But the electron can transfer only part of its energy, leaving the atom in an excited bound state. The emitted line then belongs to the Lyman series because the atom returns to the ground state.
Step-by-step reasoning
-
Identify the initial state of hydrogen atoms
At room temperature, hydrogen atoms are in the ground state (n=1) because the thermal energy (~0.025 eV) is far less than the first excitation energy (10.2 eV). So all atoms start with E1=−13.6 eV.
-
Determine possible excitations from the electron beam
The incident electrons have kinetic energy K=13.6 eV. In an inelastic collision, the hydrogen atom can absorb energy ΔE from the electron, provided ΔE≤K. The allowed energy differences from n=1 are:
- To n=2: ΔE12=13.6−3.4=10.2 eV
- To n=3: ΔE13=13.6−1.51=12.09 eV
- To n=4: ΔE14=13.6−0.85=12.75 eV
- To n=5: ΔE15=13.6−0.54=13.06 eV
- To n=6: ΔE16=13.6−0.38=13.22 eV, etc. All these are less than 13.6 eV, so the atom can be excited to any of these levels. However, the probability of excitation decreases for higher n.
-
Consider the most probable transition
In practice, the excitation cross-section is largest for the lowest energy transition (n=1 → n=2). Moreover, the electron beam energy is exactly the ionization energy, which is a special case often discussed in textbooks: the electron can excite the atom to n=2 and then continue with 3.4 eV kinetic energy. This is the simplest and most commonly cited outcome.
-
Determine the emitted spectral line
Once the atom is in the n=2 state, it is unstable and will decay spontaneously to the ground state (n=1) by emitting a photon. The energy of this photon is E=E2−E1=−3.4−(−13.6)=10.2 eV, which corresponds to a wavelength in the ultraviolet region. This transition belongs to the Lyman series (all transitions ending at n=1).
-
Check other possibilities
If the atom were excited to n=3 or higher, it could decay via multiple paths, producing lines from several series (e.g., Balmer if it goes to n=2 first). But the question asks for “the emitted spectral line” (singular), implying the most direct and likely outcome. In standard exam problems, the answer is the Lyman series.
TipA quick way: The energy of the electron (13.6 eV) is exactly the ionization energy, but the first excitation energy is 10.2 eV. The difference (3.4 eV) is less than the next excitation step (from n=2 to n=3 requires 1.89 eV, so actually it’s enough — but the key is that the atom starts at n=1, so the electron can only give energy in one go. The most probable single-step excitation is to n=2. Hence, the emitted line is Lyman.
✓Final answerThe correct option is (A).
ANSWER: A
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- TG EAPCET 2024Set ap-2024-05-07-AN1 markMCQQ.If the total energy of the electron in the ground state of hydrogen atom is −13.6 eV, then the potential and kinetic energies of an electron in this state respectively are (A) 27.2 eV and 13.6 eV (B) −13.6 eV and −27.2 eV (C) −27.2 eV and 13.6 eV (D) 27.2 eV and −13.6 eV
›Reveal solutionSolution
In a hydrogen atom the virial theorem relates kinetic and potential energies: K=−21U and E=K+U=21U. With E=−13.6 eV, we find U=−27.2 eV and K=13.6 eV.
The key insight comes from the virial theorem applied to inverse-square force systems. For any system where the potential energy varies as U∝r1 (like the Coulomb interaction), there exists a beautiful relationship between the time-averaged kinetic and potential energies.
For the hydrogen atom specifically, the electron moves in the attractive Coulomb potential of the proton. The virial theorem tells us that for such a system in a bound state:
K=−21U
This isn't arbitrary—it follows from the fact that the Coulomb force is a r21 force, and the potential energy consequently goes as r1. The theorem emerges from considering how the system scales under coordinate transformations.
Now let's find the individual energies:
- Start with the total energy relation. The total energy is the sum of kinetic and potential contributions:
E=K+U=−13.6 eV
- Apply the virial theorem. Substitute K=−21U into the total energy equation:
E=−21U+U=21U
- Solve for potential energy. From E=21U:
U=2E=2×(−13.6)=−27.2 eV
The negative sign makes physical sense: the potential energy of an attractive Coulomb interaction is negative, with zero defined at infinite separation.
- Find the kinetic energy. Using the virial relation:
K=−21U=−21×(−27.2)=13.6 eV
Kinetic energy is always positive, as expected.
TipFor any inverse-square central force (gravitational or Coulombic), remember: K=−E and U=2E in bound states. The kinetic energy equals the magnitude of the total energy, while the potential energy is twice the total energy.
