Q.How much positive and negative charge is there in a cup of water? (Assume the mass of one cup of water to be 250g.)
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The Photoelectric Effect: When Light Knocks Electrons Loose
Imagine you're throwing tennis balls at a wall covered in loose pebbles. If you throw hard enough, a pebble might get knocked off. That's the basic picture — but the photoelectric effect is the quantum version of this, and it completely shattered classical physics.
The Intuition
Light is made of tiny packets of energy called photons. Each photon carries a specific amount of energy, determined by its colour (frequency). When a photon hits a metal surface, it can transfer its energy to an electron inside the metal. If that energy is enough, the electron breaks free and flies out.
Think of electrons in a metal like people in a room with a high window. To escape, they need enough energy to reach the window sill. A photon is like a boost — but only if it gives enough energy in one shot. No amount of weak boosts (dim light) will work if each individual boost is too small.
The Precise Statement
Ephoton=hf=ϕ+Kmax
Where:
- Ephoton=hf is the energy of a photon (Planck's constant h=6.63×10−34 J⋅s, f is frequency)
- ϕ is the work function — the minimum energy needed to remove an electron from that metal
- Kmax is the maximum kinetic energy of the ejected electron
What Classical Physics Got Wrong
Before Einstein (1905), physicists thought light was a continuous wave. They expected:
- Brighter light → more energy per electron → faster electrons
- Any colour would eventually eject electrons if you waited long enough
But experiments showed the opposite:
| Observation | Classical Prediction | Actual Result |
|---|---|---|
| Effect of intensity | Brighter light → faster electrons | Brighter light → more electrons, same speed |
| Threshold frequency | None — any light works eventually | Below a certain frequency, no electrons no matter how bright |
| Time delay | Electrons need time to absorb energy | Electrons appear instantly (within 10−9 s) |
The Key Insight
Einstein said: light behaves like a stream of particles (photons), each with energy hf. One photon interacts with one electron. If hf<ϕ, the electron cannot escape — period. If hf>ϕ, the excess energy becomes kinetic energy:
Kmax=hf−ϕ
This is why:
- Increasing intensity (more photons) ejects more electrons, but each electron still gets the same energy per photon — so their speed doesn't change.
- Below threshold frequency, even a trillion photons per second can't help — each one is too weak individually.
The photoelectric effect proved that light is quantized — it comes in discrete packets. This was the birth of quantum mechanics. Einstein won the 1921 Nobel Prize for this, not for relativity.
A Worked Example
Problem: A metal has work function ϕ=2.0 eV. Light of frequency f=6.0×1014 Hz shines on it. Find the maximum kinetic energy of ejected electrons. (h=4.14×10−15 eV⋅s)
Step 1: Photon energy
E=hf=(4.14×10−15)(6.0×1014)=2.48 eV …
Why this formula?
Photoelectric Effect: Why the Key Formulas Hold
The photoelectric effect is a cornerstone of quantum physics. It showed that light behaves as particles (photons) , not just waves. Let's build the reasoning step-by-step.
1. The Core Idea: Energy Conservation
When a photon hits a metal surface, it transfers all its energy to a single electron inside the metal.
- The photon's energy is E=hf, where h is Planck's constant and f is the frequency of light.
- The electron needs a minimum energy to escape the metal — this is called the work function, ϕ.
Why only one electron?
Einstein proposed that light is quantized into discrete packets (photons). A single photon cannot split its energy among multiple electrons — it interacts with one electron at a time.
2. The Photoelectric Equation
If the photon's energy is greater than the work function, the excess energy becomes the electron's kinetic energy after escape:
hf=ϕ+Kmax
Where:
- hf = energy of incident photon
- ϕ = work function (minimum energy to remove electron)
- Kmax = maximum kinetic energy of ejected electron
Why "maximum" kinetic energy?
- Electrons inside the metal have different binding energies.
- Some electrons are near the surface (loosely bound) → get maximum K.
- Others are deeper → lose energy in collisions before escaping → lower K.
