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Physics · Ch 14 — Waves

Speed of Sound in a Gaseous Medium: Newton's Formula and Laplace's Correction

14.6

Speed of Sound in a Gaseous Medium: Newton's Formula and Laplace's Correction

Sound travels through a gas such as air as a longitudinal wave, so the relevant elastic property is the gas's bulk modulus BB (which measures its resistance to compression) and the relevant inertial property is its density ρ\rho, giving the general speed formula v=Bρv = \sqrt{\frac{B}{\rho}} The historical difficulty lay in deciding which bulk modulus to use, since a gas's bulk modulus depends on exactly how its compression takes place. Newton assumed that the compressions and rarefactions of a sound wave in air occur slowly enough for heat generated in a compression to flow away and be absorbed from a rarefaction, keeping the temperature of the gas constant throughout -- an isothermal process, obeying Boyle's law PV=constantPV=\text{constant}. Differentiating this relation gives the isothermal bulk modulus as simply Bisothermal=PB_{\text{isothermal}}=P, the gas's own pressure, so Newton's formula for the speed of sound is vN=Pρv_N = \sqrt{\frac{P}{\rho}} At standard temperature and pressure (P≈1.0×105 PaP\approx1.0\times10^{5}\ \text{Pa}, ρ≈1.29 kg m−3\rho\approx1.29\ \text{kg m}^{-3} for air) this predicts vN≈280 m s−1v_N\approx280\ \text{m s}^{-1} -- roughly 15-16% lower than the experimentally measured speed of sound in air, about 332 m s−1332\ \text{m s}^{-1}, a discrepancy Newton himself could not resolve. Laplace corrected the error over a century later, by pointing out that the compressions and rarefactions in a sound wave actually happen far too rapidly for any appreciable heat to be exchanged between neighbouring compressed and rarefied layers of air -- so the process is adiabatic, not isothermal, obeying PVγ=constantPV^\gamma=\text{constant}, where γ=CP/CV\gamma=C_P/C_V is the ratio of the gas's specific heat at constant pressure to that at constant volume. Differentiating this adiabatic relation gives the adiabatic bulk modulus as Badiabatic=γPB_{\text{adiabatic}}=\gamma P, larger than the isothermal value by the factor γ\gamma, so Laplace's corrected formula is vL=γPρv_L = \sqrt{\frac{\gamma P}{\rho}} For air, γ≈1.4\gamma\approx1.4, and Laplace's formula raises the predicted speed by a factor 1.4≈1.18\sqrt{1.4}\approx1.18 -- about 18% higher than Newton's value -- bringing the predicted speed to about 332 m s−1332\ \text{m s}^{-1}, in close agreement with experiment. Using the ideal gas equation PV=nRTPV=nRT (with …

Table 1Newton's formula versus Laplace's corrected formula for the speed of sound in air
FormulaAssumed processGas lawPredicted speed (air, STP)
NewtonvN=P/ρv_N=\sqrt{P/\rho}IsothermalPV=constantPV=\text{constant}≈280 m s−1\approx280\ \text{m s}^{-1} (too low)