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Chemistry · Ch 2 — Structure of Atom

Heisenberg's Uncertainty Principle

2.5

Heisenberg's Uncertainty Principle

Once matter is accepted to have wave character, a serious conceptual problem follows: a wave, by its very nature, is spread out over some region of space, so it does not make sense to ask exactly where a wave is located the way one asks where a classical particle is. Werner Heisenberg (1927) turned this observation into a precise, quantitative principle.

Statement. It is impossible to determine, simultaneously and with unlimited precision, both the exact position and the exact momentum (or velocity) of a microscopic particle such as an electron. If Δx\Delta x is the uncertainty in position and Δp\Delta p is the uncertainty in momentum, then

Δx⋅Δp≥h4π\Delta x \cdot \Delta p \geq \frac{h}{4\pi}

Since p=mvp = mv, and the mass mm of the particle is taken as fixed and known exactly, this can be rewritten in terms of the uncertainty in velocity, Δv\Delta v:

Δx⋅Δv≥h4πm\Delta x \cdot \Delta v \geq \frac{h}{4\pi m}

The product of the two uncertainties can never be smaller than h/4πh/4\pi -- so making one uncertainty very small (measuring position very precisely) necessarily makes the other uncertainty very large (the momentum becomes correspondingly ill-defined), and vice versa. This is not a statement about the limits of our measuring instruments; it is a fundamental feature of nature at the quantum scale, built into the wave character of matter itself. …