3. The Stopping Potential Connection
We measure Kmax using a stopping potential Vs:
Kmax=eVs
Where e is the electron charge. This is because:
- An electric field opposing the electron's motion does work eVs to stop it.
- At the stopping potential, the electron's kinetic energy is exactly balanced by the electric potential energy.
Combining:
hf=ϕ+eVs
This is the Einstein photoelectric equation in its most testable form.
4. Why the Threshold Frequency Exists
From the equation:
hf=ϕ+eVs
If f is too low, hf<ϕ. Then:
- The photon cannot supply enough energy to overcome the work function.
- No electron is ejected, regardless of light intensity.
The threshold frequency f0 is when Kmax=0:
hf0=ϕ⇒f0=hϕ
Why intensity doesn't matter for ejection?
- Intensity = number of photons per second.
- Each photon still has energy hf. If hf<ϕ, even a billion photons won't eject an electron — each photon is individually too weak.
5. Why Kinetic Energy Depends on Frequency, Not Intensity
From Kmax=hf−ϕ:
- Frequency f directly determines Kmax.
- Intensity only affects the number of electrons ejected (more photons → more electrons), not their individual energy.
This was the key experimental contradiction with classical wave theory:
- Classical: Higher intensity = bigger wave amplitude = more energy to electrons.
- Reality: Higher frequency = more energy per electron; intensity only changes current.
6. Summary of Key Relationships …
Water is electrically neutral, but each molecule packs equal amounts of positive (protons) and negative (electrons) charge. We count one kind; the other is equal in magnitude.
- Moles of water. Molar mass of H2O=18g/mol, so 250g is
n=18250=13.9mol.
- Molecules. N=nNA=13.9×6.022×1023=8.36×1024.
- Protons (or electrons) per molecule. H2O has 2(1)+8=10 of each.
- Total positive charge. …
Counting the 10 protons (and 10 electrons) in every water molecule, a 250g cup contains about 1.34×107C of positive charge and an equal magnitude of negative charge — they cancel, which is why water is neutral.
This question is about the charge that matter contains, not any net charge it carries. Every neutral molecule holds equal positive and negative charge; the task is to work out how large each of those is for a cup of water.
Step 1 — Number of moles.
The molar mass of water is M=2(1)+16=18g/mol, so
n=Mm=18250=13.9mol.
Step 2 — Number of molecules.
N=nNA=13.9×(6.022×1023)=8.36×1024 molecules.
Step 3 — Charges per molecule.
Each H2O has 2 hydrogen atoms (1 proton each) and 1 oxygen atom (8 protons), i.e. 10 protons and, being neutral, 10 electrons.
Step 4 — Total positive charge.
Total protons =10N=8.36×1025, so …
Method: Atomic Charge Counting via Avogadro's Number
This method uses the fact that every atom in water is electrically neutral overall, but contains equal amounts of positive charge (in protons) and negative charge (in electrons). We count the total number of each type of charge carrier.
Step 1: Find the number of water molecules
- Molar mass of water (H2O): 2×1+16=18 g/mol
- Number of moles in 250 g of water: n=18250≈13.89 mol
- Using Avogadro's number (NA=6.022×1023 mol−1): Nmolecules=n×NA≈13.89×6.022×1023≈8.36×1024 molecules
Step 2: Count protons and electrons per molecule
Each water molecule has:
- 10 electrons (8 from oxygen + 1 from each hydrogen)
- 10 protons (8 from oxygen + 1 from each hydrogen)
So total number of protons = total number of electrons:
Nprotons=Nelectrons=10×8.36×1024=8.36×1025
Step 3: Compute the total charge
Charge of one proton: +e=+1.602×10−19 C …
Common Mistakes: Charge in a Cup of Water
Students often make predictable errors on this question. Here are the most common ones — and how to avoid each.
1. Forgetting that water is electrically neutral
Mistake:
Students calculate only the number of electrons or protons, then report that as the net charge.
