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NCERT Exemplar · Q51

Q.Assertion (A): Boron has a smaller first ionisation enthalpy than beryllium.
Reason (R): The penetration of a 2s electron to the nucleus is more than the 2p electron hence 2p electron is more shielded by the inner core of electrons than the 2s electrons.

(i) Assertion and reason both are correct statements but reason is not correct explanation for assertion.
(ii) Assertion is correct statement but reason is wrong statement.
(iii) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(iv) Assertion and reason both are wrong statements.
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Both the assertion and the reason are correct, and the reason is the correct explanation of the assertion — option (iii).

Assertion (A): Boron (1s2 2s2 2p11s^2\,2s^2\,2p^1) does have a smaller first ionisation enthalpy than beryllium (1s2 2s21s^2\,2s^2). Measured values are ΔiH1(Be)≈899 kJ mol−1\Delta_i H_1(\text{Be}) \approx 899\ \text{kJ mol}^{-1} versus ΔiH1(B)≈801 kJ mol−1\Delta_i H_1(\text{B}) \approx 801\ \text{kJ mol}^{-1}. So the assertion is a correct statement.

Reason (R): A 2s2s electron penetrates closer to the nucleus than a 2p2p electron, so the 2p2p electron is more shielded by the inner core and is held less tightly. This too is a correct statement. …

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