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Exercises · 11.4

Q.A cylinder with a movable piston contains 3 moles of hydrogen at standard temperature and pressure. The walls of the cylinder are made of a heat insulator, and the piston is insulated by having a pile of sand on it. By what factor does the pressure of the gas increase if the gas is compressed to half its original volume?

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For an adiabatic process (insulated cylinder + piston), the pressure and volume obey PVγ=constantPV^\gamma = \text{constant}. For hydrogen (diatomic gas), γ=7/5=1.4\gamma = 7/5 = 1.4. Compressing to half volume gives a pressure increase factor of 21.4≈2.642^{1.4} \approx 2.64.

The problem describes a gas that is compressed without any heat exchange — the cylinder walls are heat insulators, and the pile of sand on the piston ensures no heat flows through it either. This is the classic setup for an adiabatic process. The key idea is that when you compress a gas adiabatically, the temperature rises because the work done on the gas goes entirely into increasing its internal energy. So pressure increases more than it would in an isothermal compression.

Let’s walk through it step by step.

  1. Identify the process. The cylinder and piston are both insulated — no heat enters or leaves the system. This is an adiabatic process. For an ideal gas undergoing a reversible adiabatic change, the relation between pressure and volume is:

PVγ=constantPV^\gamma = \text{constant}

where γ=CP/CV\gamma = C_P/C_V, the ratio of specific heats.

  1. Determine γ\gamma for hydrogen. Hydrogen (H2H_2) is a diatomic gas at standard temperature. For diatomic gases, the molar specific heats are:

CV=52R,CP=72RC_V = \frac{5}{2}R, \quad C_P = \frac{7}{2}R

Therefore:

γ=CPCV=7/25/2=75=1.4\gamma = \frac{C_P}{C_V} = \frac{7/2}{5/2} = \frac{7}{5} = 1.4

Note

At very high temperatures, diatomic molecules can have vibrational modes, but at STP (standard temperature and pressure, 0°C and 1 atm), only translational and rotational modes are active. So γ=1.4\gamma = 1.4 is correct.

  1. Apply the adiabatic relation. Let initial pressure and volume be P1P_1 and V1V_1. After compression, the volume becomes V2=V1/2V_2 = V_1/2. Using P1V1γ=P2V2γP_1 V_1^\gamma = P_2 V_2^\gamma, we get:

P2=P1(V1V2)γ=P1(V1V1/2)γ=P1(2)γP_2 = P_1 \left( \frac{V_1}{V_2} \right)^\gamma = P_1 \left( \frac{V_1}{V_1/2} \right)^\gamma = P_1 (2)^\gamma

  1. Compute the factor. The factor by which pressure increases is 2γ=21.42^\gamma = 2^{1.4}.

21.4=27/5=(27)1/5=1281/52^{1.4} = 2^{7/5} = (2^7)^{1/5} = 128^{1/5}

The fifth root of 128 is not an integer, but we can approximate: …

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