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NCERT Exemplar · Q5

Q.23He^{3}_{2}\text{He} and 13H^{3}_{1}\text{H} nuclei have the same mass number. Do they have the same binding energy?

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Binding energy depends on both mass number and proton number (Z). Even though 23He^{3}_{2}\text{He} and 13H^{3}_{1}\text{H} have the same mass number A=3A=3, their different proton counts lead to different Coulomb repulsion and different nuclear compositions, so their binding energies are not the same.

Why binding energy varies with Z

Binding energy is the energy required to break a nucleus into its individual protons and neutrons. It comes from the strong nuclear force holding nucleons together, but this force is affected by two key factors:

  1. Number of nucleons (AA) — more nucleons generally mean more binding, but the relationship isn't linear.
  2. Proton count (ZZ) — protons repel each other electrically, so extra protons reduce the net binding.

The semi-empirical mass formula (Bethe-Weizsäcker formula) captures this:

B=avA−asA2/3−acZ(Z−1)A1/3−aa(A−2Z)2A+δ(A,Z)B = a_v A - a_s A^{2/3} - a_c \frac{Z(Z-1)}{A^{1/3}} - a_a \frac{(A-2Z)^2}{A} + \delta(A,Z)

The key term here is the Coulomb term (−acZ(Z−1)A1/3-a_c \frac{Z(Z-1)}{A^{1/3}}). For fixed AA, a larger ZZ means more electrostatic repulsion, which reduces the binding energy.

Step-by-step comparison

  1. Identify the nuclei

    23He^{3}_{2}\text{He} has Z=2Z=2, N=1N=1 (one neutron, two protons).

    13H^{3}_{1}\text{H} (tritium) has Z=1Z=1, N=2N=2 (two neutrons, one proton).

    Both have A=3A=3.

  2. Apply the Coulomb term

    For 23He^{3}_{2}\text{He}: Z=2Z=2, so Z(Z−1)=2Z(Z-1)=2. The Coulomb term is −ac⋅231/3-a_c \cdot \frac{2}{3^{1/3}}.

    For 13H^{3}_{1}\text{H}: Z=1Z=1, so Z(Z−1)=0Z(Z-1)=0. The Coulomb term is zero.

    This alone tells us 23He^{3}_{2}\text{He} has less binding energy due to proton-proton repulsion.

  3. Consider the asymmetry term

    The term −aa(A−2Z)2A-a_a \frac{(A-2Z)^2}{A} penalizes imbalance between protons and neutrons.

    For 23He^{3}_{2}\text{He}: A−2Z=3−4=−1A-2Z = 3-4 = -1, so (A−2Z)2=1(A-2Z)^2 = 1.

    For 13H^{3}_{1}\text{H}: A−2Z=3−2=1A-2Z = 3-2 = 1, also (A−2Z)2=1(A-2Z)^2 = 1.

    So the asymmetry term is identical for both — no difference here.

  4. Check the pairing term

    The pairing term δ(A,Z)\delta(A,Z) accounts for whether ZZ and NN are even or odd.

    23He^{3}_{2}\text{He}: Z=2Z=2 (even), N=1N=1 (odd) → an even-ZZ, odd-NN configuration, which gives a small positive δ\delta (extra binding).

    13H^{3}_{1}\text{H}: Z=1Z=1 (odd), N=2N=2 (even) → odd-even, also a small positive δ\delta. …

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