Why it’s wrong:
A cup of water has equal numbers of protons and electrons. The net charge is zero. The question asks for the amount of positive and negative charge separately, not the net charge.
How to avoid:
Always start by stating: “Water is neutral — total positive charge equals total negative charge.” Then calculate the magnitude of one type.
2. Using the wrong molecular formula or atomic numbers
Mistake:
Treating water as H2O but forgetting that:
- Hydrogen has 1 proton (atomic number Z=1)
- Oxygen has 8 protons (Z=8)
So total protons per water molecule = 1+1+8=10.
How to avoid:
Write it down explicitly:
Protons per H2O=2×1+1×8=10
3. Confusing mass with number of molecules
Mistake:
Using 250g directly without converting to moles.
How to avoid:
Always use the molar mass:
- Molar mass of water = 18g/mol
- Number of moles = 18250≈13.89mol
- Number of molecules = 13.89×6.022×1023
4. Using the wrong value for elementary charge
Mistake:
Using e=1.6×10−19C but forgetting that proton charge is +e and electron charge is −e.
How to avoid:
Write clearly:
- Charge of one proton = +1.6×10−19C
- Charge of one electron = −1.6×10−19C
5. Reporting the answer with wrong sign or units …
- Higher Secondary (+2 Stage) Examination 2026Set ANNUAL1 markQ.The graph below shows, for a photoelectric-effect experiment, the variation of photoelectric current (I) with collector potential (V) for two different incident waves of frequencies ν1 and ν2. Which of the two frequencies ν1 and ν2 is larger?
›Reveal solutionSolution
A higher stopping potential means a higher frequency (Einstein's photoelectric equation), and here ν1's stopping potential (−V1, further from the origin/more negative) is larger in magnitude than ν2's, so ν1 > ν2.
By Einstein's photoelectric equation,
eV0=hν−ϕ0⟹V0=ehν−eϕ0 …
- Higher Secondary (+2 Stage) Examination 2025Set ANNUAL1 markMCQQ.In the photoelectric effect, which graph correctly shows the relationship between the kinetic energy of the emitted electrons and the frequency of the incident light?(a) graph (A) — straight line through the origin, moderate slope(b) graph (B) — straight line with positive intercept, gentle positive slope, offset from origin(c) graph (C) — straight line through the origin, steep slope(d) graph (D) — straight line with positive intercept, negative slope
›Reveal solutionSolution
Einstein's photoelectric equation KE_max = h*nu - phi0 is a straight line in frequency with slope h (same for every metal) that does NOT pass through the origin, because of the work function -- KE rises only above the threshold frequency.
Einstein's photoelectric equation: KEmax=hν−ϕ0, where ϕ0=hν0 is the work function and ν0 the threshold frequency.
…
- Higher Secondary (+2 Stage) Examination 2025Set ANNUAL1 markQ.In the context of the photoelectric effect, write the relationship between threshold frequency and work function.
›Reveal solutionSolution
The work function is simply the photon energy corresponding to the threshold frequency.
The threshold frequency ν0 is the minimum frequency of incident light needed to just eject an electron from a metal surface, with zero kinetic energy left over. The energy of a photon of exactly this threshold frequency equals t …
- Higher Secondary (+2 Stage) Examination 2023Set ANNUAL1 markQ.The work functions of two metals are 4 eV and 10 eV respectively. Which metal has the higher threshold wavelength?
›Reveal solutionSolution
Threshold wavelength λ0 = hc/φ0, so the SMALLER the work function, the LARGER the threshold wavelength.
The threshold frequency ν0 and work function φ0 are related by φ0 = hν0 = hc/λ0, so
λ0 = hc/φ0
This shows λ0 is inversely proportional to φ0. Comparing the two metals:
- Metal 1: φ0 = 4 eV → λ0 = hc/4eV (larger λ0, since φ0 is smaller)
- Metal 2: φ0 = 10 eV → λ0 = hc/10eV (smaller λ0) …
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