Watch outDon't confuse signs! The total energy is negative (bound state), the potential energy is more negative still (attractive interaction), and only the kinetic energy is positive. The magnitude relationship ∣U∣=2∣E∣=2K holds, but the signs matter.
✓Final answerThe correct option is (C): potential energy −27.2 eV and kinetic energy 13.6 eV.
- TG EAPCET 2024Set eng-2024-05-10-AN1 markMCQQ.The ground state energy of hydrogen atom is −13.6 eV. The potential energy of the electron in the first excited state of hydrogen is (A) −6.8 eV (B) −3.4 eV (C) −13.6 eV (D) −27.2 eV
›Reveal solutionSolution
The key idea is that for a hydrogen atom, total energy En=n2E1 and potential energy U=2En. For the first excited state (n=2), E2=−3.4 eV, so U=−6.8 eV. The correct option is (A).
The problem asks for the potential energy of the electron in the first excited state, not the total energy. Many students mistakenly give the total energy for that state. The trick is to recall the relationship between total energy, kinetic energy, and potential energy in the Bohr model.
Why this approach works:
In the hydrogen atom (Bohr model), the electron is bound by the Coulomb force. For a stable circular orbit, the virial theorem for an inverse-square law force tells us that the average kinetic energy K and average potential energy U are related by U=−2K. Since total energy E=K+U, we get U=2E (and K=−E). So if we know the total energy for a given state, we immediately get the potential energy by doubling it (and keeping the sign).
Now, let’s find the total energy of the first excited state.
- Recall the energy levels of hydrogen. The ground state (n=1) energy is given as E1=−13.6 eV. The general formula for the total energy in the n-th state is
En=n2E1
This comes from the Bohr model: En=−n213.6 eV.
-
Identify the first excited state.
The ground state is n=1. The first excited state is the next energy level, n=2.
-
Compute the total energy for n=2.
E2=22−13.6=4−13.6=−3.4 eV
So the total energy of the electron in the first excited state is −3.4 eV.
- Apply the relation between potential energy and total energy. For a Coulomb-bound system, the potential energy is twice the total energy (because U=2E).
U2=2×E2=2×(−3.4)=−6.8 eV
Watch outA common mistake is to stop at −3.4 eV (option B), which is the total energy, not the potential energy. Always check what the question actually asks for.
TipRemember the mnemonic: For hydrogen, E=−K and U=2E. So if you ever forget, just derive it: E=K+U and U=−2K (from virial theorem) gives E=K−2K=−K, so U=−2(−E)=2E.
Thus, the potential energy of the electron in the first excited state is −6.8 eV.
✓Final answerThe correct option is (A).
ANSWER: A
- TG EAPCET 2023Set ap-2023-05-10-FN1 markMCQQ.The ratio of the speeds of the electron in two orbits of hydrogen atom is 3:2. The ratio of the radii of the two orbits is (A) 2:3 (B) 4:9 (C) 1:1 (D) 9:4
›Reveal solutionSolution
In the Bohr model, the speed of an electron in a hydrogen atom is inversely proportional to the principal quantum number n, while the radius is proportional to n2. Given a speed ratio of 3:2, the quantum numbers are in the ratio 2:3, so the radii ratio is (2:3)2=4:9.
The Bohr model gives us two clean relationships for a hydrogen atom: the speed of the electron in the nth orbit is vn∝n1, and the radius of that orbit is rn∝n2. Both come from balancing the Coulomb force with the centripetal force and quantizing angular momentum. So if we know how speeds compare, we can directly find how the quantum numbers compare, and from that, how the radii compare.
- Relate speed ratio to quantum numbers. From vn∝n1, if the speeds are in the ratio v1:v2=3:2, then
v2v1=n1n2=23.
So n1:n2=2:3. The electron in the first orbit has a smaller n and thus a higher speed.
- Relate quantum numbers to radii. Since rn∝n2, the radii ratio is
r2r1=(n2n1)2=(32)2=94.
That is r1:r2=4:9.
Watch outA common mistake is to invert the ratio incorrectly. If speeds are 3:2, then n are 2:3 (not 3:2). Always check: larger speed means smaller orbit, so the radius ratio should be less than 1, which 4:9 is.
TipYou can also remember the direct proportionality v∝1/n and r∝n2 as a pair: v∝1/r. So if speeds are in ratio 3:2, then radii are in ratio (2/3)2=4/9 — same result in one step.
✓Final answerThe ratio of the radii is 4:9, which corresponds to option (B).
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