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Physics · Ch 12 — Atoms

Continuous and Characteristic X-Rays

12.8

Continuous and Characteristic X-Rays

Two distinct components in one beam. Spectroscopic analysis of the X-rays leaving a Coolidge tube (Section 1.7) -- plotting the intensity of X-rays produced against their wavelength -- reveals that the beam is not of a single kind at all, but a superposition of two physically distinct components (Figure 1): a smooth, continuously varying background, and a small number of sharp, intense spikes superimposed on top of it. Each is produced by a completely different physical process happening inside the target.

Continuous X-rays (bremsstrahlung). As a fast electron penetrates the target, it repeatedly passes close to the strong positive electric field of a target atom's nucleus, and is deflected and abruptly DECELERATED by the Coulomb attraction it experiences -- a sudden negative acceleration. Just as an accelerating charge radiates energy classically (the same principle behind why a Rutherford-model electron should have radiated continuously, Section 1.3), a decelerating electron radiates a photon carrying away the kinetic energy it loses in that one encounter. Because an electron can lose ANY fraction of its kinetic energy in a given encounter -- from a tiny sliver, in a distant near-miss, up to virtually the whole of it, in one close encounter -- the photons produced span a continuous, unbroken RANGE of energies (and hence wavelengths); this component is accordingly called the continuous X-ray spectrum, or bremsstrahlung (German for "braking radiation", describing exactly what produces it).

The short-wavelength limit λmin⁡\lambda_{\min}. Although the continuous spectrum covers a whole range of wavelengths, it does NOT extend down to arbitrarily short wavelengths -- it has a sharp, well-defined lower cut-off, λmin⁡\lambda_{\min} (Figure 1). This limit occurs for the special (rare) case in which an incident electron loses its ENTIRE kinetic energy eVeV in a SINGLE encounter, converting all of it into ONE photon of the maximum possible energy:

eV=hcλmin⁡⟹λmin⁡=hceVeV = \frac{hc}{\lambda_{\min}} \quad\Longrightarrow\quad \boxed{\lambda_{\min} = \frac{hc}{eV}}

Since this expression involves only the electron's charge ee, Planck's constant hh, the speed of light cc, and the accelerating voltage VV, λmin⁡\lambda_{\min} is completely INDEPENDENT of the target material -- a purely quantum result (Numerical 7 evaluates it for a typical tube voltage), with no counterpart at all in classical electromagnetic theory, which predicts no such minimum wavelength should exist. …

Figure 1X-ray spectrum from a Coolidge tube: continuous background plus characteristic lines

What this figure shows. A graph is drawn with wavelength λ\lambda on the horizontal axis, increasing to the right, and intensity of X-rays emitted on the vertical axis, increasing upward. A single smooth, continuous curve starts at zero intensity at a sharply defined minimum wavelength on the horizontal axis, labelled λmin⁡\lambda_{\min}, rises steeply to a broad rounded maximum a little further to the right, and then falls off gradually, tailing away smoothly toward larger wavelengths -- this smooth curve represents the continuous (bremsstrahlung) X-ray background. Superimposed on top of this smooth curve, rising sharply out of it at two specific wavelengths a little to the right of λmin⁡\lambda_{\min}, are two narrow, tall vertical spikes: a taller spike labelled KαK_\alpha at a shorter wavelength and a shorter spike labelled KβK_\beta at a slightly longer wavelength, both spikes rising well above the smooth continuous curve beneath them. A dashed vertical line is dropped from λmin⁡\lambda_{\min} down to the horizontal axis to mark its exact position clearly, dist …